scholarly journals Topological defects govern crack front motion and facet formation on broken surfaces

2017 ◽  
Vol 17 (2) ◽  
pp. 140-144 ◽  
Author(s):  
Itamar Kolvin ◽  
Gil Cohen ◽  
Jay Fineberg
Keyword(s):  
Crack Front ◽  
Topological Defects ◽  
Front Motion ◽  
Facet Formation

A Pseudo Five-Fold Symmetrical Ligand Drives Geometric Frustration in Porous Metal-Organic and Hydrogen Bonded Frameworks

2020 ◽  
Author(s):  
Frederik Haase ◽  
Gavin Craig ◽  
Mickaele Bonneau ◽  
kunihisa sugimoto ◽  
Shuhei Furukawa
Keyword(s):  
Topological Defects ◽  
Porous Metal ◽  
Building Blocks ◽  
Structural Features ◽  
Equilibrium Structure ◽  
Sorption Behavior ◽  
Building Unit ◽  
Geometric Frustration ◽  
Secondary Building Units ◽  
Hydrogen Bonded

Reticular framework materials thrive on designability, but unexpected reaction outcomes are crucial in exploring new structures and functionalities. By combining “incompatible” building blocks, we employed geometric frustration in reticular materials leading to emergent structural features. The combination of a pseudo C<sub>5</sub> symmetrical organic building unit based on a pyrrole core, with a C<sub>4</sub> symmetrical copper paddlewheel synthon led to three distinct frameworks by tuning the synthetic conditions. The frameworks show structural features typical for geometric frustration: self-limiting assembly, internally stressed equilibrium structures and topological defects in the equilibrium structure, which manifested in the formation of a hydrogen bonded framework, distorted and broken secondary building units and dangling functional groups, respectively. The influence of geometric frustration on the CO<sub>2</sub> sorption behavior and the discovery of a new secondary building unit shows geometric frustration can serve as a strategy to obtain highly complex porous frameworks.

A Pseudo Five-Fold Symmetrical Ligand Drives Geometric Frustration in Porous Metal-Organic and Hydrogen Bonded Frameworks

2020 ◽  
Author(s):  
Frederik Haase ◽  
Gavin Craig ◽  
Mickaele Bonneau ◽  
kunihisa sugimoto ◽  
Shuhei Furukawa
Keyword(s):  
Topological Defects ◽  
Porous Metal ◽  
Building Blocks ◽  
Structural Features ◽  
Equilibrium Structure ◽  
Sorption Behavior ◽  
Building Unit ◽  
Geometric Frustration ◽  
Secondary Building Units ◽  
Hydrogen Bonded

Reticular framework materials thrive on designability, but unexpected reaction outcomes are crucial in exploring new structures and functionalities. By combining “incompatible” building blocks, we employed geometric frustration in reticular materials leading to emergent structural features. The combination of a pseudo C<sub>5</sub> symmetrical organic building unit based on a pyrrole core, with a C<sub>4</sub> symmetrical copper paddlewheel synthon led to three distinct frameworks by tuning the synthetic conditions. The frameworks show structural features typical for geometric frustration: self-limiting assembly, internally stressed equilibrium structures and topological defects in the equilibrium structure, which manifested in the formation of a hydrogen bonded framework, distorted and broken secondary building units and dangling functional groups, respectively. The influence of geometric frustration on the CO<sub>2</sub> sorption behavior and the discovery of a new secondary building unit shows geometric frustration can serve as a strategy to obtain highly complex porous frameworks.

scholarly journals Defects and perturbation

2021 ◽  
Vol 2021 (4) ◽  
Author(s):  
Enrico M. Brehm
Keyword(s):  
Entanglement Entropy ◽  
Topological Defects ◽  
Field Theories ◽  
Two Dimensional ◽  
Conformal Field Theories ◽  
Minimal Models ◽  
Conformal Field

Abstract We investigate perturbatively tractable deformations of topological defects in two-dimensional conformal field theories. We perturbatively compute the change in the g-factor, the reflectivity, and the entanglement entropy of the conformal defect at the end of these short RG flows. We also give instances of such flows in the diagonal Virasoro and Super-Virasoro Minimal Models.

scholarly journals Properties of twisted topological defects in 2D nematic liquid crystals

