scholarly journals Time-resolved HAXPES using a microfocused XFEL beam: From vacuum space-charge effects to intrinsic charge-carrier recombination dynamics

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Lars-Philip Oloff ◽  
Ashish Chainani ◽  
Masaharu Matsunami ◽  
Kazutoshi Takahashi ◽  
Tadashi Togashi ◽  
...  
Research ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Essa A. Alharbi ◽  
M. Ibrahim Dar ◽  
Neha Arora ◽  
Mohammad Hayal Alotaibi ◽  
Yahya A. Alzhrani ◽  
...  

High photovoltages and power conversion efficiencies of perovskite solar cells (PSCs) can be realized by controlling the undesired nonradiative charge carrier recombination. Here, we introduce a judicious amount of guanidinium iodide into mixed-cation and mixed-halide perovskite films to suppress the parasitic charge carrier recombination, which enabled the fabrication of >20% efficient and operationally stable PSCs yielding reproducible photovoltage as high as 1.20 V. By introducing guanidinium iodide into the perovskite precursor solution, the bandgap of the resulting absorber material changed minimally; however, the nonradiative recombination diminished considerably as revealed by time-resolved photoluminescence and electroluminescence studies. Furthermore, using capacitance-frequency measurements, we were able to correlate the hysteresis features exhibited by the PSCs with interfacial charge accumulation. This study opens up a path to realize new record efficiencies for PSCs based on guanidinium iodide doped perovskite films.


Research ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Essa A. Alharbi ◽  
M. Ibrahim Dar ◽  
Neha Arora ◽  
Mohammad Hayal Alotaibi ◽  
Yahya A. Alzhrani ◽  
...  

High photovoltages and power conversion efficiencies of perovskite solar cells (PSCs) can be realized by controlling the undesired nonradiative charge carrier recombination. Here, we introduce a judicious amount of guanidinium iodide into mixed-cation and mixed-halide perovskite films to suppress the parasitic charge carrier recombination, which enabled the fabrication of >20% efficient and operationally stable PSCs yielding reproducible photovoltage as high as 1.20 V. By introducing guanidinium iodide into the perovskite precursor solution, the bandgap of the resulting absorber material changed minimally; however, the nonradiative recombination diminished considerably as revealed by time-resolved photoluminescence and electroluminescence studies. Furthermore, using capacitance-frequency measurements, we were able to correlate the hysteresis features exhibited by the PSCs with interfacial charge accumulation. This study opens up a path to realize new record efficiencies for PSCs based on guanidinium iodide doped perovskite films.


2012 ◽  
Vol 85 (7) ◽  
Author(s):  
S. Hellmann ◽  
T. Ott ◽  
L. Kipp ◽  
K. Rossnagel

1999 ◽  
Vol 74 (12) ◽  
pp. 1731-1733 ◽  
Author(s):  
S. V. Garnov ◽  
A. I. Ritus ◽  
S. M. Klimentov ◽  
S. M. Pimenov ◽  
V. I. Konov ◽  
...  

2014 ◽  
Vol 16 (12) ◽  
pp. 123045 ◽  
Author(s):  
L-P Oloff ◽  
M Oura ◽  
K Rossnagel ◽  
A Chainani ◽  
M Matsunami ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document