scholarly journals Facile Synthesis of Highly Crystalline and Large Areal Hexagonal Boron Nitride from Borazine Oligomers

2017 ◽  
Vol 7 (1) ◽  
Author(s):  
Sungchan Park ◽  
Tae Hoon Seo ◽  
Hyunjin Cho ◽  
Kyung Hyun Min ◽  
Dong Su Lee ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Facile Synthesis

scholarly journals Facile Synthesis of High-Quality Nano-Size 10B-Enriched Fibers of Hexagonal Boron Nitride

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 222
Author(s):  
Pervaiz Ahmad ◽  
Mayeen Uddin Khandaker ◽  
Fida Rehman ◽  
Nawshad Muhammad ◽  
Mohammad Rashed Iqbal Faruque ◽  
...  
Keyword(s):  
Boron Nitride ◽  
High Intensity ◽  
Hexagonal Boron Nitride ◽  
Internal Space ◽  
Facile Synthesis ◽  
High Quality ◽  
Crystalline Nature ◽  
Nano Size ◽  
Advanced Applications

The interesting properties of hexagonal boron nitride (h-BN) and its potential uses in thermo-structural advanced applications have been limited or restricted by its inherent brittleness, which can easily be eliminated by its fibers (h-BN) in nanoscale dimensions. The current study is based on the synthesis of nanoscale 10B-enriched fibers of h-BN (10BNNFs) from 10B in the precursors instead of B in two-hour annealing at 900 °C and one-hour growth at 1000 °C. All of the 10BNNFs are randomly curved and highly condensed or filled from 10h-BN species with no internal space or crack. XRD peaks reported the 10h-BN phase and highly crystalline nature of the synthesized 10BNNFs. 10h-BN phase and crystalline nature of 10BNNFs are confirmed from high-intensity peaks at 1392 (cm−1) in Raman and FTIR spectroscopes.

Facile synthesis of hexagonal boron nitride fibers and flowers

2007 ◽  
Vol 61 (8-9) ◽  
pp. 1735-1737 ◽  
Author(s):  
Liang-xu Lin ◽  
Ying Zheng ◽  
Yong Zheng ◽  
Ke-mei Wei
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Facile Synthesis

Facile synthesis of hexagonal boron nitride nanoplates via molten-salt-mediated magnesiothermic reduction

2015 ◽  
Vol 41 (10) ◽  
pp. 14941-14948 ◽  
Author(s):  
Linfeng Ye ◽  
Lei Zhao ◽  
Feng Liang ◽  
Xuan He ◽  
Wei Fang ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Molten Salt ◽  
Hexagonal Boron Nitride ◽  
Magnesiothermic Reduction ◽  
Facile Synthesis

Facile synthesis of vertically aligned hexagonal boron nitride nanosheets hybridized with graphitic domains

2012 ◽  
Vol 22 (11) ◽  
pp. 4818 ◽  
Author(s):  
Amir Pakdel ◽  
Xuebin Wang ◽  
Chunyi Zhi ◽  
Yoshio Bando ◽  
Kentaro Watanabe ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Facile Synthesis ◽  
Boron Nitride Nanosheets ◽  
Vertically Aligned

Facile synthesis of hexagonal boron nitride fibers with uniform morphology

2013 ◽  
Vol 39 (6) ◽  
pp. 6427-6431 ◽  
Author(s):  
Xinmei Hou ◽  
Ziyou Yu ◽  
Kuo-Chih Chou
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Facile Synthesis

Marcus-Hush Theory Revealed by Electron Tunneling Through Hexagonal Boron Nitride

2019 ◽  
Author(s):  
Matěj Velický ◽  
Sheng Hu ◽  
Colin R. Woods ◽  
Peter S. Toth ◽  
Viktor Zólyomi ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Boron Nitride ◽  
Electron Tunneling ◽  
Hexagonal Boron Nitride ◽  
Large Body ◽  
Liquid Solution ◽  
Limiting Current ◽  
Electron Transfer Rate Constant ◽  
Electrochemical Parameters ◽  
Voltammetric Measurements

Marcus-Hush theory of electron transfer is one of the pillars of modern electrochemistry with a large body of supporting experimental evidence presented to date. However, some predictions, such as the electrochemical behavior at microdisk electrodes, remain unverified. Herein, we present a study of electron tunneling across a hexagonal boron nitride barrier between a graphite electrode and redox levels in a liquid solution. This was achieved by the fabrication of microdisk electrodes with a typical diameter of 5 µm. Analysis of voltammetric measurements, using two common redox mediators, yielded several electrochemical parameters, including the electron transfer rate constant, limiting current, and transfer coefficient. They show a significant departure from the Butler-Volmer behavior in a clear manifestation of the Marcus-Hush theory of electron transfer. In addition, our system provides a novel experimental platform, which could be applied to address a number of scientific problems such as identification of reaction mechanisms, surface modification, or long-range electron transfer.

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