The δ13C in benthic foraminiferal tests ofFontbotia wuellerstorfi(Schwager) Relative to the δ13C of dissolved inorganic carbon in Southern Ocean Deep Water: Implications for glacial ocean circulation models

1993 ◽  
Vol 8 (5) ◽  
pp. 587-610 ◽  
Author(s):  
A. Mackensen ◽  
H. -W. Hubberten ◽  
T. Bickert ◽  
G. Fischer ◽  
D. K. Fütterer
Keyword(s):  
Southern Ocean ◽  
Ocean Circulation ◽  
Deep Water ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon

scholarly journals Inorganic carbon time series at Ocean Weather Station M in the Norwegian Sea

2007 ◽  
Vol 4 (4) ◽  
pp. 2929-2958 ◽  
Author(s):  
I. Skjelvan ◽  
E. Falck ◽  
F. Rey ◽  
S. B. Kringstad
Keyword(s):  
Surface Water ◽  
Deep Water ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Sea Surface ◽  
Linear Regression Method ◽  
Weather Station ◽  
Arctic Water ◽  
Annual Increase ◽  
Norwegian Sea

Abstract. Dissolved inorganic carbon (CT) has been collected at Ocean Weather Station M (OWSM) in the Norwegian Sea since 2001. Seasonal variations in CT are confined to the upper 50 m, where the biology is active, and below this layer no clear seasonal signal is seen. From winter to summer the surface CT concentration typical drops from 2140 to about 2040 μmol kg−1, while a deep water CT concentration of about 2163 μmol kg−1 is measured throughout the year. Observations show an annual increase in salinity normalized carbon concentration (nCT) of 1.3±0.7 μmol kg−1 in the surface layer, which is equivalent to a pCO2 increase of 2.6±1.2 μatm yr−1, i.e. larger than the atmospheric increase in this area. Observations also show an annual increase in the deep water nCT of 0.57± 0.24 μmol kg−1, of which about a tenth is due to inflow of old Arctic water with larger amounts of remineralised matter. The remaining part has an anthropogenic origin and sources for this might be Greenland Sea surface water, Iceland Sea surface water, and/or recirculated Atlantic Water. By using an extended multi linear regression method (eMLR) it is verified that anthropogenic carbon has entered the whole water column at OWSM.

scholarly journals Inorganic carbon time series at Ocean Weather Station M in the Norwegian Sea

2008 ◽  
Vol 5 (2) ◽  
pp. 549-560 ◽  
Author(s):  
I. Skjelvan ◽  
E. Falck ◽  
F. Rey ◽  
S. B. Kringstad
Keyword(s):  
Surface Water ◽  
Deep Water ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Sea Surface ◽  
Linear Regression Method ◽  
Weather Station ◽  
Arctic Water ◽  
Annual Increase ◽  
Norwegian Sea

Abstract. Dissolved inorganic carbon (CT) has been collected at Ocean Weather Station M (OWSM) in the Norwegian Sea since 2001. Seasonal variations in (CT) are confined to the upper 50 m, where the biology is active, and below this layer no clear seasonal signal is seen. From winter to summer the surface (CT) concentration typical drop from 2140 to about 2040 μmol kg−1, while a deep water (CT) concentration of about 2163 μmol kg−1 is measured throughout the year. Observations show an annual increase in salinity normalized carbon concentration (nCT) of 1.3±0.7 μmol kg−1 yr−1 in the surface layer, which is equivalent to a pCO2 increase of 2.6±1.2 μatm yr−1, i.e. larger than the atmospheric increase in this area (2.1±0.2 μatm yr-1). Observations also show an annual increase in the deep water nCT of 0.57±0.24 μmol kg−1 yr−1, of which about 15% is due to inflow of old Arctic water with larger amounts of remineralised matter. The remaining part has an anthropogenic origin and sources for this might be Greenland Sea surface water, Iceland Sea surface water, and/or recirculated Atlantic Water. By using an extended multi linear regression method (eMLR) it is verified that anthropogenic carbon has entered the whole water column at OWSM.

