scholarly journals A monotopic aluminum telluride with an Al=Te double bond stabilized by N-heterocyclic carbenes

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Daniel Franz ◽  
Tibor Szilvási ◽  
Elisabeth Irran ◽  
Shigeyoshi Inoue
Keyword(s):  
Double Bond ◽  
Heterocyclic Carbenes

Stabilization of a bismuth–bismuth double bond by anionic N-heterocyclic carbenes

2021 ◽  
Vol 50 (4) ◽  
pp. 1202-1205
Author(s):  
Luong Phong Ho ◽  
Matthias Tamm
Keyword(s):  
Double Bond ◽  
Heterocyclic Carbenes

Anionic N-heterocyclic carbenes have been employed for the isolation of the first dicarbene–dibismuth complex; the resulting dibismuthene features a trans-bent geometry with a Bi–Bi double bond and short intramolecular Bi–Cipso contacts.

Cleavage of a P=P Double Bond Mediated by N-Heterocyclic Carbenes

2017 ◽  
Vol 56 (21) ◽  
pp. 5765-5769 ◽  
Author(s):  
Naoki Hayakawa ◽  
Kazuya Sadamori ◽  
Shota Tsujimoto ◽  
Miho Hatanaka ◽  
Tomonari Wakabayashi ◽  
...  
Keyword(s):  
Double Bond ◽  
Heterocyclic Carbenes

Multiple bonds between lead atoms and short bonds between transition metals

2012 ◽  
Vol 85 (4) ◽  
pp. 649-659 ◽  
Author(s):  
Shigeru Nagase
Keyword(s):  
Double Bond ◽  
Transition Metal ◽  
Transition Metals ◽  
Triple Bond ◽  
Membered Ring ◽  
Heterocyclic Carbenes ◽  
Multiple Bonds ◽  
Ring Complexes

The heaviest analogues of alkynes are investigated to realize a short triple bond between Pb atoms. For a short double bond between Pb atoms, the Pb2 molecule stabilized by dative N-heterocyclic carbenes is investigated. For unsupported and supported short bonds between transition metals, two-coordinate transition-metal and bicyclic four-membered ring complexes are investigated.

Cleavage of a P=P Double Bond Mediated by N-Heterocyclic Carbenes

2017 ◽  
Vol 129 (21) ◽  
pp. 5859-5863 ◽  
Author(s):  
Naoki Hayakawa ◽  
Kazuya Sadamori ◽  
Shota Tsujimoto ◽  
Miho Hatanaka ◽  
Tomonari Wakabayashi ◽  
...  
Keyword(s):  
Double Bond ◽  
Heterocyclic Carbenes

THE THYMOLYTIC ACTIVITY OF 6- AND 9-HALOCORTICOIDS AND RELATED STEROIDS

1965 ◽  
Vol 49 (2) ◽  
pp. 262-270 ◽  
Author(s):  
Ralph I. Dorfman ◽  
P. G. Holton ◽  
Fred A. Kind
Keyword(s):  
Double Bond ◽  
Subcutaneous Injection ◽  
Fluocinolone Acetonide ◽  
Relative Potency ◽  
Subcutaneous Route ◽  
Adrenalectomized Rats

ABSTRACT Adrenalectomized rats were used for the determination of the relative potency of various 6- and 9-halo substituted corticoids administered subcutaneously or by gavage using thymus weightas the endpoint. By subcutaneous injection, fluocinolone acetonide was the most active corticoid at 700 times that of cortisol. This compound was also the most active corticoid by the gavage route and was judged to be 570 times as active as the standard cortisol. The introduction of the 16,17-acetonide and 16,17-acetone 21-acetate groups into 17α,21-dihydroxy-9α,11β-dichloropregna-1,4-diene-3,20-dione increased the activity by a factor of 42 and 100, respectively. The introduction of the δ1 double bond into 6α-fluoroprogesterone 16,17-acetonide caused an increase of 10-fold in thymolytic activity assessed by the subcutaneous route

Aryl-substituted Triarsiranes: Synthesis and Reactivity

2020 ◽  
Author(s):  
André Schumann ◽  
Jonas Bresien ◽  
Malte Fischer ◽  
Christian Hering-Junghans
Keyword(s):  
Organic Chemistry ◽  
Electronic Structure ◽  
Heterocyclic Carbenes ◽  
Synthetic Approaches ◽  
Inorganic And Organic

