Sensitive End-point Detection for Potentiometric Titration of Cationic Polyelectrolytes Using Marker Cation and Marker Cation-selective Electrodes

1997 ◽  
Vol 34 (9) ◽  
pp. 257-259 ◽  
Author(s):  
Takashi Masadome ◽  
Toshihiko Imato
2007 ◽  
Vol 9 (1) ◽  
pp. 33-35
Author(s):  
Barbara Sołtysik

A quick method to determine the content of sulfates in silicic and aluminosilicate fillers The paper presents the possibility of using barium-selective electrode to a potentiometric determination of sulfates in silicic and aluminosilicate fillers. The results of sulfates potentiometric titration in silicic and aluminosilicate fillers are described. A statistical interpretation of the results was carried out. The recommended method is based on the end-point detection of sulfates potentiometric titration in hydro-alcoholic medium by means of barium chlorate(VII) titrant. The potentiometric titration, which uses an ion-selective electrode as the indicator for the end-point was applied as the analytical technique. The parameter ranges for accurate sulfates determination in model solutions and the method of samples' preparation for analysis were investigated.


2009 ◽  
Author(s):  
M. Jakubowska ◽  
B. Baś ◽  
E. Niewiara ◽  
W. Reczyński ◽  
W. W. Kubiak ◽  
...  

Talanta ◽  
2009 ◽  
Vol 79 (5) ◽  
pp. 1398-1405 ◽  
Author(s):  
Małgorzata Jakubowska ◽  
Bogusław Baś ◽  
Władysław W. Kubiak

Talanta ◽  
2021 ◽  
Vol 224 ◽  
pp. 121735
Author(s):  
Claudio Avila ◽  
Christos Mantzaridis ◽  
Joan Ferré ◽  
Rodrigo Rocha de Oliveira ◽  
Uula Kantojärvi ◽  
...  

1979 ◽  
Vol 25 (6) ◽  
pp. 973-975 ◽  
Author(s):  
T Chard ◽  
A Sykes

Abstract We describe an immunoassay for human choriomammo-tropin by use of the fluorescein-labeled hormone (of human origin). The technique is generally similar to the radioimmunoassay for this material, but has the advantage of stability of tracer and avoidance of radiation hazard. However, the procedure requires approximately 50-fold more tracer than does the radioimmunoassay, and this would be a disadvantage with materials for which supplies of purified antigen are scarce. Furthermore, both within-assay variation (3.9%) and between-assay variation (7.8--7.9%) were less satisfactory than that of radioimmunoassay (1.5% and 2.2--3%, respectively). This is almost certainly the result of imprecision of end-point detection and could probably be corrected by further attention to equipment design.


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