The effect of stratospheric water vapor on the heterogeneous reaction rate of ClONO2and H2O for sulfuric acid aerosol

1992 ◽  
Vol 19 (22) ◽  
pp. 2211-2214 ◽  
Author(s):  
D. J. Hofmann ◽  
S. J. Oltmans
Keyword(s):  
Water Vapor ◽  
Sulfuric Acid ◽  
Reaction Rate ◽  
Heterogeneous Reaction ◽  
Stratospheric Water Vapor

scholarly journals Impacts of Ozone Changes in the Tropopause Layer on Stratospheric Water Vapor

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 291
Author(s):  
Jinpeng Lu ◽  
Fei Xie ◽  
Hongying Tian ◽  
Jiali Luo
Keyword(s):  
Water Vapor ◽  
Ozone Depletion ◽  
Climate Model ◽  
Global Climate ◽  
Stratospheric Water Vapor ◽  
Radiative Processes ◽  
Low Latitudes ◽  
Cold Point ◽  
The Impact ◽  
Tropopause Temperature

Stratospheric water vapor (SWV) changes play an important role in regulating global climate change, and its variations are controlled by tropopause temperature. This study estimates the impacts of tropopause layer ozone changes on tropopause temperature by radiative process and further influences on lower stratospheric water vapor (LSWV) using the Whole Atmosphere Community Climate Model (WACCM4). It is found that a 10% depletion in global (mid-low and polar latitudes) tropopause layer ozone causes a significant cooling of the tropical cold-point tropopause with a maximum cooling of 0.3 K, and a corresponding reduction in LSWV with a maximum value of 0.06 ppmv. The depletion of tropopause layer ozone at mid-low latitudes results in cooling of the tropical cold-point tropopause by radiative processes and a corresponding LSWV reduction. However, the effect of polar tropopause layer ozone depletion on tropical cold-point tropopause temperature and LSWV is opposite to and weaker than the effect of tropopause layer ozone depletion at mid-low latitudes. Finally, the joint effect of tropopause layer ozone depletion (at mid-low and polar latitudes) causes a negative cold-point tropopause temperature and a decreased tropical LSWV. Conversely, the impact of a 10% increase in global tropopause layer ozone on LSWV is exactly the opposite of the impact of ozone depletion. After 2000, tropopause layer ozone decreased at mid-low latitudes and increased at high latitudes. These tropopause layer ozone changes at different latitudes cause joint cooling in the tropical cold-point tropopause and a reduction in LSWV. Clarifying the impacts of tropopause layer ozone changes on LSWV clearly is important for understanding and predicting SWV changes in the context of future global ozone recovery.

scholarly journals Effect of the Indo-Pacific Warm Pool on Lower-Stratospheric Water Vapor and Comparison with the Effect of ENSO

2018 ◽  
Vol 31 (3) ◽  
pp. 929-943 ◽  
Author(s):  
Fei Xie ◽  
Xin Zhou ◽  
Jianping Li ◽  
Quanliang Chen ◽  
Jiankai Zhang ◽  
...  
Keyword(s):  
Water Vapor ◽  
Climate Model ◽  
Southern Oscillation ◽  
Deep Convection ◽  
Warm Pool ◽  
Latent Heat Release ◽  
Stratospheric Water Vapor ◽  
Asymmetric Effects ◽  
Pacific Warm Pool ◽  
Tropopause Temperature

Abstract Time-slice experiments with the Whole Atmosphere Community Climate Model, version 4 (WACCM4), and composite analysis with satellite observations are used to demonstrate that the Indo-Pacific warm pool (IPWP) can significantly affect lower-stratospheric water vapor. It is found that a warmer IPWP significantly dries the stratospheric water vapor by causing a broad cooling of the tropopause, and vice versa for a colder IPWP. Such imprints in tropopause temperature are driven by a combination of variations in the Brewer–Dobson circulation in the stratosphere and deep convection in the troposphere. Changes in deep convection associated with El Niño–Southern Oscillation (ENSO) reportedly have a small zonal mean effect on lower-stratospheric water vapor for strong zonally asymmetric effects on tropopause temperature. In contrast, IPWP events have zonally uniform imprints on tropopause temperature. This is because equatorial planetary waves forced by latent heat release from deep convection project strongly onto ENSO but weakly onto IPWP events.

