scholarly journals Intrinsic electrical conductivity of nanostructured metal-organic polymer chains

2013 ◽  
Vol 4 (1) ◽  
Author(s):  
Cristina Hermosa ◽  
Jose Vicente Álvarez ◽  
Mohammad-Reza Azani ◽  
Carlos J. Gómez-García ◽  
Michelle Fritz ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Polymer Chains ◽  
Organic Polymer ◽  
Metal Organic ◽  
Nanostructured Metal

Semiconducting Metal–Organic Polymer Nanosheets for a Photoinvolved Li–O2 Battery under Visible Light

2021 ◽  
Vol 143 (4) ◽  
pp. 1941-1947
Author(s):  
Qingliang Lv ◽  
Zhuo Zhu ◽  
Shuo Zhao ◽  
Liubin Wang ◽  
Qing Zhao ◽  
...  
Keyword(s):  
Visible Light ◽  
Organic Polymer ◽  
Metal Organic

scholarly journals Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks

2015 ◽  
Vol 137 (5) ◽  
pp. 1774-1777 ◽  
Author(s):  
Sarah S. Park ◽  
Eric R. Hontz ◽  
Lei Sun ◽  
Christopher H. Hendon ◽  
Aron Walsh ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Metal Organic Frameworks ◽  
Metal Organic

A new three-dimensional 4, 6-connected self-catenated net constructed from the [V8O23]6− polyoxoanions and metal–organic polymer

2010 ◽  
Vol 13 (3) ◽  
pp. 384-387 ◽  
Author(s):  
Yan-Fei Qi ◽  
Chun-Ping Lv ◽  
Yang-Guang Li ◽  
En-Bo Wang ◽  
Juan Li ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Organic Polymer ◽  
Metal Organic

On-surface synthesis: a promising strategy toward the encapsulation of air unstable ultra-thin 2D materials

Nanoscale ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 3799-3804 ◽  
Author(s):  
Qiang Li ◽  
Yinghe Zhao ◽  
Jiyuan Guo ◽  
Qionghua Zhou ◽  
Qian Chen ◽  
...  
Keyword(s):  
2D Materials ◽  
Organic Polymer ◽  
Effective Strategy ◽  
Promising Strategy ◽  
Metal Organic

The on-surface synthesis of a 2D nonporous metal organic polymer in solutions is proposed as a facile and effective strategy toward the satisfactory passivation of air unstable ultrathin 2D materials.

scholarly journals Nickel Salicylaldoxime-Based Coordination Polymer as a Cathode for Lithium-Ion Batteries

Energies ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2480
Author(s):  
Evgenii V. Beletskii ◽  
Daniil A. Lukyanov ◽  
Petr S. Vlasov ◽  
Andrei N. Yankin ◽  
Arslan B. Atangulov ◽  
...  
Keyword(s):  
Energy Storage ◽  
Cathode Materials ◽  
Lithium Ion ◽  
Building Blocks ◽  
Organic Polymer ◽  
Galvanostatic Charge ◽  
X Ray ◽  
Storage Performance ◽  
Redox Active ◽  
Metal Organic

Conjugated coordination polymers attract attention as materials for electrochemical energy storage, mostly as cathode materials for supercapacitors. Faradaic capacity may be introduced to such materials using redox-active building blocks, metals, or ligands. Using this strategy, a novel hybrid cathode material was developed based on a Ni2+ metal-organic polymer. The proposed material, in addition to double-layer capacitance, shows high pseudocapacitance, which arises from the contributions of both the metal center and ligand. A tailoring strategy in the ligand design allows us to minimize the molecular weight of the ligand, which increases its gravimetric energy. According to computational results, the ligand makes the prevailing contribution to the pseudocapacitance of the material. Different approaches to metal–organic polymer (MOP) synthesis were implemented, and the obtained materials were examined by FTIR, Raman spectroscopy, powder XRD, SEM/EDX (energy-dispersive X-ray spectroscopy), TEM, and thermal analysis. Energy-storage performance was comparatively studied with cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD). As a result, materials with an excellent discharge capacity were obtained, reaching the gravimetric energy density of common inorganic cathode materials.

scholarly journals Advances in Nanostructured Metal-Encapsulated Porous Organic-Polymer Composites for Catalyzed Organic Chemical Synthesis

Catalysts ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 492 ◽  
Author(s):  
Wilhemina Sebati ◽  
Suprakas Ray
Keyword(s):  
Binding Sites ◽  
Heterogeneous Catalysts ◽  
Acid Catalysis ◽  
High Surface ◽  
Organic Polymer ◽  
Organic Chemical ◽  
Characterization Methods ◽  
Catalytic Activities ◽  
Surface Areas ◽  
Nanostructured Metal

Porous organic polymers (POPs) are of growing research interest owing to their high surface areas, stabilities, controllable chemical configurations, and tunable pore volumes. The molecular nanoarchitecture of POP provides metal or metal oxide binding sites, which is promising for the development of advanced heterogeneous catalysts. This article highlights the development of numerous kinds of POPs and key achievements to date, including their functionalization and incorporation of nanoparticles into their framework structures, characterization methods that are predominantly in use for POP-based materials, and their applications as catalysts in several reactions. Scientists today are capable of preparing POP-based materials that show good selectivity, activity, durability, and recoverability, which can help overcome many of the current environmental and industrial problems. These POP-based materials exhibit enhanced catalytic activities for diverse reactions, including coupling, hydrogenation, and acid catalysis.

Sign in / Sign up

Export Citation Format

Share Document