Cationic alkyl aluminium ethylene polymerization catalysts based on monoanionic N,N,N-pyridyliminoamide ligands

1998 ◽  
pp. 2523-2524 ◽  
Author(s):  
Michael Bruce ◽  
Vernon C. Gibson ◽  
Carl Redshaw ◽  
Gregory A. Solan ◽  
Andrew J. P. White ◽  
...  
Keyword(s):  
Ethylene Polymerization ◽  
Polymerization Catalysts

Doubly fused N,N,N-Iron Ethylene Polymerization Catalysts appended with Fluoride Substituents; probing catalytic performance via a combined experimental and MLR study

2021 ◽  
Author(s):  
Qiuyue Zhang ◽  
Wenhong Yang ◽  
Zheng Wang ◽  
Gregory A. Solan ◽  
Tongling Liang ◽  
...  
Keyword(s):  
Ethylene Polymerization ◽  
Catalytic Performance ◽  
Chloride Complex ◽  
Polymerization Catalysts

Access to six examples of α,α’-bis(imino)-2,3:5,6-bis(pentamethylene)pyridine-iron(II) chloride complex, [2,3:5,6-{C4H8C(N(2-R1-4-R3-6-R2C6H2)}2C5HN] (R1 = Me, R2 = R3 = CH(p-FPh)2 Fe1; R1 = Et, R2 = R3 = CH(p-FPh)2 Fe2; R1 = iPr,...

scholarly journals Chromium ethylene polymerization catalysts bearing sterically enhanced α,α′-bis(imino)-2,3:5,6-bis(pentamethylene)pyridines: Tuning activity and molecular weight

Polymer ◽  
2019 ◽  
Vol 171 ◽  
pp. 87-95 ◽  
Author(s):  
Chantsalnyam Bariashir ◽  
Zheng Wang ◽  
Gregory A. Solan ◽  
Chuanbing Huang ◽  
Xiang Hao ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Ethylene Polymerization ◽  
Polymerization Catalysts

scholarly journals NMR and EPR trapping of the active species in the ethylene polymerization and trimerization catalyst systems

2016 ◽  
Vol 3 (1) ◽  
Author(s):  
I.E. Soshnikov ◽  
N.V. Semikolenova ◽  
A.A. Antonov ◽  
K.P. Bryliakov ◽  
V.A. Zakharov ◽  
...  
Keyword(s):  
Epr Spectroscopy ◽  
Ethylene Polymerization ◽  
Catalyst Deactivation ◽  
Active Species ◽  
Ion Pair ◽  
Polymerization Catalysts ◽  
Ethylene Trimerization ◽  
Catalyst Systems

AbstractIn this work, previously undetected intermediates of several practically promising catalyst systems for ethylene polymerization and trimerization are discussed. In particular, the activation of ethylene polymerization catalysts (1) LNiCl2 (L = 2,4,6-trimethyl- (N-5,6,7-trihydroquinolin-8-ylidene)phenylamine) with AlEt2Cl and AlMe2Cl, (2) activation of bis(imino)pyridine vanadium(III) chloride L1VIIICl3 (L1 = 2,6-(ArN=CMe)2C5H3N, Ar = 2,6-iPr2C6H3; 2,6-Me2C6H3; 2,4,6-Me3C6H2; 3,5- F2C6H3) with AlMe3/[Ph3C]+[B(C6F5)]4¯ and MAO, and (3) selective ethylene trimerization catalyst (FI)TiCl3 (FI = phenoxyimine ligand with an additional aryl-OCH3 donor) with MAO have been assessed by NMR and EPR spectroscopy. The nature of ion-pair intermediates – the closest precursors of the propagating species – has been established, and the major catalyst deactivation pathways are discussed.

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