Chain length dependence of the mean field temperature in poly(oxyethylene)–poly(oxybutylene) diblock copolymers

1999 ◽  
Vol 1 (9) ◽  
pp. 2093-2095 ◽  
Author(s):  
J Patrick A. Fairclough ◽  
Anthony J. Ryan ◽  
Simon Turner ◽  
Ian W. Hamley ◽  
Shaomin Mai ◽  
...  
Langmuir ◽  
2014 ◽  
Vol 30 (12) ◽  
pp. 3319-3328 ◽  
Author(s):  
Arjun Ghosh ◽  
Shin-ichi Yusa ◽  
Hideki Matsuoka ◽  
Yoshiyuki Saruwatari

Author(s):  
Klaus Morawetz

The classical non-ideal gas shows that the two original concepts of the pressure based of the motion and the forces have eventually developed into drift and dissipation contributions. Collisions of realistic particles are nonlocal and non-instant. A collision delay characterizes the effective duration of collisions, and three displacements, describe its effective non-locality. Consequently, the scattering integral of kinetic equation is nonlocal and non-instant. The non-instant and nonlocal corrections to the scattering integral directly result in the virial corrections to the equation of state. The interaction of particles via long-range potential tails is approximated by a mean field which acts as an external field. The effect of the mean field on free particles is covered by the momentum drift. The effect of the mean field on the colliding pairs causes the momentum and the energy gains which enter the scattering integral and lead to an internal mechanism of energy conversion. The entropy production is shown and the nonequilibrium hydrodynamic equations are derived. Two concepts of quasiparticle, the spectral and the variational one, are explored with the help of the virial of forces.


1981 ◽  
Vol 36 (1) ◽  
pp. 62-67 ◽  
Author(s):  
F. Schneider ◽  
N. K. Sharma

The diagrams of state of mixtures of 4-n-alkyloxybenzylidene-4'-n-butylanilines with 4-n- alkyl- and 4-n-alkyloxy-4'-cyanobiphenyls are studied. The mixtures form induced smectic phases of type SA, SB and SE. In all three smectic phases the thickness of the smectic layers agrees with the mean values of the molecular lengths. In most cases the induced SA phases do not show uninterrupted miscibility with the SA phases of the pure components. For instance, the system 40 • 4/8 CBP exhibits three separate SA phase areas. The maximum transition temperatures of the induced smectic phases increase with increasing chain length of the azomethines, but remain constant in case of the SA and SB phases or even decrease in case of the SE phases with increasing chain length of the cyanobiphenyls


2000 ◽  
Vol 61 (17) ◽  
pp. 11521-11528 ◽  
Author(s):  
Sergio A. Cannas ◽  
A. C. N. de Magalhães ◽  
Francisco A. Tamarit

2019 ◽  
Vol 46 (3) ◽  
pp. 54-55
Author(s):  
Thirupathaiah Vasantam ◽  
Arpan Mukhopadhyay ◽  
Ravi R. Mazumdar

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