Cyclotriarsanes are rare and limited synthetic approaches have hampered reactivity studies on these systems. Described in here is a scalable synthetic protocol towards (AsAr)<sub>3</sub> (Ar = Dip, 2,6-<sup>i</sup>Pr<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>; Tip, 2,4,6-<sup>i</sup>Pr<sub>3</sub>-C<sub>6</sub>H<sub>2</sub>), which allowed to study their reactivity towards [Cp<sub>2</sub>Ti(C<sub>2</sub>(SiMe<sub>3</sub>)<sub>2</sub>], affording titanocene diarsene complexes and towards N-heterocyclic carbenes (NHCs) to give straightforward access to a variety of NHC-arsinidene adducts. The electronic structure of the titanium diarsene complxes has been studied and they are best described as Ti(IV) species with a doubly reduced As<sub>2</sub>Ar<sub>2</sub> ligand. These findings will make (AsAr)<sub>3</sub> valuable precursors in the synthetic inorganic and organic chemistry.

TRIGLYCERIDE COMPOSITION OF SIXTEEN STRAINS OF MARINE DIATOM

2013 ◽  
Vol 5 (1) ◽  
Author(s):  
Lily M.G. Panggabean ◽  
Abdullah Rasyid ◽  
Zarrah Duniani ◽  
Yana Meliana ◽  
Indah Kurniasih
Keyword(s):  
Mass Spectrometry ◽  
Fatty Acid ◽  
Double Bond ◽  
Unsaturated Fatty Acid ◽  
Ion Trap ◽  
Carbon Chain ◽  
Highly Unsaturated Fatty Acid ◽  
Marine Diatom ◽  
Ion Trap Mass Spectrometry ◽  
Spectra Analysis

Trigliceride or triacylglicerol (TAG) composition in crude oil of sixteen strain of marine diatom has been detected by spectra analyses on an Electrospray - Ion Trap – Mass Spectrometry (ESI-IT-MS) HCT Bruker-Daltonic GmbH instrument with AgNO3 used as coordination ionization agent. Biomass samples of each microalga strain were taken from early and late stationary cultures in f/2 enriched seawater and algal oils were extracted according to Bligh and Dyer. Results from spectra analysis showed that P-Pt-P (C16:0-C16:1-C16:0) were distinguished in TAG from diatom strains Chaetoceros sp.1, Chaetoceros sp.2, Thalasiossira sp.1, Thalasiossira sp.2, Thalasiossira sp.3, Navicula sp. 1, Navicula sp. 2, Navicula sp. 3, Navicula sp. 4, Nitzschia sp. 2 and Amphora sp. In contrast, TAGs in Melosira sp. included P-P-P (C16:0-C16:0-C16:0) and P-P-O (C16:0-C16:0-C18:1) were identified. TAGs from Chaetoceros sp. were the most varies among samples, i.e. P-Pt-P (C16:0-C16:1-C16:0), A-P-M (C20:4-C16:0-C14:0), P-Pt-Lt (C16:0-C16:1-C18:3), P-Pt-A (C16:0-C16:1-C20:4), D-P-P (C22:6-C16:0-C16:0), A-Ln-P (C20:4-C18:2-C16:0). Various TAGs were also detected in Nitzschia sp.2, i.e. P-Pt-M (C16:0-C16:1-C14:0), P-Pt-P (C16:0-C16:1-C16:0), P-Pt-S (C16:0-C16:1-C18:0), P-Pt-A (C16:0-C16:1-C20:4). TAGs composition in Skeletonema strains that similar to those in Nitzschia sp.1 has longer carbon, i.e. P-P-O (C16:0-C16:0-C18:1), P-O-O (C16:0-C18:1-C18:1) and O-O-O (C18:1-C18:1-C18:1). TAGs with longer carbon chain and more double bond including highly unsaturated fatty acid C20:4 were increased with culture age in diatoms Chaetoceros sp.1, Chaetoceros sp.2, Thalasiossira sp.2, Navicula sp.1 and Nitzschia sp. 2.Keywords: diatom, TAG, ESI-IT-MS, f/2, early and late stationary

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