Synthesis, crystal structure and properties of trigonal bipyramidal [M(L5)2(H2O)]·H2O complexes [M = cobalt(II) (S = 3/2) or copper(II) (S = 1/2); HL5 = N-(2-chloro-6-methylphenyl)pyridine-2-carboxamide]

Author(s):  
Apurba Kumar Patra ◽  
Manabendra Ray ◽  
Rabindranath Mukherjee
2002 ◽  
Vol 55 (6) ◽  
pp. 711-716 ◽  
Author(s):  
Xing-You Xu ◽  
Tao Zheng ◽  
Wei-Xing Ma ◽  
Ming-Xing Zhang ◽  
Qing-Liang Liu ◽  
...  

1972 ◽  
Vol 33 (C2) ◽  
pp. C2-241-C2-242
Author(s):  
Yu. N. VENEVTSEV ◽  
A. G. KAPYSHEV ◽  
V. M. LEBEDEV ◽  
V. D. SAL'NIKOV ◽  
G. S. ZHDANOV

1991 ◽  
Vol 403 (1-2) ◽  
pp. 269-277 ◽  
Author(s):  
Vincenzo De Felice ◽  
Vincenzo G. Albano ◽  
Carlo Castellari ◽  
Maria E. Cucciolito ◽  
Augusto De Renzi

2005 ◽  
Vol 40 (5) ◽  
pp. 800-809 ◽  
Author(s):  
Alexander A. Tsirlin ◽  
Victoria V. Chernaya ◽  
Roman V. Shpanchenko ◽  
Evgeny V. Antipov ◽  
Joke Hadermann

Author(s):  
Zhirong Luo ◽  
Xianhong Yin ◽  
Qiaolan Wu ◽  
Jichang Zhuang ◽  
Dandan Zhao ◽  
...  

1984 ◽  
Vol 62 (3) ◽  
pp. 601-605 ◽  
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Masood A. Khan ◽  
Clovis Peppe ◽  
Dennis G. Tuck

The crystal structure of the title compound has been determined by the heavy atom method. The crystals are orthorhombic, space group Pbca, with unit cell dimensions a = 22.795(3) Å, b = 17.518(2) Å, c = 12.396(3) Å, Z = 8; R = 0.0409 for 1527 unique "observed" reflections. The structure is disordered, with each halogen site (X) occupied by 75% Br, 25% I. The molecule consists of two X2(tmen)In units (tmen = N,N,N′,N′-tetramethylethanediamine) with distorted trigonal bipyramidal geometry, joined by an In—In bond 2.775(2) Å in length.


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