Solid state nuclear bromination with N-bromosuccinimide. Part 1. Experimental and theoretical studies on some substituted aniline, phenol and nitro aromatic compounds †

Author(s):  
Jagarlapudi A. R. P. Sarma ◽  
Akula Nagaraju
2019 ◽  
Vol 15 (S350) ◽  
pp. 420-421
Author(s):  
Marina G. Rachid ◽  
Jeroen Terwisscha van Scheltinga ◽  
Daniël Koletzki ◽  
Giulia Marcandalli ◽  
Ewine F. van Dishoeck ◽  
...  

AbstractExperimental and theoretical studies have shown that Complex Organic Molecules (COMs) can be formed on icy dusty grains in molecular clouds and protoplanetary disks. The number of astronomical detections of solid COMs, however, is very limited. With the upcoming launch of the James Webb Space Telescope (JWST) this should change, but in order to identify solid state features of COMs, accurate laboratory data are needed. Here we present high resolution (0.5 cm–1) infrared ice spectra of acetone (C3H6O) and methyl formate (HCOOCH3), two molecules already identified in astronomical gas phase surveys, whose interstellar synthesis is expected to follow solid state pathways.


2015 ◽  
Vol 44 (18) ◽  
pp. 6535-6559 ◽  
Author(s):  
Kévin Cocq ◽  
Christine Lepetit ◽  
Valérie Maraval ◽  
Remi Chauvin

Recent advances in experimental and theoretical studies ofcarbo-benzene derivatives, along with the proposition of a generalization of the definition of aromaticity to the two-membered π-rings of triple bonds, suggest relevance for the notion of “carbo-aromaticity”.


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