scholarly journals Middle Holocene expansion of Pacific Deep Water into the Southern Ocean

2019 ◽  
Vol 117 (2) ◽  
pp. 889-894
Author(s):  
Torben Struve ◽  
David J. Wilson ◽  
Tina van de Flierdt ◽  
Naomi Pratt ◽  
Kirsty C. Crocket
Keyword(s):  
Southern Ocean ◽  
Ocean Circulation ◽  
Deep Water ◽  
Water Masses ◽  
Ocean Dynamics ◽  
Global Ocean ◽  
Circulation System ◽  
The Holocene ◽  
Middle Holocene ◽  
Deep Mixing

The Southern Ocean is a key region for the overturning and mixing of water masses within the global ocean circulation system. Because Southern Ocean dynamics are influenced by the Southern Hemisphere westerly winds (SWW), changes in the westerly wind forcing could significantly affect the circulation and mixing of water masses in this important location. While changes in SWW forcing during the Holocene (i.e., the last ∼11,700 y) have been documented, evidence of the oceanic response to these changes is equivocal. Here we use the neodymium (Nd) isotopic composition of absolute-dated cold-water coral skeletons to show that there have been distinct changes in the chemistry of the Southern Ocean water column during the Holocene. Our results reveal a pronounced Middle Holocene excursion (peaking ∼7,000–6,000 y before present), at the depth level presently occupied by Upper Circumpolar Deep Water (UCDW), toward Nd isotope values more typical of Pacific waters. We suggest that poleward-reduced SWW forcing during the Middle Holocene led to both reduced Southern Ocean deep mixing and enhanced influx of Pacific Deep Water into UCDW, inducing a water mass structure that was significantly different from today. Poleward SWW intensification during the Late Holocene could then have reinforced deep mixing along and across density surfaces, thus enhancing the release of accumulated CO2 to the atmosphere.

scholarly journals Late Neogene Radiolaria from the East Coast Deformed Belt, New Zealand

2021 ◽  
Author(s):  
◽  
Jeffrey Noel Ashby
Keyword(s):  
New Zealand ◽  
Southern Ocean ◽  
Ocean Circulation ◽  
Deep Water ◽  
East Coast ◽  
Sedimentary Basins ◽  
Early Pleistocene ◽  
Time Segment ◽  
Shelf Slope ◽  
Late Neogene

