scholarly journals Stiffness in vortex—like structures due to chirality-domains within a coupled helical rare-earth superlattice

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Amitesh Paul
Keyword(s):  
Rare Earth ◽  
Domain Walls ◽  
Topological Defects ◽  
Magnetic Ordering ◽  
Direct Consequence ◽  
Magnetic Vortex ◽  
Range Magnetic Order ◽  
Wide Range ◽  
Out Of Plane ◽  
The Stability

Abstract Vortex domain walls poses chirality or ‘handedness’ which can be exploited to act as memory units by changing their polarity with electric field or driving/manupulating the vortex itself by electric currents in multiferroics. Recently, domain walls formed by one dimensional array of vortex—like structures have been theoretically predicted to exist in disordered rare-earth helical magnets with topological defects. Here, in this report, we have used a combination of two rare-earth metals, e.g."Equation missing" superlattice that leads to long range magnetic order despite their competing anisotropies along the out-of-plane (Er) and in-plane (Tb) directions. Probing the vertically correlated magnetic structures by off-specular polarized neutron scattering we confirm the existence of such magnetic vortex—like domains associated with magnetic helical ordering within the Er layers. The vortex—like structures are predicted to have opposite chirality, side—by—side and are fairly unaffected by the introduction of magnetic ordering between the interfacial Tb layers and also with the increase in magnetic field which is a direct consequence of screening of the vorticity in the system due to a helical background. Overall, the stability of these vortices over a wide range of temperatures, fields and interfacial coupling, opens up the opportunity for fundamental chiral spintronics in unconventional systems.

scholarly journals Thickness-dependent magnetic order in CrI3 single crystals

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Yu Liu ◽  
Lijun Wu ◽  
Xiao Tong ◽  
Jun Li ◽  
Jing Tao ◽  
...  
Keyword(s):  
Domain Walls ◽  
Magnetic Order ◽  
Magnetic Transition ◽  
Mean Field ◽  
Magnetic Domain ◽  
Crystal Thickness ◽  
Range Magnetic Order ◽  
Plane Field ◽  
Out Of Plane ◽  
Magnetic Domain Walls

Abstract Two-dimensional (2D) materials with intrinsic ferromagnetism provide unique opportunity to engineer new functionalities in nano-spintronics. One such material is CrI3, showing long-range magnetic order in monolayer with the Curie temperature (Tc) of 45 K. Here we study detailed evolution of magnetic transition and magnetic critical properties in response to systematic reduction in crystal thickness down to 50 nm. Bulk Tc of 61 K is gradually suppressed to 57 K, however, the satellite transition at T * = 45 K is observed layer-independent at fixed magnetic field of 1 kOe. The origin of T * is proposed to be a crossover from pinning to depinning of magnetic domain walls. The reduction of thickness facilitates a field-driven metamagnetic transition around 20 kOe with out-of-plane field, in contrast to the continuous changes with in-plane field. The critical analysis around Tc elucidates the mean-field type interactions in microscale-thick CrI3.

scholarly journals Polarizability of electrically induced magnetic vortex “atoms”

2018 ◽  
Vol 185 ◽  
pp. 07003
Author(s):  
P.I. Karpov ◽  
S.I. Mukhin
Keyword(s):  
Electric Field ◽  
Electric Fields ◽  
Domain Walls ◽  
Topological Defects ◽  
Magnetic Vortex ◽  
Distribution Profile ◽  
Magnetic Structures ◽  
Magnetic Vortices ◽  
Vortex Density ◽  
Magnetoelectric Materials

Electric field control of magnetic structures, particularly topological defects in magnetoelectric materials, draws a great attention, which has led to experimental success in creation and manipulation of single magnetic defects, such as skyrmions and domain walls. In this work we explore a scenario of electric field creation of another type of topological defects – magnetic vortices and antivortices. Because of interaction of magnetic and electric subsystems each magnetic vortex (antivortex) in magnetoelectric materials possesses quantized magnetic charge, responsible for interaction between vortices, and electric charge that couples them to electric field. This property of magnetic vortices makes possible their creation by electric fields. We show that the electric field, created by a cantilever tip, produces a “magnetic atom” with a localized spot of ordered vortices (“nucleus” of the atom) surrounded by antivortices (“electronic shells”). We analytically find the vortex density distribution profile and temperature dependence of polarizability of this structure and confirm it numerically by Monte Carlo simulation.

