scholarly journals Study of Sequential Dexter Energy Transfer in High Efficient Phosphorescent White Organic Light-Emitting Diodes with Single Emissive Layer

2014 ◽  
Vol 4 (1) ◽  
Author(s):  
Jin Wook Kim ◽  
Seung Il You ◽  
Nam Ho Kim ◽  
Ju-An Yoon ◽  
Kok Wai Cheah ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Emissive Layer ◽  
Organic Light ◽  
High Efficient

High Efficient White Organic Light-Emitting Diodes Using BCzVBi as Blue Fluorescent Dopant

2008 ◽  
Vol 8 (9) ◽  
pp. 4579-4583
Author(s):  
You-Hyun Kim ◽  
Su-Hwan Lee ◽  
Hyun-Soo Yoon ◽  
Jae-Yoon Choi ◽  
Sung Sik Shin ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Light Emitting Diodes ◽  
Luminous Efficiency ◽  
Organic Light Emitting Diodes ◽  
Efficiency Improvement ◽  
Light Emitting ◽  
Organic Light ◽  
High Efficient

Efficiency improvement and color optimization of white organic light-emitting diodes (WOLEDs) were achieved via employing blue host DPVBi doped with blue fluorescent, BCzVBi. The structure of high efficient WOLED device was composed of ITO/NPB/DPVBi:BCzVBi-6%/MADN:DCM2-0.5%/Bphen/Liq/Al. WOLED doped by blue fluorescent BCzVBi exhibits 6.19 cd/A of luminous efficiency and 15400 cd/m2 of maximum luminescence. It also performs 480 cd/m2 of luminance at 5.7 V and 15,400 cd/m2 at 12.9 V with CIEx,y coordinates of (0.33, 0.32) and (0.32, 0.32), respectively. Hole carrier and energy transfer from DPVBi to BCzVBi are proposed to explain the observed phenomena.

Electrically and Optically Detected Electron Paramagnetic Resonance in Blue Organic Light Emitting Diodes

2021 ◽  
Author(s):  
◽  
Rebecca Jane Sutton
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Great Promise ◽  
Paramagnetic Resonance ◽  
Light Emitting ◽  
Emissive Layer ◽  
Organic Light ◽  
Optically Detected ◽  
Electron Paramagnetic

<p>Organic light emitting diodes (OLEDs) are an emerging technology based on electrically conducting polymer films, with great promise for large area lighting and flexible ultra-thin displays. However, despite the rapid technological development, there is still a poor understanding of the degradation and spindependent recombination processes that take place inside an OLED. In this thesis, Electron Paramagnetic Resonance (EPR) was used to investigate these processes in blue-emitting OLEDs.  A successful procedure was developed and refined for fabricating OLEDs with the structure ITO/PEDOT:PSS/emissive layer/Al/Ag, with and without the PEDOT:PSS hole-transporting layer. The organic emissive layer was either F8BT, PFO, or PVK:OXD-7:FIrpic (PB). These OLEDs were fabricated in air and with a geometry optimised for EPR experiments. Critical features for satisfactory devices were found to be a sufficiently thick organic layer and minimal exposure to the air.  A compact apparatus was developed for simultaneous light output, current, and voltage measurements on the OLEDs while in an inert glove box environment. Electroluminescence and current-voltage parameters measured for these devices showed predominantly trap-controlled space-charge-limited conduction.   OLEDs with PFO as the emissive layer and with a PEDOT:PSS layer were investigated with conventional, electrically-detected (ED) and optically-detected (OD) EPR techniques. EDEPR and ODEPR signals were observed at ~9.2 GHz and in the low (<50 mT) and high (~330 mT) magnetic field regimes and were found to change markedly with time during operation as the device degraded. The low field signals initially showed a composite broad quenching and superimposed narrow enhancing response centred around zero field strength. These signals were attributed to magneto-resistance (MR) and magneto-electroluminescence (MEL). Following operational ageing, a third, narrow quenching line was observed in the MR and the ratio of the initial two MR responses changed substantially. These effects are tentatively attributed to a hyperfine interaction.  For both EDEPR and ODEPR, quenching high field resonances with a g-value (gyromagnetic ratio) of 2.003±0.001 were observed. The current-quenching resonance gradually diminished during operation and after 4–5 hours was replaced by a current-enhancing resonance. The appearance of this latter resonance could be explained by chemical changes in the OLED due to the diffusion of oxygen through the device from the oxygen-plasma-treated ITO. A working model is proposed which can explain this observed change as spindependent trapping and recombination at free radicals, although the model requires further experimentation to test its validity.</p>

Sign in / Sign up

Export Citation Format

Share Document