<p>Within the East Coast Deformed Belt there are a number of Late Neogene sedimentary basins with relatively deep-water sediments which, at places, contain abundant radiolarian skeletons. The region was subject to relatively open ocean circulation patterns during the Neogene which, combined with the input of rhyolitic glass shards, has enhanced the siliceous microfossil preservation. A short review of the silica budget is presented and discussed in relation to the preservation of siliceous microfossils in the New Zealand sequences. Techniques were developed to extract and quantitatively study fossil Radiolaria from some of the relatively barren shelf/slope sediments. One hundred and thirty-eight radiolarian taxa are described, most of which can be assigned at the generic level, but thirty-one of which can not be assigned specific names and may eventually prove to be new species. The radiolarian zonation presented is based on detailed analysis of 155 samples from 26 sections and sites ranging in age from basal Tongaporutuan (early Late Miocene) to middle Nukumaruan (early Pleistocene). Sediments of the Kapitean (uppermost Miocene) were generally deposited in shallow water environments or are missing in unconformities in the East Coast Deformed Belt, consequently the radiolarian zonation is based on very poor data in this time segment. Also upper Opoitian and Waipipian (middle Pliocene) sediments, although at places deposited in relatively deep water, generally lack siliceous tuffs, and radiolarian preservation is poor. Five major radiolarian zones can be recognised: Diartus hughesi Zone, Didymocyrtis sp. A Zone, Didymocyrtis sp. A Zone, Didymocyrtis tetrathalmus tetrathalmus Zone, Lamprocyrtis heteroporos Zone, and Lamprocyclas gamphonycha Zone. In samples with good radiolarian preservation six subzones can be identified. The Diartus hughesi Zone can be divided into the Heliodiscus umbonatum Subzone, Didymocyrtis laticonus Subzone, Heliodiscus asteriscus forma large pores Subzone, and Anthocyrtidium ehrenbergi pliocenica Subzone. Additionally the Didymocyrtis tetrathalmus tetrathalmus Zone can be divided into the Lychnocanium sp. aff. grande Subzone and Lamprocyrtis hannai Subzone. The bioevents that define the zonal boundaries are discussed along with other biostratigraphically useful radiolarian datums. These zones and zubzones are correlated to the foraminiferal zonation which in turn has been related, in part, to the paleomagnetic time scale. Correlation are then made with other radiolarian zonations in the north Pacific, tropics, and southern ocean. Points to emerge from these correlations include the apparent provincialism in the transition from Stichocorys delmontense to Stichocorys peregrine in the tropical Pacific. This transition has been reported to occur during approximately 1.5Ma but in New Zealand occurs over a time segment of at least 5.5Ma. The first appearance of Lamprocyclas gamphonycha appears to be an isochronous datum level in temperate radiolarian faunas of the northern and southern Pacific. The last appearance datum of Diartus hughesi at about 7.5Ma is in good agreement with its level in the tropics. The presence of this taxon in lower Gilbert Antarctic cores suggests either a grossly diachronous event between tropical/temperate areas and the southern ocean or, more probably, a misinterpretation of the paleomagnetic signature from key southern ocean piston cores. If the latter situation is the case then the real age estimates on the "Pre middle Gilbert" southern ocean diatom and silicoflagellate stratigraphies are questionable because they are based on the same key cores. Statistical faunal analysis shows that during the Miocene there was not much change in the radiolarian faunas with time and a major change, probably climatically controlled, took place across the Miocene/Pliocene boundary. Variability in preservation has probably affected the faunas to obscure more precise time variation although post-Miocene faunas indicate that some is present. In conclusion, the Radiolaria, although not as common in the fossil record as the foraminifera, definitely contribute to New Zealand Late Neogene integrated stratigraphy and suggest that our knowledge could be greatly enhanced by the study of other siliceous microfossil groups.</p>

scholarly journals Early Eocene vigorous ocean overturning and its contribution to a warm Southern Ocean

2020 ◽  
Author(s):  
Yurui Zhang ◽  
Thierry Huck ◽  
Camille Lique ◽  
Yannick Donnadieu ◽  
Jean-Baptiste Ladant ◽  
...  
Keyword(s):  
Southern Ocean ◽  
Heat Transport ◽  
Southern Hemisphere ◽  
Ocean Circulation ◽  
Deep Water ◽  
Atmospheric Co2 ◽  
Early Eocene ◽  
Deep Water Formation ◽  
Overturning Circulation ◽  
Water Formation

Abstract. The early Eocene (~ 55 Ma) is the warmest period, and most likely characterized by the highest atmospheric CO2 concentrations, of the Cenozoic era. Here, we analyze simulations of the early Eocene performed with the IPSL-CM5A2 coupled climate model set up with paleogeographic reconstructions of this period from the DeepMIP project, with different levels of atmospheric CO2, and compare them with simulations of the modern conditions. This allows us to explore the changes of the ocean circulation and the resulting ocean meridional heat transport. At a CO2 level of 840 ppm, the Early Eocene simulation is characterized by a strong abyssal overturning circulation in the Southern Hemisphere (40 Sv at 60º S), fed by deep water formation in the three sectors of the Southern Ocean. Deep convection in the Southern Ocean is favored by the closed Drake and Tasmanian passages, which provide western boundaries for the build-up of strong subpolar gyres in the Weddell and Ross seas, in the middle of which convection develops. The strong overturning circulation, associated with the subpolar gyres, sustains the poleward advection of saline subtropical water to the convective region in the Southern Ocean, maintaining deep-water formation. This salt-advection feedback mechanism works similarly in the present-day North Atlantic overturning circulation. The strong abyssal overturning circulation in the 55 Ma simulations primarily results in an enhanced poleward ocean heat transport by 0.3–0.7 PW in the Southern Hemisphere compared to modern conditions, reaching 1.7 PW southward at 20° S, and contributing to maintain the Southern Ocean and Antarctica warm in the Eocene. Simulations with different atmospheric CO2 levels show that the ocean circulation and heat transport are relatively insensitive to CO2-doubling.

