scholarly journals Growth rate controlled synthesis of hierarchical Bi2S3/In2S3 core/shell microspheres with enhanced photocatalytic activity

2014 ◽  
Vol 4 (1) ◽  
Author(s):  
Juan Zhou ◽  
Guohui Tian ◽  
Yajie Chen ◽  
Yunhan Shi ◽  
Chungui Tian ◽  
...  

Abstract Core/shell heterostructure composite has great potential applications in photocatalytic field because the introduction of core can remarkably improve charge transport and enhance the electron-hole separation. Herein, hierarchical Bi2S3/In2S3 core/shell structured microspheres were prepared via a simple one-pot hydrothermal process based on different growth rate of the two kinds of sulphides. The results showed that, the as-prepared hierarchical Bi2S3/In2S3 core/shell heterostructure exhibits significant visible light photocatalytic activity for degradation of 2, 4-dichlorophenol. The introduction of Bi2S3 core can not only improve charge transport and enhance the electron-hole separation, but also broaden the visible light response. The hierarchical porous folwer-like shell of In2S3 could increase the specific surface area and remarkably enhanced the chemical stability of Bi2S3 against oxidation.

2018 ◽  
Vol 5 (12) ◽  
pp. 3148-3154 ◽  
Author(s):  
Ming-yang Li ◽  
Yu-bin Tang ◽  
Wei-long Shi ◽  
Fang-yan Chen ◽  
Yu Shi ◽  
...  

Core–shell Fe2O3/CuBi2O4 heterojunction photocatalysts with enhanced photocatalytic activity were fabricated through one-step hydrothermal method.


2018 ◽  
Vol 20 (13) ◽  
pp. 3014-3023 ◽  
Author(s):  
Yanan Wang ◽  
Yiqing Zeng ◽  
Xuanyu Chen ◽  
Qiuyang Wang ◽  
Lina Guo ◽  
...  

A novel 3D BiFeWOx/Bi2WO6 (BFW/BWO) composite has been synthesized via a facile one-pot hydrothermal process.


NANO ◽  
2016 ◽  
Vol 11 (01) ◽  
pp. 1650006 ◽  
Author(s):  
Hui Xu ◽  
Min Zeng ◽  
Jing Li ◽  
Fuyun Li

Cr-doped TiO2 core-shell nanospheres have been prepared by a facile one-pot hydrothermal process. The as-prepared Cr–TiO2 nanospheres exhibit not only a high visible light activity, but also an excellent lithium storage capacity. Various characterization methods indicate that Cr[Formula: see text] ions are uniformly distributed into the TiO2 lattice and a doping level emerges in the bandgap of TiO2, which leads to a prominent photocatalytic activity. When the Cr–TiO2 nanospheres are employed as lithium battery electrodes, the high lithium storage capacity of Cr2O3 and the p-type conductivity of TiO2 due to doping may be beneficial to improve the electrochemical performances of these electrodes.


Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3948
Author(s):  
Lingfang Qiu ◽  
Zhiwei Zhou ◽  
Mengfan Ma ◽  
Ping Li ◽  
Jinyong Lu ◽  
...  

Novel visible-light responded aluminosilicophosphate-5 (SAPO-5)/g-C3N4 composite has been easily constructed by thermal polymerization for the mixture of SAPO-5, NH4Cl, and dicyandiamide. The photocatalytic activity of SAPO-5/g-C3N4 is evaluated by degrading RhB (30 mg/L) under visible light illumination (λ > 420 nm). The effects of SAPO-5 incorporation proportion and initial RhB concentration on the photocatalytic performance have been discussed in detail. The optimized SAPO-5/g-C3N4 composite shows promising degradation efficiency which is 40.6% higher than that of pure g-C3N4. The degradation rate improves from 0.007 min−1 to 0.022 min−1, which is a comparable photocatalytic performance compared with other g-C3N4-based heterojunctions for dye degradation. The migration of photo-induced electrons from g-C3N4 to the Al site of SAPO-5 should promote the photo-induced electron-hole pairs separation rate of g-C3N4 efficiently. Furthermore, the redox reactions for RhB degradation occur on the photo-induced holes in the g-C3N4 and Al sites in SAPO-5, respectively. This achievement not only improves the photocatalytic activity of g-C3N4 efficiently, but also broadens the application of SAPOs in the photocatalytic field.


RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2733-2743
Author(s):  
Parisa Talebi ◽  
Harishchandra Singh ◽  
Ekta Rani ◽  
Marko Huttula ◽  
Wei Cao

Surface plasmonic resonance enabled Ni@NiO/NiCO3 core–shell nanostructures as promising photocatalysts for hydrogen evolution under visible light.


2016 ◽  
Vol 69 (1) ◽  
pp. 119 ◽  
Author(s):  
Li Lin ◽  
Ya Wang ◽  
Manhong Huang ◽  
Donghui Chen

Three-dimensional (3D) BiOBr/BiOI hierarchical microspheres were successfully fabricated on the surface of fly ash cenospheres (FACs) via a facile one-pot solvothermal method for the first time. The as-prepared samples were characterized by XRD, SEM, energy-dispersive X-ray spectroscopy, UV–visible diffuse reflectance spectroscopy, and high-resolution transmission electron microscopy. The results indicated that the loaded hierarchical microspheres exhibited a uniform distribution, and some aggregation was observed. These well-dispersed hierarchical microspheres were composed of 2D nanosheets, which possess heterojunction structures. Based on the photodegradation tests examining the removal of rhodamine B from water under visible light irradiation (λ > 420 nm), the photocatalytic activity of BiOB/BiOI/FACs was superior to that of BiOBr/FACs and BiOI/FACs. A proposed mechanism for the enhanced photocatalytic activity displayed by BiOB/BiOI/FACs is discussed.


NANO ◽  
2016 ◽  
Vol 11 (10) ◽  
pp. 1650114 ◽  
Author(s):  
Dan Li ◽  
Jianwei Li ◽  
Caiqin Han ◽  
Xinsheng Zhao ◽  
Haipeng Chu ◽  
...  

Few-layered MoS2 nanostructures were successfully synthesized by a simple hydrothermal method without the addition of any catalysts or surfactants. Their morphology, structure and photocatalytic activity were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, electrochemical impedance spectra and UV-Vis absorption spectroscopy, respectively. These results show that the MoS2 nanostructures synthesized at 180[Formula: see text]C exhibit an optimal visible light photocatalytic activity (99%) in the degradation of Rhodamine B owing to the relatively easier adsorption of pollutants, higher visible light absorption and lower electron–hole pair recombination.


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