Gas-phase formation of zinc/cadmium chalcogenide cluster complexes and their solid-state thermal decomposition to form II-VI nanoparticulate material

1998 ◽  
Vol 8 (12) ◽  
pp. 2769-2776 ◽  
Author(s):  
Nigel L. Pickett ◽  
Steven Lawson ◽  
W. Gregor Thomas ◽  
Frank G. Riddell ◽  
Douglas F. Foster ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Solid State ◽  
Gas Phase ◽  
Phase Formation ◽  
Cluster Complexes ◽  
Cadmium Chalcogenide ◽  
Zinc Cadmium

Corrigendum to: Valence Bond Formulations of Mechanisms for the Formation and Decomposition of N2O5

2006 ◽  
Vol 3 (6) ◽  
pp. 457 ◽  
Author(s):  
Richard D. Harcourt ◽  
Thomas M. Klapötke
Keyword(s):  
Thermal Decomposition ◽  
Gas Phase ◽  
Phase Formation ◽  
Electronic Structures ◽  
Electron Pair ◽  
Valence Bond ◽  
Pair Bonds ◽  
Normal Electron ◽  
Stratospheric Clouds ◽  
Increased Valence

Environmental Context. N2O5 is an important nitrogen reservoir in polar stratospheric clouds found in Antarctica and involved with the ozone hole. Here we provide valence bond representations for the gas-phase formation and decomposition of this molecule. Abstract. Qualitative valence bond considerations are used to suggest how electronic reorganization could proceed for (a) the formation of N2O5 via the reactions NO2 + O3 → NO3 + O2, and NO2 + NO3 → N2O5, and (b) the thermal decomposition of N2O5 via the following sets of reactions: (i) N2O5 → NO2 + NO3, 2NO3 → O2NOONO2 → 2NO2 + O2; (ii) NO2 + NO3 → ONOONO2 → NO + O2 + NO2, NO + NO3 → 2NO2. Increased-valence structures, which possess one-electron bonds and fractional electron-pair bonds as well as 'normal' electron-pair bonds, are used to represent the electronic structures of the molecules.

Valence Bond Formulations of Mechanisms for the Formation and Decomposition of N2O5

2006 ◽  
Vol 3 (5) ◽  
pp. 355 ◽  
Author(s):  
Richard D. Harcourt ◽  
Thomas M. Klapötke
Keyword(s):  
Thermal Decomposition ◽  
Gas Phase ◽  
Phase Formation ◽  
Electronic Structures ◽  
Electron Pair ◽  
Valence Bond ◽  
Pair Bonds ◽  
Normal Electron ◽  
Stratospheric Clouds ◽  
Increased Valence

Environmental Context. N2O5 is an important nitrogen reservoir in polar stratospheric clouds found in Antarctica and involved with the ozone hole. Here we provide valence bond representations for the gas-phase formation and decomposition of this molecule. Abstract. Qualitative valence bond considerations are used to suggest how electronic reorganization could proceed for (a) the formation of N2O5 via the reactions NO2 + O3 → NO3 + O2, and NO2 + NO3 → N2O5, and (b) the thermal decomposition of N2O5 via the following sets of reactions: (i) N2O5 → NO2 + NO3, 2NO3 → O2NOONO2 →2NO2 + O2; (ii) NO2 + NO3 → ONOONO2 → NO + O2 + NO2, NO + NO3 → 2NO2. Increased-valence structures, which possess one-electron bonds and fractional electron-pair bonds as well as ‘normal’ electron-pair bonds, are used to represent the electronic structures of the molecules.

Heterometallic molecular precursors for a lithium–iron oxide material: synthesis, solid state structure, solution and gas-phase behaviour, and thermal decomposition

2017 ◽  
Vol 46 (17) ◽  
pp. 5644-5649 ◽  
Author(s):  
Haixiang Han ◽  
Zheng Wei ◽  
Matthew C. Barry ◽  
Alexander S. Filatov ◽  
Evgeny V. Dikarev
Keyword(s):  
Thermal Decomposition ◽  
Solid State ◽  
Gas Phase ◽  
Phase Behaviour ◽  
Oxide Material ◽  
Single Source ◽  
State Structure ◽  
Material Synthesis ◽  
Molecular Precursors ◽  
Structure Solution

Heterometallic single-source precursors with the appropriate Li : Fe ratio were shown to yield the target LiFeO2 cathode material upon thermal decomposition.

On the trustability of semi-empirical methods to the calculation of gas phase formation enthalpies of inorganic compounds containing heavy metals: tin borates

2017 ◽  
Author(s):  
Robson de Farias
Keyword(s):  
Heavy Metals ◽  
Gas Phase ◽  
Phase Formation ◽  
Inorganic Compounds ◽  
Formation Enthalpy ◽  
Computational Time ◽  
Gas Formation ◽  
Formation Enthalpies ◽  
Knudsen Effusion Mass Spectrometry ◽  
Semi Empirical

<p>In the present work, are calculated the gas formation enthalpies (SE; PM3 and PM6) for tin borates: SnB<sub>2</sub>O<sub>4</sub><sup> </sup>and Sn<sub>2</sub>B<sub>2</sub>O<sub>5</sub>. The calculated values are compared with experimental ones, obtained by Knudsen effusion mass spectrometry [3]. It is shown that SE methods, besides their lower computational time consuming can, indeed, provide reliable gas phase formation enthalpy values for inorganic compounds containing heavy metals.</p>

Peculiarities of Intermetallic Phase Formation in the Process of a Solid State Reaction in (Al/Cu)n Multilayer Thin Films

JOM ◽  
2021 ◽  
Author(s):  
Evgeny T. Moiseenko ◽  
Sergey M. Zharkov ◽  
Roman R. Altunin ◽  
Oleg V. Belousov ◽  
Leonid A. Solovyov ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Phase Formation ◽  
Solid State Reaction ◽  
Intermetallic Phase ◽  
Multilayer Thin Films

Gas-Phase Formation of the Gomberg-Bachmann Magnesium Ketyl

2008 ◽  
Vol 47 (47) ◽  
pp. 9118-9121 ◽  
Author(s):  
Charlene C. L. Thum ◽  
George N. Khairallah ◽  
Richard A. J. O'Hair
Keyword(s):  
Gas Phase ◽  
Phase Formation

Spontaneous Generation of Stable Pnictinyl Radicals from “Jack-in-the-Box” Dipnictines:  A Solid-State, Gas-Phase, and Theoretical Investigation of the Origins of Steric Stabilization1

2001 ◽  
Vol 123 (37) ◽  
pp. 9045-9053 ◽  
Author(s):  
Sarah L. Hinchley ◽  
Carole A. Morrison ◽  
David W. H. Rankin ◽  
Charles L. B. Macdonald ◽  
Robert J. Wiacek ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Theoretical Investigation ◽  
Spontaneous Generation

Intramolecular London Dispersion Interaction Effects on Gas-Phase and Solid-State Structures of Diamondoid Dimers

2017 ◽  
Vol 139 (46) ◽  
pp. 16696-16707 ◽  
Author(s):  
Andrey A. Fokin ◽  
Tatyana S. Zhuk ◽  
Sebastian Blomeyer ◽  
Cristóbal Pérez ◽  
Lesya V. Chernish ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Interaction Effects ◽  
Dispersion Interaction ◽  
London Dispersion ◽  
Solid State Structures
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