scholarly journals Abiotic synthesis of amino acids and self-crystallization under prebiotic conditions

2014 ◽  
Vol 4 (1) ◽  
Author(s):  
Liying Jiang ◽  
Pawel Dziedzic ◽  
Zdenek Spacil ◽  
Gui-Ling Zhao ◽  
Lennart Nilsson ◽  
...  
Keyword(s):  
Amino Acids ◽  
Abiotic Synthesis

Abiotic synthesis of amino acids by x-ray irradiation of simple inorganic gases

1999 ◽  
Vol 74 (6) ◽  
pp. 877-879 ◽  
Author(s):  
Jun-ichi Takahashi ◽  
Teruo Hosokawa ◽  
Hitomi Masuda ◽  
Takeo Kaneko ◽  
Kensei Kobayashi ◽  
...  
Keyword(s):  
Amino Acids ◽  
X Ray ◽  
Abiotic Synthesis

Abiotic synthesis of amino acids and imidazole by proton irradiation of simulated primitive earth atmospheres

1990 ◽  
Vol 20 (2) ◽  
pp. 99-109 ◽  
Author(s):  
Kensei Kobayashi ◽  
Masahiko Tsuchiya ◽  
Tairo Oshima ◽  
Hiroshi Yanagawa
Keyword(s):  
Amino Acids ◽  
Proton Irradiation ◽  
Primitive Earth ◽  
Abiotic Synthesis

Abiotic Synthesis of Amino Acids by Proton Irradiation of a Mixture of Carbon Monoxide, Nitrogen, and Water

1989 ◽  
Vol 18 (9) ◽  
pp. 1527-1530 ◽  
Author(s):  
Kensei Kobayashi ◽  
Tairo Oshima ◽  
Hiroshi Yanagawa
Keyword(s):  
Amino Acids ◽  
Carbon Monoxide ◽  
Proton Irradiation ◽  
Abiotic Synthesis

Abiotic synthesis of amino acids in the recesses of the oceanic lithosphere

Nature ◽  
2018 ◽  
Vol 564 (7734) ◽  
pp. 59-63 ◽  
Author(s):  
Bénédicte Ménez ◽  
Céline Pisapia ◽  
Muriel Andreani ◽  
Frédéric Jamme ◽  
Quentin P. Vanbellingen ◽  
...  
Keyword(s):  
Amino Acids ◽  
Oceanic Lithosphere ◽  
Abiotic Synthesis

Homochirality as the Signature of Extra-Terrestrial Life

1997 ◽  
Vol 161 ◽  
pp. 505-510
Author(s):  
Alexandra J. MacDermott ◽  
Laurence D. Barron ◽  
Andrè Brack ◽  
Thomas Buhse ◽  
John R. Cronin ◽  
...  
Keyword(s):  
Amino Acids ◽  
Protein Synthesis ◽  
Optical Rotation ◽  
Physical Origin ◽  
Natural Choice ◽  
Rosetta Mission ◽  
Terrestrial Life ◽  
Subsurface Layers ◽  
Solar System Bodies ◽  
Origin Of Homochirality

AbstractThe most characteristic hallmark of life is its homochirality: all biomolecules are usually of one hand, e.g. on Earth life uses only L-amino acids for protein synthesis and not their D mirror images. We therefore suggest that a search for extra-terrestrial life can be approached as a Search for Extra- Terrestrial Homochirality (SETH). The natural choice for a SETH instrument is optical rotation, and we describe a novel miniaturized space polarimeter, called the SETH Cigar, which could be used to detect optical rotation as the homochiral signature of life on other planets. Moving parts are avoided by replacing the normal rotating polarizer by multiple fixed polarizers at different angles as in the eye of the bee. We believe that homochirality may be found in the subsurface layers on Mars as a relic of extinct life, and on other solar system bodies as a sign of advanced pre-biotic chemistry. We discuss the chiral GC-MS planned for the Roland lander of the Rosetta mission to a comet and conclude with theories of the physical origin of homochirality.

Hydrogen Cyanide Polymers from the Impact of Comet P/Shoemaker-Levy 9 on Jupiter

1997 ◽  
Vol 161 ◽  
pp. 179-187
Author(s):  
Clifford N. Matthews ◽  
Rose A. Pesce-Rodriguez ◽  
Shirley A. Liebman
Keyword(s):  
Amino Acids ◽  
Solar System ◽  
Hydrogen Cyanide ◽  
Nitrogen Heterocycles ◽  
Laboratory Studies ◽  
Heterogeneous Solids ◽  
The Many ◽  
Comet Halley ◽  
The Impact ◽  
By Products

AbstractHydrogen cyanide polymers – heterogeneous solids ranging in color from yellow to orange to brown to black – may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orangebrown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia, the color observed depending on the concentration of HCN involved. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to α-amino acids. Black polymers and multimers with conjugated ladder structures derived from HCN could also be formed and might well be the source of the many nitrogen heterocycles, adenine included, observed after pyrolysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter might therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized directly from HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.

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