scholarly journals Catalytic oxidation of methane to methyl hydroperoxide and other oxygenates under mild conditions

1997 ◽  
pp. 397-398 ◽  
Author(s):  
Galina V. Nizova ◽  
Georg Süss-Fink ◽  
Georgiy B. Shul’pin
Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 944
Author(s):  
Anil C. Banerjee

Methane (the major component of natural gas) is one of the main energy sources for gas-powered turbines for power generation, and transport vehicles [...]


1998 ◽  
Vol 76 (10) ◽  
pp. 1467-1473 ◽  
Author(s):  
Veranja Karunaratne ◽  
David Dolphin

A variety of substituted 2-methylpyrroles (3-8) were oxidized using the metalloporphyrin catalysts iron(III) meso-tetra(2,6-dichloro-3-sulphonatophenyl)-β-octachloroporphyrin chloride 1 and iron(III) meso-tetra(2,6-dichlorophenyl)-β-octachloroporphyrin chloride 2 under very mild conditions. Treatment of the resulting allylic alcohols 3a-8a with α-free pyrroles 9 and 10 resulted in a very efficient synthesis of the corresponding dipyrromethanes 3b-8b and 3c-8c. Furthermore, the above allylic alcohols when treated with furfurylamine produced the novel (2-furylmethyl)-2-pyrrolylmethylamines 3d-8d.Key words: catalytic oxidation, metalloporphyrins, pyrroles, dipyrromethanes, polyhalogenated porphyrins.


2012 ◽  
Vol 2012 ◽  
pp. 1-10
Author(s):  
Misal Giuseppe Memeo ◽  
Mariella Mella ◽  
Paolo Quadrelli

Isoxazolineγ-lactams are prepared starting from the regioisomeric cycloadducts of benzonitrile oxide to theN-alkyl 2-azanorbornenes taking advantage of the efficient catalytic oxidation by RuO4. The reduction of the amide groups is easily conducted in the presence of LiAlH4under mild conditions, which allowed for the chemoselective reduction of the amide moiety followed by ring opening to afford the desired conformationally locked isoxazoline-carbocyclic aminols, as valuable intermediates for nucleoside synthesis.


ChemInform ◽  
2006 ◽  
Vol 37 (15) ◽  
Author(s):  
Qiao-xiang Kang ◽  
Ju-jie Luo ◽  
Yan-bin Bai ◽  
Zhi-wang Yang ◽  
Zi-qiang Lei

2018 ◽  
Vol 9 (33) ◽  
pp. 6765-6773 ◽  
Author(s):  
Ágnes Szécsényi ◽  
Guanna Li ◽  
Jorge Gascon ◽  
Evgeny A. Pidko

Reaction paths underlying the catalytic oxidation of methane with H2O2 over an Fe containing MIL-53(Al) metal–organic framework were studied by periodic DFT calculations.


Fuel ◽  
2020 ◽  
Vol 260 ◽  
pp. 116200 ◽  
Author(s):  
Hui Liu ◽  
Huanhuan Xu ◽  
Mingqing Hua ◽  
LinLin Chen ◽  
Yanchen Wei ◽  
...  

2020 ◽  
Vol 487 ◽  
pp. 110886 ◽  
Author(s):  
Mauro Álvarez ◽  
Pablo Marín ◽  
Salvador Ordóñez

2013 ◽  
Vol 160 (1) ◽  
pp. 149-154 ◽  
Author(s):  
Taichang Zhang ◽  
Yuxuan Xin ◽  
Zhuyin Ren ◽  
Fei Qi ◽  
Chung K. Law

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