Topological spin/structure couplings in layered chiral magnet Cr1/3TaS2: The discovery of spiral magnetic superstructure

2021 ◽  
Vol 118 (40) ◽  
pp. e2023337118
Author(s):  
Kai Du ◽  
Fei-Ting Huang ◽  
Jaewook Kim ◽  
Seong Joon Lim ◽  
Kasun Gamage ◽  
...  
Keyword(s):  
Domain Walls ◽  
Topological Defects ◽  
Magnetic Texture ◽  
Spintronic Devices ◽  
Wide Range ◽  
Domain Boundaries ◽  
Complex Spin ◽  
Magnetic Skyrmions ◽  
Magnetic States ◽  
Opposite Chirality

Chiral magnets have recently emerged as hosts for topological spin textures and related transport phenomena, which can find use in next-generation spintronic devices. The coupling between structural chirality and noncollinear magnetism is crucial for the stabilization of complex spin structures such as magnetic skyrmions. Most studies have been focused on the physical properties in homochiral states favored by crystal growth and the absence of long-ranged interactions between domains of opposite chirality. Therefore, effects of the high density of chiral domains and domain boundaries on magnetic states have been rarely explored so far. Herein, we report layered heterochiral Cr1/3TaS2, exhibiting numerous chiral domains forming topological defects and a nanometer-scale helimagnetic order interlocked with the structural chirality. Tuning the chiral domain density, we discovered a macroscopic topological magnetic texture inside each chiral domain that has an appearance of a spiral magnetic superstructure composed of quasiperiodic Néel domain walls. The spirality of this object can have either sign and is decoupled from the structural chirality. In weak, in-plane magnetic fields, it transforms into a nonspiral array of concentric ring domains. Numerical simulations suggest that this magnetic superstructure is stabilized by strains in the heterochiral state favoring noncollinear spins. Our results unveil topological structure/spin couplings in a wide range of different length scales and highly tunable spin textures in heterochiral magnets.

scholarly journals Observation of domain wall bimerons in chiral magnets

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Tomoki Nagase ◽  
Yeong-Gi So ◽  
Hayata Yasui ◽  
Takafumi Ishida ◽  
Hiroyuki K. Yoshida ◽  
...  
Keyword(s):  
Domain Wall ◽  
Magnetic Anisotropy ◽  
Domain Walls ◽  
Topological Defects ◽  
Dipolar Interaction ◽  
Micromagnetic Simulations ◽  
Localized State ◽  
Transmission Electron ◽  
Wide Range ◽  
Lorentz Transmission Electron Microscopy

AbstractTopological defects embedded in or combined with domain walls have been proposed in various systems, some of which are referred to as domain wall skyrmions or domain wall bimerons. However, the experimental observation of such topological defects remains an ongoing challenge. Here, using Lorentz transmission electron microscopy, we report the experimental discovery of domain wall bimerons in chiral magnet Co-Zn-Mn(110) thin films. By applying a magnetic field, multidomain structures develop, and simultaneously, chained or isolated bimerons arise as the localized state between the domains with the opposite in-plane components of net magnetization. The multidomain formation is attributed to magnetic anisotropy and dipolar interaction, and domain wall bimerons are stabilized by the Dzyaloshinskii-Moriya interaction. In addition, micromagnetic simulations show that domain wall bimerons appear for a wide range of conditions in chiral magnets with cubic magnetic anisotropy. Our results promote further study in various fields of physics.

scholarly journals Making waves round a structured cloak: lattices, negative refraction and fringes

