Synthesis and structural characterisation of the novel tetranuclear cluster compound [Pd4(µ-SO2)2(µ3-S)(CO)(PBz3)4] (Bz = C6H5CH2) †

1999 ◽  
pp. 653 ◽  
Author(s):  
Stephen V. Tarlton ◽  
Nick Choi ◽  
Mary McPartlin ◽  
D. Michael P. Mingos ◽  
Ramón Vilar
Keyword(s):  
Cluster Compound ◽  
The Novel ◽  
Tetranuclear Cluster ◽  
Structural Characterisation

Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (η5C5Me5)IrFe2(CO)9 / Synthesis and Molecular Structure of the Trinuclear Cluster Compound (η5-C5Me5)IrFe2(CO)9

1981 ◽  
Vol 36 (9) ◽  
pp. 1053-1059 ◽  
Author(s):  
Ernst Guggolz ◽  
Manfred L. Ziegler ◽  
Willibald Kalcher ◽  
Johann Plank ◽  
Doris Riedel ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Cluster Compound ◽  
The Novel ◽  
X Ray Diffraction ◽  
Sandwich Complex ◽  
X Ray ◽  
Trinuclear Cluster ◽  
Half Sandwich

Abstract Reaction of triirondodecacarbonyl (1) with the dinuclear chloroiridium complex [(η5 -C5Me5)Ir(μ-Cl)Cl]2 (2) in benzene at 50 °C yields the novel mixed iron iridium cluster of composition (η5 -C5Me5)IrFe2(CO)9 (8) the molecular structure of which has been established by X-ray diffraction methods. The mononuclear half-sandwich complex (η5 -C5Me5)Ir(CO)2 (4) present in the reaction mixture was found to represent the immediate precursor of the cluster compound 8.

Unexpected ligand substitutions in the cluster core {Re6Se8}: synthesis and structure of the novel cluster compound Cs11(H3O)[Re6Se4O4Cl6]3·4H2O

2005 ◽  
pp. 719-721 ◽  
Author(s):  
S. S. Yarovoi ◽  
Y. V. Mironov ◽  
S. F. Solodovnikov ◽  
D. Y. Naumov ◽  
N. K. Moroz ◽  
...  
Keyword(s):  
Cluster Core ◽  
Cluster Compound ◽  
The Novel

Displacement of benzene by an alkyne in a tetraosmium cluster; synthesis and structural characterisation of the novel cluster [H2Os4(CO)9(μ3-η2-Ph2C2)(η2-Ph2C2)]

1991 ◽  
Vol 405 (2) ◽  
pp. C22-C24 ◽  
Author(s):  
Hong Chen ◽  
Brian F.G. Johnson ◽  
Jack Lewis ◽  
Dario Braga ◽  
Fabrizia Grepioni ◽  
...  
Keyword(s):  
The Novel ◽  
Structural Characterisation
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