Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism

Nature ◽  
1992 ◽  
Vol 359 (6397) ◽  
pp. 710-712 ◽  
Author(s):  
C. T. Kresge ◽  
M. E. Leonowicz ◽  
W. J. Roth ◽  
J. C. Vartuli ◽  
J. S. Beck
2012 ◽  
Vol 258 (22) ◽  
pp. 8895-8901 ◽  
Author(s):  
Hongping Pu ◽  
Caiyun Han ◽  
Hua Wang ◽  
Siwei Xu ◽  
Liuyi Zhang ◽  
...  

2020 ◽  
Vol 39 (6) ◽  
Author(s):  
Ta‐Wui Cheng ◽  
Ya‐Wen Lin ◽  
Kang‐Wei Lo ◽  
Chiao‐Ying Chen ◽  
Kae‐Long Lin

Author(s):  
Marcela N. Barbosa ◽  
Maria J. F. Costa ◽  
Maricele N. Barbosa ◽  
Valter J. Fernandes Jr. ◽  
Giancarlo R. Salazar-Banda ◽  
...  

The adsorption of carbon dioxide on amino silanes-functionalized MCM-41 and SBA-15 materials is reported. The functionalization of mesoporous silicas was made by post-synthesis method, by impregnation of 3-aminopropyltriethoxysilane. The obtained materials were characterized by X-ray diffraction, scanning and transmission electron microscopies, nitrogen adsorption-desorption and X-ray photoelectron spectroscopy measurements. The carbon dioxide adsorption capacities for the samples were carried out under ambient pressures. The obtained results evidenced that amino-silanes with a terminal amine (–NH2) were functionalized through covalent coupling of this group on the surface of the channels in the ordered mesoporous silica, meaning that the amine is anchored on the surface of the bigger pores of the MCM-41 and SBA-15 support. For functionalized materials, the CO2 adsorption capacity of the AMCM-41 increased from 0.18 to 1.1 mmol·g−1, whereas for ASBA-15, it was from 0.6 to 1.8 mmol·g−1. The Lagergren kinetic algorithms were applied in order to validate the obtained results, evidencing the enhanced carbon dioxide adsorption capacity and stability of the functionalized ordered mesoporous molecular sieves.


2013 ◽  
Vol 179 ◽  
pp. 258-264 ◽  
Author(s):  
Elena G. Kovaleva ◽  
Leonid S. Molochnikov ◽  
Elena L. Golovkina ◽  
Martin Hartmann ◽  
Igor. A. Kirilyuk ◽  
...  

1999 ◽  
Vol 2 (3) ◽  
pp. 173-179 ◽  
Author(s):  
Rogério A.A. Melo ◽  
Marcus V. Giotto ◽  
João Rocha ◽  
Ernesto A. Urquieta-González

1992 ◽  
Vol 114 (27) ◽  
pp. 10834-10843 ◽  
Author(s):  
J. S. Beck ◽  
J. C. Vartuli ◽  
W. J. Roth ◽  
M. E. Leonowicz ◽  
C. T. Kresge ◽  
...  

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