Microwave Enhanced Hydrogenation Reactions using Solid Hydrogen, Deuterium and Tritium Donors

1998 ◽  
pp. 400-401 ◽  
Author(s):  
Mohammed H. Al-Qahtani ◽  
Nicola Cleator ◽  
Timothy N. Danks ◽  
Russell N. Garman ◽  
John R. Jones ◽  
...  
Keyword(s):  
Solid Hydrogen ◽  
Hydrogenation Reactions ◽  
Hydrogen Deuterium

Muon molecular formation and transfer rate in solid hydrogen-deuterium mixtures

1996 ◽  
Vol 101-102 (1) ◽  
pp. 239-248 ◽  
Author(s):  
R. Jacot-Guillarmod ◽  
J. M. Bailey ◽  
G. A. Beer ◽  
J. L. Beveridge ◽  
M. C. Fujiwara ◽  
...  
Keyword(s):  
Transfer Rate ◽  
Solid Hydrogen ◽  
Molecular Formation ◽  
Hydrogen Deuterium

Catalytic Hydrogenation with Amorphous and Crystalline Pd8 0Si2 0

1981 ◽  
Vol 8 ◽  
Author(s):  
Bill C. Giessen ◽  
Sabri S. Mahmoud ◽  
David A. Forsyth ◽  
Markus Hediger
Keyword(s):  
Double Bond ◽  
Catalytic Hydrogenation ◽  
Metallic Glasses ◽  
Hydrogen Deuterium Exchange ◽  
Reaction Conditions ◽  
Crystalline Phases ◽  
Hydrogenation Catalysts ◽  
Double Bond Migration ◽  
Hydrogenation Reactions ◽  
Hydrogen Deuterium

ABSTRACTSeveral metallic glasses in the form of ribbons were screened for activity as hydrogenation catalysts. Pd80Si20 and (Ni50Fe50)80B20 showed activity in reducing cyclohexene. Pd 80 Si20 was further examined for differences between the glassy and crystalline phases in the selectivity shown during hydrogenation reactions of n-hexenes, phenylethyne, α-pinene, and cyclododecene. No significant differences were found for catalytic selectivity in regard to cis-trans isomerization, double bond migration, and stereochemistry of addition under the reaction conditions used. Minor differences were observed in hydrogen-deuterium exchange.

scholarly journals Dynamical effects in solid hydrogen and hydrogen-deuterium mixtures at elevated pressures.

2014 ◽  
Vol 70 (a1) ◽  
pp. C899-C899
Author(s):  
Ioan Magdau ◽  
Ross Howie ◽  
Graeme Ackland ◽  
Eugene Gregoryanz
Keyword(s):  
Raman Spectra ◽  
High Pressures ◽  
Elevated Temperatures ◽  
Melting Curve ◽  
Solid Hydrogen ◽  
Raman Signal ◽  
True Nature ◽  
Point Energy ◽  
Hydrogen Deuterium ◽  
Phase Iv

We employed molecular dynamics simulations together with some novel theoretical techniques to calculate finite temperature Raman spectra in both hydrogen (H) and hydrogen-deuterium (HD) mixtures. By conditioning the simulations with the experimental data, we have discovered the true nature of Phase IV in solid hydrogen. X-ray and neutron diffraction measurements are virtually impossible in current state of the art experiments. The experimental investigation, thus, relies mainly on spectroscopic methods which provide minimal data about crystallography. Extensive work done so far [1] has led to an impressive amount of Raman and IR data up to pressures of almost 400 GPa. By carefully investigating the positions and widths of the peaks, they discovered phase IV of solid hydrogen and mapped out the melting curve up to very high pressures. Phase IV is only stable at elevated temperatures and therefore static relaxation calculations cannot reproduce the correct crystal structure. Previous theoretical work has predicted a class of exotic crystal structures with alternating layers of different character: B (well-defined molecules) and G (poorly-defined molecules) [2] that could qualitatively describe the Raman signal. By means of MD simulations we show that at high temperature, the Pc structure acquires higher symmetry which is sufficient to reproduce the exact position of the Raman peaks. It had been suggested that in a mixed hydrogen-deuterium alloy, the heavier atoms would segregate in the B layers which would decrease the overall zero-point energy and stabilise the Pc structure. Joining efforts with the experimental team we thoroughly investigated this problem. We found no evidence of isotopic layer segregation, but our theoretical model correctly described the Raman spectra found experimentally. We concluded that the phase boundaries in HD mixtures are slightly offset which we attribute to the inhomogeneous mass effect on the temperature of the broken symmetries, but the general behaviour is similar to that of solid hydrogen. We uncovered a new effect in HD, namely mass induced phonon localization. Matching experimental and theoretical results in this respect are yet another validation of the crystallographic conformation of phase IV.

Dynamic shear stress and heat transfer of solid hydrogen, deuterium, and neon

2012 ◽  
Vol 111 (8) ◽  
pp. 083513 ◽  
Author(s):  
Jacob Leachman ◽  
John Pfotenhauer ◽  
Greg Nellis
Keyword(s):  
Heat Transfer ◽  
Shear Stress ◽  
Solid Hydrogen ◽  
Dynamic Shear ◽  
Hydrogen Deuterium

The Raman spectrum of solid hydrogen

1965 ◽  
Vol 26 (11) ◽  
pp. 615-620 ◽  
Author(s):  
E.J. Allin ◽  
A.H. M ◽  
V. Soots ◽  
H.L. Welsh
Keyword(s):  
Raman Spectrum ◽  
Solid Hydrogen

Orientational ordering in solid hydrogen

1976 ◽  
Vol 37 (7-8) ◽  
pp. 981-989 ◽  
Author(s):  
N.S. Sullivan
Keyword(s):  
Solid Hydrogen ◽  
Orientational Ordering
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