Synthesis, crystal structures and NMR and luminescence spectra of lanthanide complexes of 1,4,7,10-tetraazacyclododecane with N-methylene(phenyl)phosphinic acid pendant arms †

Author(s):  
Jan Rohovec ◽  
Pavel Vojtíšek ◽  
Petr Hermann ◽  
Jiří Mosinger ◽  
Zdirad Žák ◽  
...  
1992 ◽  
Vol 46 (2) ◽  
pp. 273-276 ◽  
Author(s):  
G. Chen ◽  
R. G. Haire ◽  
J. R. Peterson

We have investigated the Eu3+ ion luminescence spectra from different host crystals of the lanthanide sesquioxides exhibiting either the A, B, or C form. The Eu3+ ion luminescence spectra from B-type Eu2O3 and from Eu3+-doped A-type La2O3 and C-type Lu2O3 were obtained at room temperature. It is suggested that the luminescence from f-f transitions in the Eu3+ ion can be used to determine the crystal structure, because the different Eu3+ ion site symmetries in the different crystal structures give rise to different characteristic spectral splitting patterns.


2015 ◽  
Vol 615 ◽  
pp. 1-7 ◽  
Author(s):  
Xiao-Xia Qi ◽  
Jun-Chen Wu ◽  
Ning Ren ◽  
Chun-Li Zhao ◽  
Jian-Jun Zhang ◽  
...  

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