An AAAA–DDDD quadruple hydrogen-bond array

2011 ◽  
Vol 3 (3) ◽  
pp. 244-248 ◽  
Author(s):  
Barry A. Blight ◽  
Christopher A. Hunter ◽  
David A. Leigh ◽  
Hamish McNab ◽  
Patrick I. T. Thomson
Keyword(s):  
Hydrogen Bond ◽  
Quadruple Hydrogen Bond

Solvent-mediated pseudo-quadruple hydrogen-bond motifs in three lamotrigine–carboxylic acid complexes

2013 ◽  
Vol 69 (10) ◽  
pp. 1164-1169 ◽  
Author(s):  
Balasubramanian Sridhar ◽  
Jagadeesh Babu Nanubolu ◽  
Krishnan Ravikumar
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Carboxylic Acid ◽  
Proton Transfer ◽  
Antiepileptic Drug ◽  
Carboxylic Acids ◽  
Solvent Interactions ◽  
Partial Transfer ◽  
Quadruple Hydrogen Bonding ◽  
Quadruple Hydrogen Bond

Lamotrigine, an antiepileptic drug, has been complexed with three aromatic carboxylic acids. All three compounds crystallize with the inclusion ofN,N-dimethylformamide (DMF) solvent,viz.lamotriginium [3,5-diamino-6-(2,3-dichlorophenyl)-1,2,4-triazin-2-ium] 4-iodobenzoateN,N-dimethylformamide monosolvate, C9H8Cl2N5+·C7H4IO2−·C3H7NO, (I), lamotriginium 4-methylbenzoateN,N-dimethylformamide monosolvate, C9H7Cl2N5+·C8H8O2−·C3H7NO, (II), and lamotriginium 3,5-dinitro-2-hydroxybenzoateN,N-dimethylformamide monosolvate, C9H8Cl2N5+·C7H3N2O7−·C3H7NO, (III). In all three structures, proton transfer takes place from the acid to the lamotrigine molecule. However, in (I) and (II), the acidic H atom is disordered over two sites and there is only partial transfer of the H atom from O to N. In (III), the corresponding H atom is ordered and complete proton transfer has occurred. Lamotrigine–lamotrigine, lamotrigine–acid and lamotrigine–solvent interactions are observed in all three structures and they thereby exhibit isostructurality. The DMF solvent extends the lamotrigine–lamotrigine dimers into a pseudo-quadruple hydrogen-bonding motif.

Molecular Conductance through a Quadruple-Hydrogen-Bond-Bridged Supramolecular Junction

2016 ◽  
Vol 55 (40) ◽  
pp. 12393-12397 ◽  
Author(s):  
Lin Wang ◽  
Zhong-Liang Gong ◽  
Shu-Ying Li ◽  
Wenjing Hong ◽  
Yu-Wu Zhong ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Molecular Conductance ◽  
Quadruple Hydrogen Bond

scholarly journals AAAA-DDDD Quadruple Hydrogen-Bond Arrays Featuring NH···N and CH···N Hydrogen Bonds

2013 ◽  
Vol 135 (26) ◽  
pp. 9939-9943 ◽  
Author(s):  
David A. Leigh ◽  
Craig C. Robertson ◽  
Alexandra M. Z. Slawin ◽  
Patrick I. T. Thomson
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Quadruple Hydrogen Bond

ChemInform Abstract: Self-Assembled Multiporphyrin Arrays Mediated by Self-Complementary Quadruple Hydrogen Bond Motifs.

ChemInform ◽  
2001 ◽  
Vol 32 (19) ◽  
pp. no-no
Author(s):  
Charles Michael Drain ◽  
Xinxu Shi ◽  
Tatjana Milic ◽  
Fotis Nifiatis
Keyword(s):  
Hydrogen Bond ◽  
Self Assembled ◽  
Quadruple Hydrogen Bond

Self-assembled multiporphyrin arrays mediated by self-complementary quadruple hydrogen bond motifs

2001 ◽  
pp. 287-288 ◽  
Author(s):  
Charles Michael Drain ◽  
Xinxu Shi ◽  
Tatjana Milic ◽  
Fotis Nifiatis
Keyword(s):  
Hydrogen Bond ◽  
Self Assembled ◽  
Quadruple Hydrogen Bond

Cyclic Tetramer of a Metalloporphyrin Based on a Quadruple Hydrogen Bond

2006 ◽  
Vol 8 (11) ◽  
pp. 2225-2228 ◽  
Author(s):  
Haruki Ohkawa ◽  
Akihiro Takayama ◽  
Satoshi Nakajima ◽  
Hiroyuki Nishide
Keyword(s):  
Hydrogen Bond ◽  
Quadruple Hydrogen Bond

Synthesis and properties of polystyrene-based polyHIPEs reinforced with quadruple hydrogen bond functionality

2015 ◽  
Vol 22 (8) ◽  
Author(s):  
Guanghui Jing ◽  
Haojie Yu ◽  
Li Wang ◽  
Jie Shan ◽  
Jin Huang ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Quadruple Hydrogen Bond

The AAAA·DDDD Hydrogen Bond Dimer. Synthesis of a Soluble Sulfurane as AAAA Domain and Generation of a DDDD Counterpart

2009 ◽  
Vol 62 (11) ◽  
pp. 1550 ◽  
Author(s):  
Jörg Taubitz ◽  
Ulrich Lüning
Keyword(s):  
Hydrogen Bond ◽  
Complex Formation ◽  
Association Constant ◽  
Recognition Site ◽  
Nmr Titration ◽  
Quadruple Hydrogen Bond

Sulfurane 5b with solubility enhancing substituents has been synthesized to be used as an AAAA recognition site in quadruple hydrogen bond heterodimers. A complementary DDDD partner [4b + H+] has been generated from a DDAD domain 4b by protonation. The association constant for the heterodimer complex formation has been determined by NMR titration in chloroform.

Generation-Independent Dimerization Behavior of Quadruple Hydrogen-Bond-Containing Oligoether Dendrons

2006 ◽  
Vol 8 (9) ◽  
pp. 1811-1814 ◽  
Author(s):  
Chun-Ho Wong ◽  
Hak-Fun Chow ◽  
Sin-Kam Hui ◽  
Kong-Hung Sze
Keyword(s):  
Hydrogen Bond ◽  
Quadruple Hydrogen Bond

scholarly journals SYNTHESIS AND PERFORMANCE OF POLYURETHANE WITH QUADRUPLE HYDROGEN BOND UNITS

2012 ◽  
Vol 012 (3) ◽  
pp. 318-325 ◽  
Author(s):  
Zhi-cheng Feng ◽  
Bo Zhu ◽  
Hong-xi Yao ◽  
Ming-jun Wang ◽  
Xiao-hui Yang
Keyword(s):  
Hydrogen Bond ◽  
And Performance ◽  
Quadruple Hydrogen Bond
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