2013 ◽  
Vol 469 (2157) ◽  
pp. 20130218 ◽  
Author(s):  
D. J. Colquitt ◽  
I. S. Jones ◽  
N. V. Movchan ◽  
A. B. Movchan ◽  
M. Brun ◽  
...  
Keyword(s):  
Electromagnetic Waves ◽  
Negative Refraction ◽  
Lattice Structure ◽  
Low Frequency ◽  
Plane Shear ◽  
Wide Range ◽  
Out Of Plane ◽  
Frequency Regime ◽  
The Stability

Using the framework of transformation optics, this paper presents a detailed analysis of a non-singular square cloak for acoustic, out-of-plane shear elastic and electromagnetic waves. Analysis of wave propagation through the cloak is presented and accompanied by numerical illustrations. The efficacy of the regularized cloak is demonstrated and an objective numerical measure of the quality of the cloaking effect is provided. It is demonstrated that the cloaking effect persists over a wide range of frequencies. As a demonstration of the effectiveness of the regularized cloak, a Young's double slit experiment is presented. The stability of the interference pattern is examined when a cloaked and uncloaked obstacle are successively placed in front of one of the apertures. This novel link with a well-known quantum mechanical experiment provides an additional method through which the quality of cloaks may be examined. In the second half of the paper, it is shown that an approximate cloak may be constructed using a discrete lattice structure. The efficiency of the approximate lattice cloak is analysed and a series of illustrative simulations presented. It is demonstrated that effective cloaking may be obtained by using a relatively simple lattice structure, particularly, in the low-frequency regime.

Performance of Electronic Structure Methods for the Description of Hückel-Möbius Interconversions in Extended π-Systems

2019 ◽  
Author(s):  
Tatiana Woller ◽  
Ambar Banerjee ◽  
Nitai Sylvetsky ◽  
Xavier Deraet ◽  
Frank De Proft ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Basis Set ◽  
Dft Methods ◽  
Molecular Switching ◽  
Wide Range ◽  
Electronic Structure Methods ◽  
Explicitly Correlated ◽  
Relative Errors ◽  
The Stability ◽  
Basis Set Expansion

<p>Expanded porphyrins provide a versatile route to molecular switching devices due to their ability to shift between several π-conjugation topologies encoding distinct properties. Taking into account its size and huge conformational flexibility, DFT remains the workhorse for modeling such extended macrocycles. Nevertheless, the stability of Hückel and Möbius conformers depends on a complex interplay of different factors, such as hydrogen bonding, p···p stacking, steric effects, ring strain and electron delocalization. As a consequence, the selection of an exchange-correlation functional for describing the energy profile of topological switches is very difficult. For these reasons, we have examined the performance of a variety of wavefunction methods and density functionals for describing the thermochemistry and kinetics of topology interconversions across a wide range of macrocycles. Especially for hexa- and heptaphyrins, the Möbius structures have a pronouncedly stronger degree of static correlation than the Hückel and figure-eight structures, and as a result the relative energies of singly-twisted structures are a challenging test for electronic structure methods. Comparison of limited orbital space full CI calculations with CCSD(T) calculations within the same active spaces shows that post-CCSD(T) correlation contributions to relative energies are very minor. At the same time, relative energies are weakly sensitive to further basis set expansion, as proven by the minor energy differences between MP2/cc-pVDZ and explicitly correlated MP2-F12/cc-pVDZ-F12 calculations. Hence, our CCSD(T) reference values are reasonably well-converged in both 1-particle and n-particle spaces. While conventional MP2 and MP3 yield very poor results, SCS-MP2 and particularly SOS-MP2 and SCS-MP3 agree to better than 1 kcal mol<sup>-1</sup> with the CCSD(T) relative energies. Regarding DFT methods, only M06-2X provides relative errors close to chemical accuracy with a RMSD of 1.2 kcal mol<sup>-1</sup>. While the original DSD-PBEP86 double hybrid performs fairly poorly for these extended p-systems, the errors drop down to 2 kcal mol<sup>-1</sup> for the revised revDSD-PBEP86-NL, again showing that same-spin MP2-like correlation has a detrimental impact on performance like the SOS-MP2 results. </p>

