Diazoacetaldehyde: completion of the rate profile for hydration of its photo-Wolff rearrangement product, ketene, in aqueous solution and kinetics and mechanism of acid-catalyzed hydrolysis of the diazoaldehyde †

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/a901238i ◽

1999 ◽

pp. 1107-1110 ◽

Cited By ~ 10

Author(s):

Y. Chiang ◽

A. J. Kresge ◽

V. V. Popik

Keyword(s):

Aqueous Solution ◽

Kinetics And Mechanism ◽

Rearrangement Product ◽

Wolff Rearrangement ◽

Acid Catalyzed ◽

Rate Profile ◽

Hydrolysis Of

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ChemInform Abstract: Diazoacetaldehyde: Completion of the Rate Profile for Hydration of Its Photo-Wolff Rearrangement Product, Ketene, in Aqueous Solution and Kinetics and Mechanism of Acid-Catalyzed Hydrolysis of the Diazoaldehyde.

ChemInform ◽

10.1002/chin.199933053 ◽

2010 ◽

Vol 30 (33) ◽

pp. no-no

Author(s):

Y. Chiang ◽

A. J. Kresge ◽

V. V. Popik

Keyword(s):

Aqueous Solution ◽

Kinetics And Mechanism ◽

Rearrangement Product ◽

Wolff Rearrangement ◽

Acid Catalyzed ◽

Rate Profile ◽

Hydrolysis Of

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Kinetics and mechanism of the reactions of sulfito complexes in aqueous solution. 3. Formation, acid-catalyzed decomposition, and intramolecular isomerization of oxygen-bonded (.alpha..beta.S)-(sulfito)(tetraethylenepentamine)cobalt(III) ion and the hydrolysis of its sulfur-bonded analog

Inorganic Chemistry ◽

10.1021/ic50224a007 ◽

1981 ◽

Vol 20 (10) ◽

pp. 3160-3166 ◽

Cited By ~ 22

Author(s):

A. C. Dash ◽

A. A. El-Awady ◽

G. M. Harris

Keyword(s):

Aqueous Solution ◽

Kinetics And Mechanism ◽

Acid Catalyzed ◽

Hydrolysis Of

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ChemInform Abstract: Kinetics and Mechanism of the Acid-Catalyzed Hydrolysis of 1,1- Dimethoxyethene (Ketene Dimethyl Acetal) and Trimethoxyethene in Aqueous Solution.

ChemInform ◽

10.1002/chin.199231079 ◽

2010 ◽

Vol 23 (31) ◽

pp. no-no

Author(s):

A. J. KRESGE ◽

M. LEIBOVITCH

Keyword(s):

Aqueous Solution ◽

Dimethyl Acetal ◽

Kinetics And Mechanism ◽

Acid Catalyzed ◽

Hydrolysis Of

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Kinetics and mechanism of the acid-catalyzed hydrolysis of 1,1-dimethoxyethene (ketene dimethyl acetal) and trimethoxyethene in aqueous solution

Journal of the American Chemical Society ◽

10.1021/ja00034a052 ◽

1992 ◽

Vol 114 (8) ◽

pp. 3099-3102 ◽

Cited By ~ 8

Author(s):

A. J. Kresge ◽

M. Leibovitch

Keyword(s):

Aqueous Solution ◽

Dimethyl Acetal ◽

Kinetics And Mechanism ◽

Acid Catalyzed ◽

Hydrolysis Of

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ChemInform Abstract: Kinetics and Mechanism of the Acid-Catalyzed Aquation and Base Hydrolysis of Nitropentacyanoferrate(III) in Aqueous Solution. Evidence for a Pseudo-Zero-Order Hydrolysis Process

ChemInform ◽

10.1002/chin.198848261 ◽

1988 ◽

Vol 19 (48) ◽

Author(s):

G. STOCHEL ◽

R. VAN ELDIK ◽

E. HEJMO ◽

Z. STASICKA

Keyword(s):

Aqueous Solution ◽

Zero Order ◽

Kinetics And Mechanism ◽

Base Hydrolysis ◽

Hydrolysis Process ◽

Acid Catalyzed ◽

Hydrolysis Of

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Kinetics and mechanism of the acid-catalyzed aquation and base hydrolysis of nitropentacyanoferrate(III) in aqueous solution. Evidence for a pseudo-zero-order hydrolysis process

Inorganic Chemistry ◽

10.1021/ic00289a005 ◽

1988 ◽

Vol 27 (16) ◽

pp. 2767-2770 ◽

Cited By ~ 14

Author(s):

G. Stochel ◽

R. Van Eldik ◽

E. Hejmo ◽

Z. Stasicka

Keyword(s):

Aqueous Solution ◽

Zero Order ◽

Kinetics And Mechanism ◽

Base Hydrolysis ◽

Hydrolysis Process ◽

Acid Catalyzed ◽

Hydrolysis Of

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Kinetics and Mechanism of Isomerization and Hydrolysis of 4,6-Diamino-1-(3,5)-dichlorophenyl-1,2-dihydro-2,2-dimethyl-1,3,5-triazine in Dilute Aqueous Solution

Journal of Pharmaceutical Sciences ◽

10.1002/jps.2600531005 ◽

1964 ◽

Vol 53 (10) ◽

pp. 1156-1160 ◽

Cited By ~ 10

Author(s):

D.H. Szulczewski ◽

C.M. Shearer ◽

A.J. Aguiar

Keyword(s):

Aqueous Solution ◽

Kinetics And Mechanism ◽

Dilute Aqueous Solution ◽

Hydrolysis Of

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THE CHEMISTRY OF ETHYLENE OXIDE: V. THE REACTION OF ETHYLENE OXIDE WITH HALIDE IONS IN NEUTRAL AND ACID SOLUTION

Canadian Journal of Chemistry ◽

10.1139/v52-025 ◽

1952 ◽

Vol 30 (3) ◽

pp. 169-176 ◽

Cited By ~ 8

Author(s):

A. M. Eastham ◽

G. A. Latremouille

Keyword(s):

Aqueous Solution ◽

Ethylene Oxide ◽

Acid Solution ◽

Activation Energies ◽

Hydrogen Halide ◽

Halide Ions ◽

Neutral Aqueous Solution ◽

Rate Of Hydrolysis ◽

Acid Catalyzed ◽

Hydrolysis Of

The rates of reaction of halide ions with ethylene oxide in neutral aqueous solution and the rate of hydrolysis of ethylene oxide in acid solution have been measured and the activation energies determined. From these data and from the ratio of glycol to chlorohydrin formed when ethylene oxide reacts with excess aqueous hydrogen halide, the rates of the acid-catalyzed addition of halide ions to ethylene oxide at 25 °C. have been estimated.

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