Relationship between Viscous Flow and Diffusion

Nature ◽  
1962 ◽  
Vol 195 (4840) ◽  
pp. 482-483 ◽  
Author(s):  
F. A. L. DULLIEN
Keyword(s):  
2013 ◽  
Vol 2013.21 (0) ◽  
pp. _409-1_-_409-3_
Author(s):  
Fumihiro WAKAI ◽  
Yutaka SHINODA ◽  
Takashi AKATSU ◽  
Kenneth Brakke

1971 ◽  
Vol 42 (11) ◽  
pp. 4183-4187 ◽  
Author(s):  
R. A. Pasternak ◽  
M. V. Christensen

1992 ◽  
Vol 46 (17) ◽  
pp. 10701-10705 ◽  
Author(s):  
M. Y. Lin ◽  
B. Abeles ◽  
J. S. Huang ◽  
H. E. Stasiewski ◽  
Q. Zhang
Keyword(s):  

AIChE Journal ◽  
1989 ◽  
Vol 35 (8) ◽  
pp. 1370-1375 ◽  
Author(s):  
Gülşen Do??u ◽  
Ahmet Pekediz ◽  
Timur Do??u

1942 ◽  
Vol 15 (3) ◽  
pp. 537-544 ◽  
Author(s):  
Richard M. Barrer

Abstract Some properties of flow of solutes in and through rubbers are outlined. These properties indicate that, due to fluctuations of thermal energy, activated zones exist in certain polymers, of which viscous flow and diffusion are a consequence. A simple statistics of activated zones has been given, and from it equations are obtained for ΣN, D, Ds, and η, denoting respectively the total number of activated zones in rubber, the diffusion constant of simple solutes in the polymer, the self-diffusion constant of rubber, and its viscosity. Functional relations are predicted between log Do, log ηo, or ΔS* (the entropy of activation) and the Arrhenius energy of activation for diffusion or viscous flow. The available data clearly demonstrate this relationship. They also indicate no discontinuity between rubbers and liquids as diffusion media.


1981 ◽  
Vol 59 (14) ◽  
pp. 2170-2172 ◽  
Author(s):  
Robert A. Stairs

A correlation is proposed between the ratios: Y = πΔV≠/E(p)≠ (where π is the internal pressure of a liquid, ΔV≠ the volume of activation RT(∂ ln η/∂p)T, and E(p)≠ the activation energy at constant pressure for viscous flow, or the corresponding quantities for diffusion) and X = E(ρ)≠/E(p) (where E(ρ) is the "energy of thermal expansion", defined by: −R[∂ ln (ρ−1 − ρ0−1)/∂T−1]p). The first, Y, involves quantities measured at high pressures, while X requires only measurements at ordinary pressure. The correlation will permit estimation of viscosities and diffusion coefficients at high pressures from low-pressure measurements.


1991 ◽  
Vol 46 (1-2) ◽  
pp. 141-147 ◽  
Author(s):  
Kazuko Tanaka ◽  
Reita Tamamushi

AbstractThe experimental values of density, viscosity, electric conductivity and diffusion coefficients of trace ions in aqueous solutions of lithium chloride in wide ranges of concentration and temperature are collected and discussed. The thermal expansivity and the activation energies of viscous flow, electric conductance and diffusion of trace ions show significant changes at a molality around 12 mol/kg, beyond which the hydration requirement is not satisfied


2019 ◽  
Vol 57 (8) ◽  
pp. 529-532
Author(s):  
Benjamin Spitznagel ◽  
Justin Weigal ◽  
Juan Rodriguez

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