4-tert-Butylcalix[4]arene tetrahydroxamate chelators for the selective extraction of actinide ions: synthesis and preliminary metal ion extraction studies 1

Author(s):  
Lakkaraju Dasaradhi ◽  
Peter C. Stark ◽  
Vincent J. Huber ◽  
Paul H. Smith ◽  
Gordon D. Jarvinen ◽  
...  
2010 ◽  
Vol 7 (3) ◽  
pp. 1108-1115 ◽  
Author(s):  
A. Nezhadali ◽  
H. Vahedi ◽  
M. Roigar ◽  
A. Sadeghi

The competitive metal ion extraction and transport of Cu(II), Ni(II), Zn(II) and Mn(II) with benzoyl acetone and EDTA was studied. In the experiments the ligand was dissolved in chloroform and the pH and time of extraction or transport were varied. Also the rate of shaking and ligand concentration on the efficiency of extraction and transport was studied. The results revealed that the ligands exclusively extract Cu(II) from the mixture of the above cations.


2015 ◽  
Vol 10 (2) ◽  
pp. 135-145 ◽  
Author(s):  
Prasanta Kumar Mohapatra

Abstract This review article gives a comprehensive account of the extraction of actinide ions using room temperature ionic liquid-based solvent systems containing diglycolamide (DGA) or functionalized DGA extractants. These extractants include multiple DGA-functionalized ligands such as tripodal DGA (T-DGA) and DGA-functionalized calix [4]arenes (C4DGA). Apart from metal ion extraction behaviour, other important features of the ionic liquid-based solvent systems such as separation behaviour, luminescence spectroscopic results, thermodynamics of extraction and radiolytic stability of the ionic liquid-based solvents are also reviewed. Results from studies on DGA-functionalized task-specific ionic liquids (TSIL) are also included in this review article.


2017 ◽  
Vol 46 (34) ◽  
pp. 11355-11362 ◽  
Author(s):  
Seraj Ahmad Ansari ◽  
Prasanta Kumar Mohapatra ◽  
Andrea Leoncini ◽  
Jurriaan Huskens ◽  
Willem Verboom

Three benzene-centred tripodal diglycolamide (Bz-T-DGA) ligands were evaluated for actinide ion extraction/complexation in an ionic liquid medium.


1990 ◽  
Vol 23 (4) ◽  
pp. 659-674 ◽  
Author(s):  
Wing Hong Chan ◽  
Albert Wai Ming Lee ◽  
Wai Kin Choi ◽  
Jason Chi Shun Wong ◽  
Kwok Keung Fung

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