scholarly journals Glacial CO<sub>2</sub> decrease and deep-water deoxygenation by iron fertilization from glaciogenic dust

2019 ◽  
Author(s):  
Akitomo Yamamoto ◽  
Ayako Abe-Ouchi ◽  
Rumi Ohgaito ◽  
Akinori Ito ◽  
Akira Oka
Keyword(s):  
Southern Ocean ◽  
Ocean Circulation ◽  
Deep Water ◽  
Large Scale ◽  
Deep Ocean ◽  
Oxygen Solubility ◽  
Biological Pump ◽  
Surface Cooling ◽  
Iron Fertilization ◽  
Water Deoxygenation

Abstract. Increased accumulation of respired carbon in the deep ocean associated with enhanced efficiency of the biological carbon pump is thought to be a key mechanism of glacial CO2 drawdown. Despite greater oxygen solubility due to sea surface cooling, recent quantitative and qualitative proxy data show glacial deep-water deoxygenation, reflecting increased accumulation of respired carbon. However, the mechanisms of deep-water deoxygenation and contribution from the biological pump to glacial CO2 drawdown have remained unclear. In this study, we report the significance of iron fertilization from glaciogenic dust for glacial CO2 decrease and deep-water deoxygenation using our numerical simulation, which successfully reproduces the magnitude and large-scale pattern of the observed oxygen changes from the present to Last Glacial Maximum. Sensitivity experiments reveal that physical changes (e.g., more sluggish ocean circulation) contribute to only half of all glacial deep deoxygenation, whereas the other half is driven by enhanced efficiency of the biological pump. We found that iron input from the glaciogenic dust with higher iron solubility is the most significant factor for enhancement of the biological pump and deep-water deoxygenation. Glacial deep-water deoxygenation expands the hypoxic waters in the deep Pacific and Indian Ocean. The simulated global volume of hypoxic waters is nearly double the present value, which suggest that the glacial deep-water is sever environment for the benthic animals. Our model underestimated the deoxygenation in the deep Southern Ocean due to enhanced ventilation. The model-proxy comparison of oxygen change suggest that the stratified Southern Ocean is required for reproducing oxygen decline in the deep Southern Ocean. Enhanced efficiency of biological pump contributes to decrease of glacial CO2 by more than 30 ppm, which is supported by the model-proxy agreement of oxygen change. Our findings confirm the significance of the biological pump in glacial CO2 drawdown and deoxygenation.

scholarly journals Effects of eustatic sea-level change, ocean dynamics, and nutrient utilization on atmospheric <i>p</i>CO<sub>2</sub> and seawater composition over the last 130 000 years: a model study

2016 ◽  
Vol 12 (2) ◽  
pp. 339-375 ◽  
Author(s):  
K. Wallmann ◽  
B. Schneider ◽  
M. Sarnthein
Keyword(s):  
Southern Ocean ◽  
Sea Level ◽  
Ocean Circulation ◽  
Dissolved Inorganic Carbon ◽  
Nutrient Utilization ◽  
Meridional Overturning Circulation ◽  
Ocean Dynamics ◽  
Total Alkalinity ◽  
Global Ocean ◽  
Atmospheric Pco2

