Preparation and X-ray crystal structures of the first radical cation salts of4-iodotetrathiafulvalene: [ITTF.+]2{Pd[S2C2(CN) 2]2}2− and ITTF .+HSO4−

1997 ◽  
Vol 7 (3) ◽  
pp. 387-389 ◽  
Author(s):  
Andrei S. Batsanov ◽  
Adrian J. Moore ◽  
Neil Robertson ◽  
Andrew Green ◽  
Martin R. Bryce ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Radical Cation ◽  
X Ray ◽  
Radical Cation Salts

Synthesis and X-ray crystal structures of radical cation salts of benzo-TTF derivatives with Cu2Cl62−, CuCl42− and ClO4− anions

2011 ◽  
Vol 161 (17-18) ◽  
pp. 1800-1804 ◽  
Author(s):  
Louiza Boudiba ◽  
Abdelkrim Gouasmia ◽  
Stéphane Golhen ◽  
Lahcène Ouahab
Keyword(s):  
Crystal Structures ◽  
Radical Cation ◽  
X Ray ◽  
Radical Cation Salts

Functionalized Tetrathiafulvalene Derivatives and their Radical Cation Salts: Synthesis and X-Ray Crystal Structures

1997 ◽  
Vol 488 ◽  
Author(s):  
Martin R. Bryce ◽  
Adrian J. Moore ◽  
Andrei S. Batsanov ◽  
Antony Chesney ◽  
Clare L. Wood ◽  
...  
Keyword(s):  
Solid State ◽  
Crystal Structures ◽  
Intermolecular Interactions ◽  
Radical Cation ◽  
X Ray ◽  
Radical Cation Salts ◽  
Radical Ion Salts ◽  
New Donors

AbstractWe report our investigations into tetrathiafulvalene (TTF) derivatives bearing N-methylthiocarbamoyl and halogen substituents which engage in intermolecular interactions in the solid state. The synthesis of new donors is presented, along with the X-ray crystal structures of some of these derivatives and their radical ion salts.

scholarly journals exo-Methylene-BEDT-TTF and alkene-functionalised BEDT-TTF derivatives: synthesis and radical cation salts

RSC Advances ◽  
2015 ◽  
Vol 5 (39) ◽  
pp. 31104-31112 ◽  
Author(s):  
Matteo Zecchini ◽  
Jordan R. Lopez ◽  
Scott W. Allen ◽  
Simon J. Coles ◽  
Claire Wilson ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Radical Cation ◽  
Side Chain ◽  
Terminal Alkene ◽  
Radical Cation Salts

The syntheses of novel BEDT-TTF donors with either an exo-alkene group or a terminal alkene side chain are described along with the crystal structures of their first radical cation salts which include a new semiconductor.

scholarly journals New Radical-Cation Salts Based on the TMTTF and TMTSF Donors with Iron and Chromium Bis(Dicarbollide) Complexes: Synthesis, Structure, Properties

Crystals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1118
Author(s):  
Denis M. Chudak ◽  
Olga N. Kazheva ◽  
Irina D. Kosenko ◽  
Gennady V. Shilov ◽  
Igor B. Sivaev ◽  
...  
Keyword(s):  
Single Crystal ◽  
Radical Cation ◽  
Wide Temperature Range ◽  
Electrophysical Properties ◽  
Narrow Gap ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Third ◽  
Radical Cation Salts ◽  
Structure Properties

New radical-cation salts based on tetramethyltetrathiafulvalene (TMTTF) and tetramethyltetraselenefulvalene (TMsTSF) with metallacarborane anions (TMTTF)[3,3′-Cr(1,2-C2B9H11)2], (TMTTF)[3,3′-Fe(1,2-C2B9H11)2], and (TMTSF)2[3,3′-Cr(1,2-C2B9H11)2] were synthesized by electrocrystallization. Their crystal structures were determined by single crystal X-ray diffraction, and their electrophysical properties in a wide temperature range were studied. The first two salts are dielectrics, while the third one is a narrow-gap semiconductor: σRT = 5 × 10−3 Ohm−1cm−1; Ea ≈ 0.04 eV (aprox. 320 cm−1).

Synthesis, crystal structures and properties of new radical cation salts based on some tetrathiapentalene derivatives with halogenomercurate anions

2006 ◽  
Vol 156 (16-17) ◽  
pp. 991-998 ◽  
Author(s):  
E.I. Zhilyaeva ◽  
A.M. Flakina ◽  
R.N. Lyubovskaya ◽  
I.V. Fedyanin ◽  
K.A. Lyssenko ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Radical Cation ◽  
Structures And Properties ◽  
Radical Cation Salts

Syntheses, structures and theoretical calculations of stable triarylarsine radical cations

2018 ◽  
Vol 54 (12) ◽  
pp. 1493-1496 ◽  
Author(s):  
Tao Li ◽  
Gengwen Tan ◽  
Cheng Cheng ◽  
Yue Zhao ◽  
Li Zhang ◽  
...  
Keyword(s):  
Radical Cation ◽  
Epr Spectroscopy ◽  
Theoretical Calculations ◽  
Radical Cations ◽  
X Ray ◽  
X Ray Crystallography ◽  
Radical Cation Salts

Two stable triarylarsine radical cation salts have been synthesized and fully characterized by X-ray crystallography and EPR spectroscopy.

New Electroconducting Radical Cation Salts Based on BEDT-TTF with 8,8’-Dibromo Cobalt Bis(Dicarbollide) Anion

2008 ◽  
Vol 54 ◽  
pp. 331-336 ◽  
Author(s):  
Olga Kazheva ◽  
Grigorii Alexandrov ◽  
Andrey Kravchenko ◽  
Vladimir Starodub ◽  
Irina Lobanova ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Electrical Conductivity ◽  
Crystal Structures ◽  
Radical Cation ◽  
Molecular Conductors ◽  
Electrical Conductivities ◽  
Radical Cation Salts

New molecular conductors on the base of 8,8’-dibromo cobalt bis(dicarbollide) anion, (BEDT-TTF)2[8,8’-Br2-3,3’-Co(1,2-C2B9H10)2] (1), and (BEDT-TTF)[8,8’-Br2-3,3’-Co(1,2-C2B9H10)2] (2) were synthesized and their crystal structures and electrical conductivities were determined. Both radical cation salts prepared were found to be semiconductors. The introduction of two bromine atoms in the cobalt bis(dicarbollide) anion produces a strong effect on crystal structure and electrical conductivity of the prepared materials.

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