Soft Matter ◽  
2021 ◽  
Author(s):  
Daniel Pearce ◽  
Karsten Kruse
Keyword(s):  
Liquid Crystals ◽  
Nematic Liquid Crystals ◽  
Topological Defects ◽  
Two Dimensional

Topological defects are one of the most conspicuous features of liquid crystals. In two dimensional nematics, they have been shown to behave effectively as particles with both, charge and orientation,...

scholarly journals Thermal Delamination Modelling and Evaluation of Aluminium–Glass Fibre-Reinforced Polymer Hybrid

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 492
Author(s):  
Zhen Pei Chow ◽  
Zaini Ahmad ◽  
King Jye Wong ◽  
Seyed Saeid Rahimian Koloor ◽  
Michal Petrů
Keyword(s):  
Crack Front ◽  
Cohesive Zone ◽  
Experimental Tests ◽  
Mode I ◽  
Mode Ii ◽  
Cohesive Model ◽  
Reinforced Polymer ◽  
Glass Fibre Reinforced Polymer ◽  
Fibre Reinforced Polymer ◽  
Glass Fibre Reinforced

This paper aims to propose a temperature-dependent cohesive model to predict the delamination of dissimilar metal–composite material hybrid under Mode-I and Mode-II delamination. Commercial nonlinear finite element (FE) code LS-DYNA was used to simulate the material and cohesive model of hybrid aluminium–glass fibre-reinforced polymer (GFRP) laminate. For an accurate representation of the Mode-I and Mode-II delamination between aluminium and GFRP laminates, cohesive zone modelling with bilinear traction separation law was implemented. Cohesive zone properties at different temperatures were obtained by applying trends of experimental results from double cantilever beam and end notched flexural tests. Results from experimental tests were compared with simulation results at 30, 70 and 110 °C to verify the validity of the model. Mode-I and Mode-II FE models compared to experimental tests show a good correlation of 5.73% and 7.26% discrepancy, respectively. Crack front stress distribution at 30 °C is characterised by a smooth gradual decrease in Mode-I stress from the centre to the edge of the specimen. At 70 °C, the entire crack front reaches the maximum Mode-I stress with the exception of much lower stress build-up at the specimen’s edge. On the other hand, the Mode-II stress increases progressively from the centre to the edge at 30 °C. At 70 °C, uniform low stress is built up along the crack front with the exception of significantly higher stress concentrated only at the free edge. At 110 °C, the stress distribution for both modes transforms back to the similar profile, as observed in the 30 °C case.

Topological defects involving Fe/N co-doped mesoporous carbon nanosheets as novel electrocatalysts for the oxygen reduction reaction and Zn–air batteries

Nanoscale ◽  
2021 ◽  
Author(s):  
Junjie Ding ◽  
Dongchuang Wu ◽  
Senhe Huang ◽  
Chenbao Lu ◽  
Yu Chen ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Topological Defects ◽  
Reduction Reaction ◽  
Defect Engineering ◽  
Carbon Nanosheets ◽  
Renewable Energy Technologies ◽  
Central Focus ◽  
Energy Technologies ◽  
Co Doped

Developing effective electrocatalysts for oxygen reduction reaction is of great significance for clean and renewable energy technologies, such as metal–air batteries and fuel cells. Defect engineering is the central focus...

scholarly journals Wavefront dislocations reveal the topology of quasi-1D photonic insulators

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Clément Dutreix ◽  
Matthieu Bellec ◽  
Pierre Delplace ◽  
Fabrice Mortessagne
Keyword(s):  
Local Density ◽  
Topological Defects ◽  
Wave Functions ◽  
Topological Classification ◽  
Local Density Of States ◽  
Topological Phase Transition ◽  
Interference Fringes ◽  
Classical Wave ◽  
Phase Singularities

AbstractPhase singularities appear ubiquitously in wavefields, regardless of the wave equation. Such topological defects can lead to wavefront dislocations, as observed in a humongous number of classical wave experiments. Phase singularities of wave functions are also at the heart of the topological classification of the gapped phases of matter. Despite identical singular features, topological insulators and topological defects in waves remain two distinct fields. Realising 1D microwave insulators, we experimentally observe a wavefront dislocation – a 2D phase singularity – in the local density of states when the systems undergo a topological phase transition. We show theoretically that the change in the number of interference fringes at the transition reveals the topological index that characterises the band topology in the insulator.

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