scholarly journals Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Pengfei Zhang ◽  
Li Wang ◽  
Shize Yang ◽  
Jennifer A. Schott ◽  
Xiaofei Liu ◽  
...  
Catalysts ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 23
Author(s):  
Farzeen Sakina ◽  
Carlos Fernandez-Ruiz ◽  
Jorge Bedia ◽  
Luisa Gomez-Sainero ◽  
Richard Baker

Ordered mesoporous carbon (OMC) was employed as a support for palladium nanoparticles in catalysts for the gas phase hydrodechlorination (HDC) of trichloromethane (TCM). 1 wt% palladium was incorporated using three methods: incipient wetness (IW); a dilute solution (DS) method; and a solid-liquid (SL) method. The effect of the preparation method on catalyst structure and activity was investigated. Catalyst composition and nanostructure were studied using gas physisorption, high specification transmission electron microscopy and X-ray photoelectron spectroscopy. Catalytic conversion and product selectivities were determined in steady-state activity tests at temperatures between 70 and 300 °C. Two of the catalysts (IW and DS) showed excellent dispersion of fine Pd nanoparticles of average diameter ~2 nm. These materials showed excellent activity for HDC of TCM which compares favourably with the performance reported for Pd on amorphous carbon catalysts. In addition, they showed relatively high selectivities to the more valuable higher hydrocarbons. However, the SL method gave rise to catalysts with larger particles (~3 nm) and a less uniform palladium distribution. This resulted in lower conversion and lower selectivities to higher hydrocarbons and in more severe catalyst deactivation at the highest reaction temperatures.


2020 ◽  
Vol 12 (14) ◽  
pp. 16541-16547
Author(s):  
Qiang Zhang ◽  
Liangting Cai ◽  
Gaozhan Liu ◽  
Qihua Li ◽  
Miao Jiang ◽  
...  

2016 ◽  
Vol 18 (24) ◽  
pp. 6637-6647 ◽  
Author(s):  
Paul Dornath ◽  
Stephen Ruzycky ◽  
Shintaro Pang ◽  
Lili He ◽  
Paul Dauenhauer ◽  
...  

The hydrolysis of cellulose and β(1 → 4) oligosaccharides on carbon catalysts is a promising approach for the selective production of glucose from cellulose and its derivatives.


Carbon ◽  
2018 ◽  
Vol 131 ◽  
pp. 102-110 ◽  
Author(s):  
Zhuoran Wang ◽  
Naftali Opembe ◽  
Takeshi Kobayashi ◽  
Nicholas C. Nelson ◽  
Igor I. Slowing ◽  
...  

ChemCatChem ◽  
2018 ◽  
Vol 10 (15) ◽  
pp. 3299-3304 ◽  
Author(s):  
Pengfei Zhang ◽  
Nanqing Chen ◽  
Dong Chen ◽  
Shize Yang ◽  
Xiaofei Liu ◽  
...  

2019 ◽  
Vol 25 (36) ◽  
pp. 8494-8498 ◽  
Author(s):  
Li Wang ◽  
Jiahua Zhao ◽  
Pengfei Zhang ◽  
Shize Yang ◽  
Wangcheng Zhan ◽  
...  

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