scholarly journals Zeta potential in oil-water-carbonate systems and its impact on oil recovery during controlled salinity water-flooding

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Matthew D. Jackson ◽  
Dawoud Al-Mahrouqi ◽  
Jan Vinogradov
Keyword(s):  
Zeta Potential ◽  
Oil Recovery ◽  
Water Flooding ◽  
Salinity Water ◽  
Oil Water ◽  
Water Carbonate

A Comparison of Different Nanoparticles' Effect on Fine Migration by Low Salinity Water Injection for Oil Recovery: Introducing an Optimum Condition

2021 ◽  
pp. 1-22 ◽  
Author(s):  
Ali Madadizadeh ◽  
Alireza Sadeghein ◽  
Siavash Riahi
Keyword(s):  
Porous Media ◽  
Zeta Potential ◽  
Oil Recovery ◽  
Fine Particles ◽  
Production Equipment ◽  
Water Flooding ◽  
Sand Production ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water

Abstract Today, enhance oil recovery (EOR) methods are attracting more attention to increase the petroleum production rate. Some EOR methods such as low salinity water flooding (LSW) can increase the amount of fine migration and sand production in sandstone reservoirs which causes a reduction in permeability and inflict damages on to the reservoir and the production equipment. One of the methods to control fine migration is using nanotechnology. Nanoparticles (NPs) can reduce fine migration by various mechanisms such as reducing the zeta potential of fine particles' surfaces. In this paper, three NPs including SiO2, MgO, and Al2O3 's effects on controlling fine migration and sand production were investigated in two scenarios of pre-flush and co-injection by using sandpack as a porous media sample. When NPs are injected into the porous media sample, the outflow turbidity and zeta potential of particles decreases. Experiments showed that SiO2 has the best effect on controlling fine migration in comparison with other NPs and it could reduce fine migration 69% in pre-flush and 75% in co-injection. Also, MgO and Al2O3 decreased fine migration 65% and 33% in the pre-flush scenario and 49%,13% in the co-injection scenario, respectively.

scholarly journals Dissecting The Salinity-Dependence Of Wettability In Oil/Brine/Calcite System Using Molecular Simulations

2019 ◽  
Author(s):  
Mohamed Alhosani ◽  
Arjun Valiya Parambathu ◽  
Fernando Miguel Yrazu ◽  
Dilip Asthagiri ◽  
Walter Chapman
Keyword(s):  
Ionic Strength ◽  
Oil Recovery ◽  
Molecular Simulations ◽  
Water Flooding ◽  
Great Promise ◽  
Low Salinity ◽  
Complex Interactions ◽  
Salinity Water ◽  
Oil Water ◽  
Two Fluid

Low salinity water flooding has shown great promise due to its cost-effectiveness and low environmental impact for improving and sustaining oil production. It is believed that injecting water with ionic strength lower than that of the reservoir changes the reservoir from less to more water-wet and enhances oil recovery. This alteration phenomenon is not well understood, due to complex interactions between oil, water, and rock. Here we use molecular simulations to characterize the wettability of the 10.4-face of calcite in a calcite/brine/oil system, and address how wettability is altered by changing ionic strength and salt type (NaCl vs. CaCl<sub>2</sub>). Using the test area method we calculate the superficial tension of the fluids against the solid and the surface tension between the two fluid phases. As the salinity is decreased, the wetting of calcite by brine is progressively less favored, contrary to what might be expected based on low salinity flooding. However, as salinity is decreased, forming the oil-brine interface is more favored. On balance, it is the latter effect that leads to the enhanced wetting of calcite by brine in the oil-brine-calcite system, and it is suggested as an important element in the physics underlying low-salinity flooding. <br>

scholarly journals Investigation of Clay Type on Low Salinity Water Flooding Using a Glass Micromodel

2020 ◽  
Vol 8 ◽  
Author(s):  
Xuemei Wei ◽  
Wenchao Jiang ◽  
Yanyu Zhang ◽  
Zhao Wang ◽  
Xiaojun Li ◽  
...  
Keyword(s):  
Zeta Potential ◽  
Clay Minerals ◽  
Oil Recovery ◽  
Wetting Angle ◽  
Water Flooding ◽  
Residual Oil ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Displacement Experiments ◽  
Salinity Water

Clay minerals are usually regarded as an important factor affecting the results of low salinity water (LSW) flooding. However, experiments on clay minerals are mainly in qualitative stage, the mechanism of clay minerals has not been studied completely. In this paper, Zeta potential of four kinds of clay minerals (montmorillonite; chlorite; illite; kaolinite) in different brine was measured, microscopic models of these clay minerals were made to measured wetting angle in different brine, and montmorillonite and kaolinite were chosen to conduct microscopic displacement experiments through customized micro-glass etching models. From experiment results, the following conclusions can be get: 1). With the decrease of salinity of injected water, the negative zeta potential of clay minerals increases and the wetting angle decreases. 2). Clay minerals are more sensitive to monovalent Na+ than bivalent Ca2+. 3). The results of microscopic experiments show that LSW can effectively improve oil recovery, whether kaolinite or montmorillonite. The recovery of montmorillonite is better with a relatively high salinity of LSW and kaolinite is better with a relatively low salinity of LSW. The mechanism of LSW improves kaolinite recovery factor is the change of wettability while that of montmorillonite is the increase of water phase wettability. However, a lot of droplet-like residual oil cannot be displaced in the montmorillonite throat. In filed production, both kaolinite-rich and montmorillonite-rich reservoirs are suitable for LSW flooding to improve oil recovery. However, for kaolinite reservoirs, a lower salinity of injected water would produce a better result, while for montmorillonite reservoirs, residual oil droplets in the throat are noteworthy.

