Solvent effects on the stability of simple secondary amides †

Author(s):  
Kathleen M. Morgan ◽  
Daniel A. Kopp
1970 ◽  
Vol 48 (14) ◽  
pp. 2197-2203 ◽  
Author(s):  
A. Foldes ◽  
C. Sandorfy

The influence of solvent effects and hydrogen bond formation on the anharmonicity of the NH stretching vibration of simple secondary amides, lactams, anilides, indole, pyrrole, and imidazole have been studied; and the frequencies of the first and second overtones, their half widths and solvent shifts measured. The validity of Buckingham's theory is established in the case of inert solvents; whereas the second order perturbation treatments are shown to be inapplicable to the case of hydrogen bonding solvents. All NH stretching modes seem to exhibit the same anharmonic behavior which is very different from that of OH vibrations.


Biochemistry ◽  
1985 ◽  
Vol 24 (8) ◽  
pp. 2086-2094 ◽  
Author(s):  
David R. Hickey ◽  
Douglas H. Turner

2021 ◽  
Vol 933 ◽  
pp. 121632
Author(s):  
Dongling Zhong ◽  
Yueru Ying ◽  
Mingliang Gui ◽  
Cong Wang ◽  
Hua Zhong ◽  
...  

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