Chemistry of ruthenium(II) complexes of N-substituted 1,2-benzoquinone diimines. Synthesis, structure and redox properties ‡

1998 ◽  
pp. 2901-2906 ◽  
Author(s):  
Kedar Nath Mitra ◽  
Subrata Choudhury ◽  
Alfonso Castiñeiras ◽  
Sreebrata Goswami
Keyword(s):  
Redox Properties ◽  
Benzoquinone Diimines

Polymer oxidation catalyst containing acidic functional groups

1981 ◽  
Vol 46 (5) ◽  
pp. 1237-1247
Author(s):  
Zdeněk Prokop ◽  
Karel Setínek
Keyword(s):  
Functional Groups ◽  
Elevated Temperatures ◽  
Redox Properties ◽  
Oxidation Catalyst ◽  
Carbon Clusters ◽  
Oxidation Activity ◽  
Redox Sites ◽  
Styrene Divinylbenzene ◽  
Proportional Decrease ◽  
Polymer Oxidation

The catalyst containing redox sites in addition to acid functional groups was prepared by sulphonation of a macroporous chloromethylated styrene-divinylbenzene copolymer with concentrated sulphuric acid at elevated temperatures. Its activity was tested for the oxidation of 2-propanol by molecular oxygen at 120 °C and was found to be comparable to that of the iridium on carbon catalyst.Neutralisation of acid functional groups by alkali metal led to proportional decrease in the oxidation activity. The results of EPR spectroscopic study of these catalysts show that the redox properties of the polymer are caused by carbon clusters which are capable of electron exchange.

Solvation and redox properties of [Co(en)3]3+-[Co(en)3]2+ system

1980 ◽  
Vol 45 (2) ◽  
pp. 335-338 ◽  
Author(s):  
Adéla Kotočová ◽  
Ulrich Mayer
Keyword(s):  
Hydrogen Bond ◽  
Lewis Acid ◽  
Specific Interaction ◽  
Redox Properties ◽  
Solvation Effect ◽  
Interacting Particles ◽  
Acid Base ◽  
Polar Solvents ◽  
Oxidation Reduction ◽  
Solvent Molecules

The solvation effect of a number of nonaqueous polar solvents was studied on the oxidation-reduction properties of the [Co(en)3]3+-[Co(en)3]2+ system. Interactions of these ions with the solvent molecules are discussed in terms of their coordination, which is accompanied by a specific interaction of the Lewis acid-base type, namely formation of a hydrogen bond between the interacting particles. This is the main controlling factor of the redox properties of the studied system.

Influence of Metal Core Composition on Redox Properties and Photoreactivity of the Clusters [H4-xRu4-xRhx(CO)12] (x = 0, 2, 3, 4)

2001 ◽  
Vol 66 (7) ◽  
pp. 1062-1077 ◽  
Author(s):  
Maarten J. Bakker ◽  
Tapani A. Pakkanen ◽  
František Hartl
Keyword(s):  
Electrochemical Properties ◽  
Electrochemical Reduction ◽  
Redox Properties ◽  
Metal Core ◽  
Loss Product ◽  
Condensation Reactions ◽  
Core Composition ◽  
Co Dissociation ◽  
Major Reduction

Electrochemical properties of tetrahedral clusters [H2Ru2Rh2(CO)12], [HRuRh3(CO)12] and [Rh4(CO)12] were investigated in order to evaluate the influence of metal core composition in the series [H4-xRu4-xRhx(CO)12] (x = 0-4). The cluster [H3Ru3Rh(CO)12] was not available in sufficient quantities. As reported for [H4Ru4(CO)12], electrochemical reduction of the hydride-containing clusters [H2Ru2Rh2(CO)12] and [HRuRh3(CO)12] also results in (stepwise) loss of hydrogen, producing the anions [HRu2Rh2(CO)12]-, [Ru2Rh2(CO)12]2- and [RuRh3(CO)12]-. These anions can also be prepared from the neutral parent clusters via chemical routes. Electrochemical reduction of [Rh4(CO)12] does not result in the formation of any stable tetranuclear anion. Instead, [Rh5(CO)15]- and [Rh6(CO)15]2- are the major reduction products detected in the course of IR spectroelectrochemical experiments. Most likely, these cluster species are formed from the secondary CO-loss product [Rh4(CO)11]2- by fast redox condensation reactions. Their reoxidation regenerates parent [Rh4(CO)12], together with some [Rh6(CO)16]. Unlike [H4Ru4(CO)12] that undergoes photochemical CO-dissociation, [H2Ru2Rh2(CO)12] and [Rh4(CO)12] are completely photostable in neat hexane and dichloromethane as well as in the presence of oct-1-ene.

Nonoxido Vanadium(IV) Compounds Involving Dithiocarbazate-Based Tridentate ONS Ligands: Synthesis, Electronic and Molecular Structure, Spectroscopic and Redox Properties

2015 ◽  
Vol 54 (13) ◽  
pp. 6203-6215 ◽  
Author(s):  
Sanchita Kundu ◽  
Dhrubajyoti Mondal ◽  
Kisholoy Bhattacharya ◽  
Akira Endo ◽  
Daniele Sanna ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Redox Properties

Redox properties and evolution of human glutaredoxins

2007 ◽  
Vol 68 (4) ◽  
pp. 879-892 ◽  
Author(s):  
Johan Sagemark ◽  
Tobias H. Elgán ◽  
Thomas R. Bürglin ◽  
Catrine Johansson ◽  
Arne Holmgren ◽  
...  
Keyword(s):  
Redox Properties

Effect of PM characterization on PM oxidative potential by acellular assays: a review

2020 ◽  
Vol 35 (4) ◽  
pp. 461-470
Author(s):  
Huibin Guo ◽  
Lei Jin ◽  
Sijing Huang
Keyword(s):  
Lung Cancer ◽  
Ascorbic Acid ◽  
Health Risks ◽  
Measurement Techniques ◽  
Measurement Methods ◽  
Redox Properties ◽  
Oxidative Potential ◽  
Cellular Assays ◽  
Copper Manganese ◽  
Risk Ratios

AbstractThe health risks brought by particles cannot be present via a sole parameter. Instead, the particulate matter oxidative potential (PM OP), which expresses combined redox properties of particles, is used as an integrated metric to assess associated hazards and particle-induced health effects. OP definition provides the capacity of PM toward target oxidation. The latest technologies of a cellular OP measurement has been growing in relevant studies. In this review, OP measurement techniques are focused on discussing along with PM characterization because of many related studies via OP measurements investigating relationship with human health. Many OP measurement methods, such as dithiothreitol (DTT), ascorbic acid (AA), glutathione (GSH) assay and other a cellular assays, are used to study the association between PM toxicity and PM characterization that make different responses, including PM components, size and sources. Briefly, AA and DTT assays are sensitive to metals (such as copper, manganese and iron etc.) and organics (quinones, VOCs and PAH). Measured OP have significant association with certain PM-related end points, for example, lung cancer, COPD and asthma. Literature has found that exposure to measured OP has higher risk ratios than sole PM mass, which may be containing the PM health-relevant fraction. PM characterization effect on health via OP measurement display a promising method.

scholarly journals Cationic Bismuth Aminotroponiminates: Charge Controls Redox Properties

2020 ◽  
Author(s):  
Anna Hanft ◽  
Krzysztof Radacki ◽  
Crispin Lichtenberg
Keyword(s):  
Redox Properties
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