Determination of the Bimolecular Rate Constant for the Reaction Between Organophosphorous Inhibitors and Esterases in the Presence of Substrate

Nature ◽  
1963 ◽  
Vol 198 (4880) ◽  
pp. 551-553 ◽  
Author(s):  
A. R. MAIN ◽  
W. C. DAUTERMAN
Keyword(s):  
Rate Constant ◽  
Bimolecular Rate Constant

Determination of the Bimolecular Rate Constant of Polyacrylamide and Hydroxyl Radicals

2015 ◽  
Vol 44 (2) ◽  
pp. 220-222
Author(s):  
Sonia N. Nomi ◽  
Yumi Higaonna ◽  
Tomoha Kasaba ◽  
Takemitsu Arakaki
Keyword(s):  
Hydroxyl Radicals ◽  
Rate Constant ◽  
Bimolecular Rate Constant

Determination of rate constants of redox reactions of second order from current-less potential-time curves by a simplified graphical-numerical method

1983 ◽  
Vol 48 (5) ◽  
pp. 1358-1367 ◽  
Author(s):  
Antonín Tockstein ◽  
František Skopal
Keyword(s):  
Numerical Method ◽  
Explicit Form ◽  
Rate Constant ◽  
Optimization Algorithm ◽  
Rate Constants ◽  
Redox Reactions ◽  
Second Order ◽  
Wide Region ◽  
Recurrent Formula

A method for constructing curves is proposed that are linear in a wide region and from whose slopes it is possible to determine the rate constant, if a parameter, θ, is calculated numerically from a rapidly converging recurrent formula or from its explicit form. The values of rate constants and parameter θ thus simply found are compared with those found by an optimization algorithm on a computer; the deviations do not exceed ±10%.

Regeneration Mechanism Studied by Potential-Time Response to Sinusoidal Current-Time Function

1997 ◽  
Vol 62 (10) ◽  
pp. 1511-1526
Author(s):  
María-Luisa Alcaraz ◽  
Ángela Molina
Keyword(s):  
Kinetic Parameters ◽  
Rate Constant ◽  
Theoretical Study ◽  
Time Function ◽  
Time Response ◽  
Current Time ◽  
Regeneration Mechanism ◽  
Sinusoidal Current ◽  
Regeneration Processes

A theoretical study of the potential-time response to sinusoidal current applied to static and dynamic electrodes for regeneration processes is presented. Methods for determination of the regeneration fraction, rate constant of the chemical reaction and heterogeneous kinetic parameters are proposed.

Direct determination of the rate constant for the reaction CO + N2O → CO2 + N2

1985 ◽  
Vol 122 (5) ◽  
pp. 489-492 ◽  
Author(s):  
Nobuyuki Fujii ◽  
Tomohisa Kakuda ◽  
Takeo Sugiyama ◽  
Hajime Miyama
Keyword(s):  
Rate Constant ◽  
Direct Determination
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