Carbon dioxide activation: synthesis and characterization of a cadmium(ii) dinuclear complex with a novel μ-carbonato bridge

1997 ◽  
pp. 1307-1308 ◽  
Author(s):  
Chandi Pariya ◽  
Vedavati G. Puranik ◽  
Nirmalendu Ray Chaudhuri
Keyword(s):  
Carbon Dioxide ◽  
Dinuclear Complex ◽  
Synthesis And Characterization ◽  
Carbon Dioxide Activation

Synthesis and Characterization of a Composite Zeolite-Metglas Carbon Dioxide Sensor

2005 ◽  
Vol 15 (7) ◽  
pp. 1165-1170 ◽  
Author(s):  
I. G. Giannakopoulos ◽  
D. Kouzoudis ◽  
C. A. Grimes ◽  
V. Nikolakis
Keyword(s):  
Carbon Dioxide ◽  
Synthesis And Characterization ◽  
Carbon Dioxide Sensor

Synthesis and characterization of clathrate hydrates containing carbon dioxide and ethanol

2010 ◽  
Vol 12 (33) ◽  
pp. 9927 ◽  
Author(s):  
Takeshi Makiya ◽  
Takashi Murakami ◽  
Satoshi Takeya ◽  
Amadeu K. Sum ◽  
Saman Alavi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Clathrate Hydrates ◽  
Synthesis And Characterization

Synthesis and characterization of a structure H hydrate formed with carbon dioxide and 3,3-dimethyl-2-butanone

2013 ◽  
Vol 49 (5) ◽  
pp. 505-507 ◽  
Author(s):  
Kyoichi Tezuka ◽  
Renkai Shen ◽  
Taku Watanabe ◽  
Satoshi Takeya ◽  
Saman Alavi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Synthesis And Characterization

Synthesis and characterization of novel polysiloxane-grafted fluoropolymers

2005 ◽  
Vol 83 (6-7) ◽  
pp. 553-558 ◽  
Author(s):  
Bilal Baradie ◽  
Patricia HM Lai ◽  
Molly S Shoichet
Keyword(s):  
Carbon Dioxide ◽  
Thermal Stability ◽  
Supercritical Carbon Dioxide ◽  
Vinyl Acetate ◽  
Vinyl Alcohol ◽  
Contact Angles ◽  
Synthesis And Characterization ◽  
Water Contact ◽  
Degradation Temperature

Fluorosilicone polymers combine the properties of both fluorocarbons and siloxanes, yielding materials with unique properties. Novel crosslinked fluorosilicone polymers were synthesized by grafting diisocyanate-terminated polydimethylsiloxane (PDMS) to hydroxyl-functionalized fluoropolymers of poly(tetrafluoroethylene-co-vinyl acetate-co-vinyl alcohol) (PTFE-VAc-VA), as confirmed by elemental bulk and surface analysis. The fluorosilicone polymers containing 34 mol% of TFE were thermally stable with a degradation temperature of 267 °C. Fluorosilicone films were found to be more hydrophobic than the parent, non-grafted fluoropolymers; dynamic advancing and receding water contact angles for PTFE-co-VAc-co-VA-g-PDMS were 104° ± 1° and 61° ± 1°, respectively, whereas for PTFE-co-VAc they were 90° ± 2° and 59° ± 2°. The combined properties of thermal stability and hydrophobicity suggest that these fluorosilicones may be useful for coating and paint applications.Key words: fluoropolymers, fluorosilicone, polydimethylsiloxane, supercritical carbon dioxide.

Synthesis and characterization of ZnO/PET composite using supercritical carbon dioxide impregnation technology

2011 ◽  
Vol 42 (7) ◽  
pp. 757-761 ◽  
Author(s):  
Marcos R. Mauricio ◽  
Fernando C.G. Manso ◽  
Marcos H. Kunita ◽  
Daniel S. Velasco ◽  
Antonio C. Bento ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Synthesis And Characterization ◽  
Supercritical Carbon

scholarly journals Synthesis and characterization of ceria-supported catalysts for carbon dioxide transformation to diethyl carbonate

2018 ◽  
Vol 306 ◽  
pp. 128-137 ◽  
Author(s):  
Ewelina Leino ◽  
Narendra Kumar ◽  
Päivi Mäki-Arvela ◽  
Anne-Riikka Rautio ◽  
Johnny Dahl ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supported Catalysts ◽  
Synthesis And Characterization ◽  
Diethyl Carbonate

scholarly journals Synthesis and Characterization of New Cyclam-Based Zr(IV) Alkoxido Derivatives

Reactions ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 323-332
Author(s):  
Luis G. Alves ◽  
Ana M. Martins
Keyword(s):  
Carbon Dioxide ◽  
Solid State ◽  
Molecular Structures ◽  
Synthesis And Characterization ◽  
Metal Centers ◽  
Trigonal Prismatic

In this study, new mono- and di-alkoxido zirconium(IV) complexes supported by tetradentate dianionic cyclam ligands were synthesized and characterized. These compounds were obtained by reaction of the parent Zr(IV) dichlorido species with one or two equivalents of the corresponding lithium alkoxido, whereas (3,5-Me2Bn2Cyclam)Zr(OPh)2 was prepared by protonolysis of the orthometallated species (3,5-Me-C6H4CH2)2Cyclam)Zr with phenol. The solid-state molecular structures of (Bn2Cyclam)ZrCl(OtBu) and (4-tBuBn2Cyclam)Zr(OiPr)2 show a trigonal prismatic geometry around the metal centers. (Bn2Cyclam)Zr(SPh)(OtBu) and (Bn2Cyclam)ZrMe(OiPr) were prepared by reaction of (Bn2Cyclam)ZrCl(OR) (R = iPr, tBu) with one equivalent of LiSPh or MeMgCl, respectively. The reactions of (Bn2Cyclam)Zr(OiPr)2 and (4-tBuBn2Cyclam)Zr(OiPr)2 with carbon dioxide suggested the formation of species that correspond to the addition of four CO2 molecules.

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