New catalysts for the aerobic selective oxidation of hydrocarbons: Mn(III)- and Co(III)-containing molecular sieves for the epoxidation of alkenes

1999 ◽  
pp. 829-830 ◽  
Author(s):  
Robert Raja ◽  
Gopinathan Sankar ◽  
John Meurig Thomas
Keyword(s):  
Selective Oxidation ◽  
Molecular Sieves ◽  
Oxidation Of Hydrocarbons ◽  
Epoxidation Of Alkenes

Selective Oxidation Of Hydrocarbons By Cobaltsubstituted Aluminophosphate Molecular Sieves

1991 ◽  
Vol 233 ◽  
Author(s):  
Victor A. Maroni ◽  
Lennox E. Iton
Keyword(s):  
Selective Oxidation ◽  
Radical Cation ◽  
Low Temperatures ◽  
Molecular Sieves ◽  
Inorganic Compounds ◽  
Observable Change ◽  
Aluminophosphate Molecular Sieves ◽  
Oxidation Of Hydrocarbons ◽  
Aldehydes And Ketones ◽  
Dimer Radical Cation

ABSTRACTThe Co(III) form of cobalt-substituted aluminophosphate molecular sieves, Co(III)-APOs, was found to be a selective oxidant for a variety of organic and inorganic compounds. At relatively low temperatures (20 to 100°C), alcohols are converted to aldehydes and ketones, benzene becomes a dimer radical cation, amines are transformed to imines, and NO is oxidized to NO+. There is also evidence that Co(III)APOs activate the C-H bonds of methane at higher temperatures (400–500°C). Accompanying all these reactions is a clearly observable change of color from the yellow of the Co(III) form to the blue of the Co(II) form.

ChemInform Abstract: Nanoaggregates of Simple Mn Porphyrin Complexes as Catalysts for the Selective Oxidation of Hydrocarbons.

ChemInform ◽  
2014 ◽  
Vol 45 (3) ◽  
pp. no-no
Author(s):  
Abdolreza Rezaeifard ◽  
Vahideh Soltani ◽  
Maasoumeh Jafarpour
Keyword(s):  
Selective Oxidation ◽  
Oxidation Of Hydrocarbons

scholarly journals Mesoporous MnCeOx solid solutions for low temperature and selective oxidation of hydrocarbons

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Pengfei Zhang ◽  
Hanfeng Lu ◽  
Ying Zhou ◽  
Li Zhang ◽  
Zili Wu ◽  
...  
Keyword(s):  
Low Temperature ◽  
Selective Oxidation ◽  
Solid Solutions ◽  
Oxidation Of Hydrocarbons

Heterogeneous epoxidation of alkenes with H2O2 catalyzed by a recyclable organic–inorganic polyoxometalate-based framework catalyst

2015 ◽  
Vol 39 (12) ◽  
pp. 9879-9885 ◽  
Author(s):  
Hedayat Haddadi ◽  
Shahrbanou Moradpour Hafshejani ◽  
Mostafa Riahi Farsani ◽  
Ali Kazemi Babahydari
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Stable Catalyst ◽  
Epoxidation Of Alkenes

PW-MOF as an efficient, recyclable and stable catalyst for the selective oxidation of alkenes with hydrogen peroxide.

Nickel Molybdate Catalysts and Their Use in the Selective Oxidation of Hydrocarbons

ChemInform ◽  
2004 ◽  
Vol 35 (34) ◽  
Author(s):  
L. M. Madeira ◽  
M. F. Portela ◽  
C. Mazzocchia
Keyword(s):  
Selective Oxidation ◽  
Nickel Molybdate ◽  
Oxidation Of Hydrocarbons
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