Abstract. We have developed and employed an Earth system model to explore the forcings of atmospheric pCO2 change and the chemical and isotopic evolution of seawater over the last glacial cycle. Concentrations of dissolved phosphorus (DP), reactive nitrogen, molecular oxygen, dissolved inorganic carbon (DIC), total alkalinity (TA), 13C-DIC, and 14C-DIC were calculated for 24 ocean boxes. The bi-directional water fluxes between these model boxes were derived from a 3-D circulation field of the modern ocean (Opa 8.2, NEMO) and tuned such that tracer distributions calculated by the box model were consistent with observational data from the modern ocean. To model the last 130 kyr, we employed records of past changes in sea-level, ocean circulation, and dust deposition. According to the model, about half of the glacial pCO2 drawdown may be attributed to marine regressions. The glacial sea-level low-stands implied steepened ocean margins, a reduced burial of particulate organic carbon, phosphorus, and neritic carbonate at the margin seafloor, a decline in benthic denitrification, and enhanced weathering of emerged shelf sediments. In turn, low-stands led to a distinct rise in the standing stocks of DIC, TA, and nutrients in the global ocean, promoted the glacial sequestration of atmospheric CO2 in the ocean, and added 13C- and 14C-depleted DIC to the ocean as recorded in benthic foraminifera signals. The other half of the glacial drop in pCO2 was linked to inferred shoaling of Atlantic meridional overturning circulation and more efficient utilization of nutrients in the Southern Ocean. The diminished ventilation of deep water in the glacial Atlantic and Southern Ocean led to significant 14C depletions with respect to the atmosphere. According to our model, the deglacial rapid and stepwise rise in atmospheric pCO2 was induced by upwelling both in the Southern Ocean and subarctic North Pacific and promoted by a drop in nutrient utilization in the Southern Ocean. The deglacial sea-level rise led to a gradual decline in nutrient, DIC, and TA stocks, a slow change due to the large size and extended residence times of dissolved chemical species in the ocean. Thus, the rapid deglacial rise in pCO2 can be explained by fast changes in ocean dynamics and nutrient utilization whereas the gradual pCO2 rise over the Holocene may be linked to the slow drop in nutrient and TA stocks that continued to promote an ongoing CO2 transfer from the ocean into the atmosphere.

scholarly journals Two decades of inorganic carbon dynamics along the West Antarctic Peninsula

2015 ◽  
Vol 12 (22) ◽  
pp. 6761-6779 ◽  
Author(s):  
C. Hauri ◽  
S. C. Doney ◽  
T. Takahashi ◽  
M. Erickson ◽  
G. Jiang ◽  
...  
Keyword(s):  
Antarctic Peninsula ◽  
Ocean Circulation ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
World Ocean ◽  
Nutrient Utilization ◽  
Total Alkalinity ◽  
Data Set ◽  
Molar Ratios ◽  
Wide Range

Abstract. We present 20 years of seawater inorganic carbon measurements collected along the western shelf and slope of the Antarctic Peninsula. Water column observations from summertime cruises and seasonal surface underway pCO2 measurements provide unique insights into the spatial, seasonal, and interannual variability in this dynamic system. Discrete measurements from depths > 2000 m align well with World Ocean Circulation Experiment observations across the time series and underline the consistency of the data set. Surface total alkalinity and dissolved inorganic carbon data showed large spatial gradients, with a concomitant wide range of Ωarag (< 1 up to 3.9). This spatial variability was mainly driven by increasing influence of biological productivity towards the southern end of the sampling grid and meltwater input along the coast towards the northern end. Large inorganic carbon drawdown through biological production in summer caused high near-shore Ωarag despite glacial and sea-ice meltwater input. In support of previous studies, we observed Redfield behavior of regional C / N nutrient utilization, while the C / P (80.5 ± 2.5) and N / P (11.7 ± 0.3) molar ratios were significantly lower than the Redfield elemental stoichiometric values. Seasonal salinity-based predictions of Ωarag suggest that surface waters remained mostly supersaturated with regard to aragonite throughout the study. However, more than 20 % of the predictions for winters and springs between 1999 and 2013 resulted in Ωarag < 1.2. Such low levels of Ωarag may have implications for important organisms such as pteropods. Even though we did not detect any statistically significant long-term trends, the combination of on\\-going ocean acidification and freshwater input may soon induce more unfavorable conditions than the ecosystem experiences today.

scholarly journals What drives the latitudinal gradient in open-ocean surface dissolved inorganic carbon concentration?