Insights into Potent Therapeutical Antileukemic Agent L-glutaminase Enzyme Under Solid-state Fermentation: A Review

2020 ◽  
Vol 21 (3) ◽  
pp. 211-220 ◽  
Author(s):  
Chandrasai Potla Durthi ◽  
Madhuri Pola ◽  
Satish Babu Rajulapati ◽  
Anand Kishore Kola
Keyword(s):  
Solid State ◽  
Solid State Fermentation ◽  
Food Industry ◽  
Energy Requirement ◽  
Production Studies ◽  
Wide Range ◽  
Hybridoma Technology ◽  
Bacteria And Fungi ◽  
The Stability ◽  
Glutaminase Activity

Aim & objective: To review the applications and production studies of reported antileukemic drug L-glutaminase under Solid-state Fermentation (SSF). Overview: An amidohydrolase that gained economic importance because of its wide range of applications in the pharmaceutical industry, as well as the food industry, is L-glutaminase. The medical applications utilized it as an anti-tumor agent as well as an antiretroviral agent. L-glutaminase is employed in the food industry as an acrylamide degradation agent, as a flavor enhancer and for the synthesis of theanine. Another application includes its use in hybridoma technology as a biosensing agent. Because of its diverse applications, scientists are now focusing on enhancing the production and optimization of L-glutaminase from various sources by both Solid-state Fermentation (SSF) and submerged fermentation studies. Of both types of fermentation processes, SSF has gained importance because of its minimal cost and energy requirement. L-glutaminase can be produced by SSF from both bacteria and fungi. Single-factor studies, as well as multi-level optimization studies, were employed to enhance L-glutaminase production. It was concluded that L-glutaminase activity achieved by SSF was 1690 U/g using wheat bran and Bengal gram husk by applying feed-forward artificial neural network and genetic algorithm. The highest L-glutaminase activity achieved under SSF was 3300 U/gds from Bacillus sp., by mixture design. Purification and kinetics studies were also reported to find the molecular weight as well as the stability of L-glutaminase. Conclusion: The current review is focused on the production of L-glutaminase by SSF from both bacteria and fungi. It was concluded from reported literature that optimization studies enhanced L-glutaminase production. Researchers have also confirmed antileukemic and anti-tumor properties of the purified L-glutaminase on various cell lines.

scholarly journals Polymer-Drug Conjugates as Nanotheranostic Agents

2021 ◽  
Vol 2 (1) ◽  
pp. 63-81
Author(s):  
Sajana Manandhar ◽  
Erica Sjöholm ◽  
Johan Bobacka ◽  
Jessica M. Rosenholm ◽  
Kuldeep K. Bansal
Keyword(s):  
Drug Delivery ◽  
Drug Release ◽  
Treatment Options ◽  
The Body ◽  
Drug Conjugates ◽  
Imaging Characteristics ◽  
Wide Range ◽  
Systemic Side Effects ◽  
Theranostic Agents ◽  
The Stability

Since the last decade, the polymer-drug conjugate (PDC) approach has emerged as one of the most promising drug-delivery technologies owing to several benefits like circumventing premature drug release, offering controlled and targeted drug delivery, improving the stability, safety, and kinetics of conjugated drugs, and so forth. In recent years, PDC technology has advanced with the objective to further enhance the treatment outcomes by integrating nanotechnology and multifunctional characteristics into these systems. One such development is the ability of PDCs to act as theranostic agents, permitting simultaneous diagnosis and treatment options. Theranostic nanocarriers offer the opportunity to track the distribution of PDCs within the body and help to localize the diseased site. This characteristic is of particular interest, especially among those therapeutic approaches where external stimuli are supposed to be applied for abrupt drug release at the target site for localized delivery to avoid systemic side effects (e.g., Visudyne®). Thus, with the help of this review article, we are presenting the most recent updates in the domain of PDCs as nanotheranostic agents. Different methodologies utilized to design PDCs along with imaging characteristics and their applicability in a wide range of diseases, have been summarized in this article.

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