Polymer chain dynamics and glass transition in athermal polymer/nanoparticle mixtures

2009 ◽  
Vol 8 (2) ◽  
pp. 139-143 ◽  
Author(s):  
Hyunjoon Oh ◽  
Peter F. Green
1987 ◽  
Vol 20 (6) ◽  
pp. 1362-1368 ◽  
Author(s):  
Peter H. Verdier ◽  
David E. Kranbuehl

Polymers ◽  
2018 ◽  
Vol 10 (6) ◽  
pp. 590 ◽  
Author(s):  
Qingliang Song ◽  
Yongyun Ji ◽  
Shiben Li ◽  
Xianghong Wang ◽  
Linli He

Polymer ◽  
2009 ◽  
Vol 50 (23) ◽  
pp. 5456-5466 ◽  
Author(s):  
Steven J. Teertstra ◽  
Wai Yau Lin ◽  
Mario Gauthier ◽  
Mark Ingratta ◽  
Jean Duhamel

2021 ◽  
Vol 87 (11) ◽  
pp. 26-32
Author(s):  
A. A. Pushkareva ◽  
O. A. Vozisova ◽  
M. A. Leuhina ◽  
L. L. Khimenko ◽  
A. N. Ilyin ◽  
...  

The oligomer microstructure, reflecting the configuration of the elementary units (cis-1,4-, trans-1,4-, and 1,2-) and their distribution order in the polymer chain, decisively affects the physicochemical and rheological properties of the oligomer. Parameters of microstructure-dependent transitions (glass transition) characterize the oligomer behavior under abnormal low-temperature conditions. We present the results of studying the microstructure of low-molecular rubbers. We determined the content of cis-1,4- and trans-1,4-structural links of poly-divinyl-isoprene-urethane-epoxy oligomer. The structure of polybutadiene HTPB-IV with terminal hydroxyl groups was analyzed using NMR and IR spectroscopy. A comparative analysis of the microstructure of the poly-divinyl-isoprene-urethane-epoxy oligomer and low molecular rubbers with a known content of structural units has been carried out. The obtained results can be used to obtain oligomers with the desired physicochemical and mechanical properties.


2013 ◽  
Vol 46 (6) ◽  
pp. 2235-2240 ◽  
Author(s):  
Kevin A. Masser ◽  
Hongyi Yuan ◽  
Alamgir Karim ◽  
Chad R. Snyder
Keyword(s):  

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