2019 ◽  
Vol 16 (13) ◽  
pp. 2661-2681 ◽  
Author(s):  
Yingxu Wu ◽  
Mathis P. Hain ◽  
Matthew P. Humphreys ◽  
Sue Hartman ◽  
Toby Tyrrell
Keyword(s):  
Southern Ocean ◽  
High Latitude ◽  
Latitudinal Gradient ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Latitudinal Gradients ◽  
Total Alkalinity ◽  
Global Ocean ◽  
Low Latitude ◽  
Surface Ocean

Abstract. Previous work has not led to a clear understanding of the causes of spatial pattern in global surface ocean dissolved inorganic carbon (DIC), which generally increases polewards. Here, we revisit this question by investigating the drivers of observed latitudinal gradients in surface salinity-normalized DIC (nDIC) using the Global Ocean Data Analysis Project version 2 (GLODAPv2) database. We used the database to test three different hypotheses for the driver producing the observed increase in surface nDIC from low to high latitudes. These are (1) sea surface temperature, through its effect on the CO2 system equilibrium constants, (2) salinity-related total alkalinity (TA), and (3) high-latitude upwelling of DIC- and TA-rich deep waters. We find that temperature and upwelling are the two major drivers. TA effects generally oppose the observed gradient, except where higher values are introduced in upwelled waters. Temperature-driven effects explain the majority of the surface nDIC latitudinal gradient (182 of the 223 µmol kg−1 increase from the tropics to the high-latitude Southern Ocean). Upwelling, which has not previously been considered as a major driver, additionally drives a substantial latitudinal gradient. Its immediate impact, prior to any induced air–sea CO2 exchange, is to raise Southern Ocean nDIC by 220 µmol kg−1 above the average low-latitude value. However, this immediate effect is transitory. The long-term impact of upwelling (brought about by increasing TA), which would persist even if gas exchange were to return the surface ocean to the same CO2 as without upwelling, is to increase nDIC by 74 µmol kg−1 above the low-latitude average.

scholarly journals Measurements of total alkalinity and inorganic dissolved carbon in the Atlantic Ocean and adjacent Southern Ocean between 2008 and 2010

2013 ◽  
Vol 6 (2) ◽  
pp. 621-639
Author(s):  
U. Schuster ◽  
A. J. Watson ◽  
D. C. E. Bakker ◽  
A. M. de Boer ◽  
E. M. Jones ◽  
...  
Keyword(s):  
Quality Control ◽  
Atlantic Ocean ◽  
Southern Ocean ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Drake Passage ◽  
Total Alkalinity ◽  
Global Ocean ◽  
Atlantic Sector ◽  
Dissolved Carbon

Abstract. Water column dissolved inorganic carbon and total alkalinity were measured during five hydrographic sections in the Atlantic Ocean and Drake Passage. The work was funded through the Strategic Funding Initiative of the UK's Oceans2025 programme, which ran from 2007 to 2012. The aims of this programme were to establish the regional budgets of natural and anthropogenic carbon in the North Atlantic, the South Atlantic, and the Atlantic sector of the Southern Ocean, as well as the rates of change of these budgets. This paper describes the dissolved inorganic carbon and total alkalinity data collected along east-west sections at 55–60° N (Arctic Gateway), 24.5° N, and 24° S in the Atlantic and across two Drake Passage sections. Other hydrographic and biogeochemical parameters were measured during these sections, yet are not covered in this paper. Over 95% of samples taken during the 24.5° N, 24° S, and the Drake Passage sections were analysed onboard and subjected to a 1st level quality control addressing technical and analytical issues. Samples taken during Arctic Gateway were analysed and subjected to quality control back in the laboratory. Complete post-cruise 2nd level quality control was performed using cross-over analysis with historical data in the vicinity of measurements, and data are available through the Carbon Dioxide Information Analysis Center (CDIAC) and are included in the Global Ocean Data Analyses Project, version 2 (GLODAP 2).

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