scholarly journals Dissecting The Salinity-Dependence Of Wettability In Oil/Brine/Calcite System Using Molecular Simulations

2019 ◽  
Author(s):  
Mohamed Alhosani ◽  
Arjun Valiya Parambathu ◽  
Fernando Miguel Yrazu ◽  
Dilip Asthagiri ◽  
Walter Chapman
Keyword(s):  
Ionic Strength ◽  
Oil Recovery ◽  
Molecular Simulations ◽  
Water Flooding ◽  
Great Promise ◽  
Low Salinity ◽  
Complex Interactions ◽  
Salinity Water ◽  
Oil Water ◽  
Two Fluid

Low salinity water flooding has shown great promise due to its cost-effectiveness and low environmental impact for improving and sustaining oil production. It is believed that injecting water with ionic strength lower than that of the reservoir changes the reservoir from less to more water-wet and enhances oil recovery. This alteration phenomenon is not well understood, due to complex interactions between oil, water, and rock. Here we use molecular simulations to characterize the wettability of the 10.4-face of calcite in a calcite/brine/oil system, and address how wettability is altered by changing ionic strength and salt type (NaCl vs. CaCl<sub>2</sub>). Using the test area method we calculate the superficial tension of the fluids against the solid and the surface tension between the two fluid phases. As the salinity is decreased, the wetting of calcite by brine is progressively less favored, contrary to what might be expected based on low salinity flooding. However, as salinity is decreased, forming the oil-brine interface is more favored. On balance, it is the latter effect that leads to the enhanced wetting of calcite by brine in the oil-brine-calcite system, and it is suggested as an important element in the physics underlying low-salinity flooding. <br>

scholarly journals Manipulation of surface charges of oil droplets and carbonate rocks to improve oil recovery

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jian Hou ◽  
Ming Han ◽  
Jinxun Wang
Keyword(s):  
Zeta Potential ◽  
Oil Recovery ◽  
Carbonate Rocks ◽  
Zwitterionic Surfactant ◽  
Surface Charges ◽  
Oil Droplets ◽  
Zeta Potentials ◽  
Potential Value ◽  
Oil Water ◽  
Incremental Oil Recovery

AbstractThis work investigates the effect of the surface charges of oil droplets and carbonate rocks in brine and in surfactant solutions on oil production. The influences of the cations in brine and the surfactant types on the zeta-potentials of both oil droplets and carbonate rock particles are studied. It is found that the addition of anionic and cationic surfactants in brine result in both negative or positive zeta-potentials of rock particles and oil droplets respectively, while the zwitterionic surfactant induces a positive charge on rock particles and a negative charge on oil droplets. Micromodels with a CaCO3 nanocrystal layer coated on the flow channels were used in the oil displacement tests. The results show that when the oil-water interfacial tension (IFT) was at 10−1 mN/m, the injection of an anionic surfactant (SDS-R1) solution achieved 21.0% incremental oil recovery, higher than the 12.6% increment by the injection of a zwitterionic surfactant (SB-A2) solution. When the IFT was lowered to 10−3 mM/m, the injection of anionic/non-ionic surfactant SMAN-l1 solution with higher absolute zeta potential value (ζoil + ζrock) of 34 mV has achieved higher incremental oil recovery (39.4%) than the application of an anionic/cationic surfactant SMAC-l1 solution with a lower absolute zeta-potential value of 22 mV (30.6%). This indicates that the same charge of rocks and oil droplets improves the transportation of charged oil/water emulsion in the porous media. This work reveals that the surface charge in surfactant flooding plays an important role in addition to the oil/water interfacial tension reduction and the rock wettability alteration.

scholarly journals A mechanistic investigation of low salinity water flooding coupled with ion tuning for enhanced oil recovery

RSC Advances ◽  
2020 ◽  
Vol 10 (69) ◽  
pp. 42570-42583
Author(s):  
Rohit Kumar Saw ◽  
Ajay Mandal
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Water Flooding ◽  
Wettability Alteration ◽  
Rock Surface ◽  
Calcite Dissolution ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Mechanistic Investigation ◽  
Salinity Water

The combined effects of dilution and ion tuning of seawater for enhanced oil recovery from carbonate reservoirs. Dominating mechanisms are calcite dissolution and the interplay of potential determining ions that lead to wettability alteration of rock surface.

scholarly journals Modelling Low-Salinity Water Flooding as a Tertiary Oil Recovery Technique

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Oluwasanmi Olabode ◽  
David Alaigba ◽  
Daniel Oramabo ◽  
Oreofeoluwa Bamigboye
Keyword(s):  
Oil Recovery ◽  
Water Flooding ◽  
High Salinity Water ◽  
Low Salinity ◽  
Low Salinity Water ◽  
First Case ◽  
Short Period ◽  
Tertiary Oil Recovery ◽  
Salinity Water ◽  
Field Production

In this project, low-salinity water flooding has been modeled on ECLIPSE black oil simulator in three cases for a total field production life of twenty-five years. In the first case, low-salinity water flooding starts fifteen years after secondary water flooding. For the second case, low-salinity water flooding starts five years after secondary water flooding and runs till the end of the field production life. For the third case, low-salinity water flooding starts five years after secondary water flooding, but low-salinity water flooding is injected in measured pore volumes for a short period of time; then, high-salinity water flooding was resumed till the end of the field production life. This was done to measure the effect of low-salinity water flooding as slug injection. From the three cases presented, oil recovery efficiency, field oil production rate, and field water cut were observed. Increased percentages of 22.66%, 35.12%, and 26.77% were observed in the three cases, respectively.

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