Measurement of heavy isotope enrichment in tropospheric ozone

1995 ◽  
Vol 22 (13) ◽  
pp. 1713-1716 ◽  
Author(s):  
D. Krankowsky ◽  
F. Bartecki ◽  
G. G. Klees ◽  
K. Mauersberger ◽  
K. Schellenbach ◽  
...  
2018 ◽  
Vol 20 (4) ◽  
pp. 621-631 ◽  
Author(s):  
Carluvy Baptista-Salazar ◽  
Holger Hintelmann ◽  
Harald Biester

Light/heavy isotope enrichment is strongly related with Hg species. Combining Hg isotope analysis and Hg speciation allows the differentiation between Hg sources and Hg species transformation in Hg contaminated areas.


1993 ◽  
Vol 39 (132) ◽  
pp. 275-291 ◽  
Author(s):  
Bryn Hubbard ◽  
Martin Sharp

AbstractA simple model is developed to simulate the isotopic fractionation which accompanies Weertman regelation at the bed of temperate-based glaciers. The fractionation equations of Jouzel and Souchez (1982) are applied to multiple refreezing events over measured glacier-bed profiles, and mass balance is maintained as the basal ice and meltwater produced at one bedrock hummock enter the next. Simulation results indicate that undeformed regelation ice layers are on the order of millimetres to centimetres thick, often being completely melted at the stoss face of certain hummocks and exceptionally reaching a thickness in excess of 10 cm. Neither the internal morphology nor the isotopic composition of these layers is constant, but both vary down-glacier in accordance with bedrock configuration. A glacier-wide fractionation process is identified whereby heavy isotopes are preferentially removed from the basal meltwater film and incorporated into the basal ice. This process might go some way to explaining the anomalously “light” isotopic composition measured in base-flow waters leaving some glaciers. Vertical isotope profiles through undeformed basal ice layers are reconstructed and show that significant isotopic excursions can occur at a scale of millimeteres, while the range of isotopic compositions within such multi-layered regelation ice is greater than that which would occur in ice produced by a single refreezing event. In circumstances where the regelation system is disrupted by removal of film waters into a network of linked cavities, it is found that the remaining basal ice may be significantly enriched in heavy isotopes relative to the composition of the initial mass inputs to the system. Heavy isotope enrichment of this magnitude and consideration of the thickness of the basal ice layers concerned may explain the absence of recorded basal ice samples heavy enough to have been formed in equilibrium with subglacial precipitates sampled at one of the sites (Glacier de Tsanfleuron) and reported in an earlier paper.


1993 ◽  
Vol 39 (132) ◽  
pp. 275-291 ◽  
Author(s):  
Bryn Hubbard ◽  
Martin Sharp

AbstractA simple model is developed to simulate the isotopic fractionation which accompanies Weertman regelation at the bed of temperate-based glaciers. The fractionation equations of Jouzel and Souchez (1982) are applied to multiple refreezing events over measured glacier-bed profiles, and mass balance is maintained as the basal ice and meltwater produced at one bedrock hummock enter the next. Simulation results indicate that undeformed regelation ice layers are on the order of millimetres to centimetres thick, often being completely melted at the stoss face of certain hummocks and exceptionally reaching a thickness in excess of 10 cm. Neither the internal morphology nor the isotopic composition of these layers is constant, but both vary down-glacier in accordance with bedrock configuration. A glacier-wide fractionation process is identified whereby heavy isotopes are preferentially removed from the basal meltwater film and incorporated into the basal ice. This process might go some way to explaining the anomalously “light” isotopic composition measured in base-flow waters leaving some glaciers. Vertical isotope profiles through undeformed basal ice layers are reconstructed and show that significant isotopic excursions can occur at a scale of millimeteres, while the range of isotopic compositions within such multi-layered regelation ice is greater than that which would occur in ice produced by a single refreezing event. In circumstances where the regelation system is disrupted by removal of film waters into a network of linked cavities, it is found that the remaining basal ice may be significantly enriched in heavy isotopes relative to the composition of the initial mass inputs to the system. Heavy isotope enrichment of this magnitude and consideration of the thickness of the basal ice layers concerned may explain the absence of recorded basal ice samples heavy enough to have been formed in equilibrium with subglacial precipitates sampled at one of the sites (Glacier de Tsanfleuron) and reported in an earlier paper.


2017 ◽  
Vol 4 (3) ◽  
pp. 160810 ◽  
Author(s):  
Elena Gorokhova

In ecology, stable isotope labelling is commonly used for tracing material transfer in trophic interactions, nutrient budgets and biogeochemical processes. The main assumption in this approach is that the enrichment with a heavy isotope has no effect on the organism growth and metabolism. This assumption is, however, challenged by theoretical considerations and experimental studies on kinetic isotope effects in vivo . Here, I demonstrate profound changes in life histories of the rotifer Brachionus plicatilis fed 15 N-enriched algae (0.4–5.0 at%); i.e. at the enrichment levels commonly used in ecological studies. These findings support theoretically predicted effects of heavy isotope enrichment on growth, metabolism and ageing in biological systems and underline the importance of accounting for such effects when using stable isotope labelling in experimental studies.


2008 ◽  
Vol 14 (5) ◽  
pp. 85-94 ◽  
Author(s):  
A.V. Shavrina ◽  
◽  
Ya.V. Pavlenko ◽  
O.A. Veles' ◽  
V.A. Sheminova ◽  
...  
Keyword(s):  

Tellus B ◽  
1993 ◽  
Vol 45 (2) ◽  
pp. 106-119 ◽  
Author(s):  
Petteri Taalas ◽  
Esko KyrÖ ◽  
Ari Supperi ◽  
Victoria Tafuri ◽  
Maximo Ginzburg

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Sunmin Park ◽  
Seok-Woo Son ◽  
Myung-Il Jung ◽  
Jinkyung Park ◽  
Sang Seo Park
Keyword(s):  

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