scholarly journals Features and trends in Atmospheric Trace Molecule Spectroscopy (ATMOS) version 3 stratospheric water vapor and methane measurements

2000 ◽  
Vol 105 (D18) ◽  
pp. 22713-22724 ◽  
Author(s):  
H. A. Michelsen ◽  
F. W. Irion ◽  
G. L. Manney ◽  
G. C. Toon ◽  
M. R. Gunson
Keyword(s):  
Water Vapor ◽  
Stratospheric Water Vapor

The Role of Binary and Ion Nucleation of Sulfuric Acid and Water Vapor in the Dynamics of Sulfate Aerosol Formation in the Atmosphere

2021 ◽  
pp. 53-60
Author(s):  
A. E. Aloyan ◽  
◽  
A. N. Yermakov ◽  
V. O. Arutyunyan ◽  
◽  
...  
Keyword(s):  
Water Vapor ◽  
Sulfuric Acid ◽  
Three Dimensional ◽  
Ionization Rate ◽  
Sulfate Aerosol ◽  
Aerosol Formation ◽  
Three Dimensional Model ◽  
Aerosol Composition ◽  
Transport And Transformation

The results of one-dimensional calculations of the height profiles of nucleated sulfate aerosol particles for the northern mid-latitudes and tropics in winter are presented. Numerical calculations were performed using a three-dimensional model of the transport and transformation of multicompo- nent gas and aerosol substances in the atmosphere, incorporating photochemistry, nucleation involving neutral molecules and ions, as well as condensation/evaporation and coagulation. It is found that the resulting dynamics of the formation of aerosol particle nuclei is not a simple sum of ion and binary (water vapor/sulfuric acid) nucleation rates. This dynamics is determined by the ratio of critical radii of nucleated particles due to binary and ion nucleation of these substances (rcr_bin and rcr_ion) depending on temperature, relative humidity, and ionization rate. This should be taken into account in modeling the gas and aerosol composition of the atmosphere and comparing calculated and observed data.

scholarly journals Decadal changes in tropical convection suggest effects on stratospheric water vapor

2010 ◽  
Vol 37 (14) ◽  
pp. n/a-n/a ◽  
Author(s):  
George Tselioudis ◽  
Eric Tromeur ◽  
William B. Rossow ◽  
C. S. Zerefos
Keyword(s):  
Water Vapor ◽  
Tropical Convection ◽  
Stratospheric Water Vapor

scholarly journals The increase in stratospheric water vapor from balloonborne, frostpoint hygrometer measurements at Washington, D.C., and Boulder, Colorado

2000 ◽  
Vol 27 (21) ◽  
pp. 3453-3456 ◽  
Author(s):  
Samuel J. Oltmans ◽  
Holger Vömel ◽  
David J. Hofmann ◽  
Karen H. Rosenlof ◽  
Dieter Kley
Keyword(s):  
Water Vapor ◽  
Stratospheric Water Vapor

scholarly journals Modeling upper tropospheric and lower stratospheric water vapor anomalies

2013 ◽  
Vol 13 (4) ◽  
pp. 9653-9679 ◽  
Author(s):  
M. R. Schoeberl ◽  
A. E. Dessler ◽  
T. Wang
Keyword(s):  
Water Vapor ◽  
Lower Stratosphere ◽  
Calculation Model ◽  
Vapor Concentration ◽  
Cold Temperatures ◽  
Tropical Tropopause Layer ◽  
Stratospheric Water Vapor ◽  
Tropical Tropopause ◽  
Minimum Displacement ◽  
Asian Monsoons

Abstract. The domain-filling, forward trajectory calculation model developed by Schoeberl and Dessler (2011) is used to further investigate processes that produce upper tropospheric and lower stratospheric water vapor anomalies. We examine the pathways parcels take from the base of the tropical tropopause layer (TTL) to the lower stratosphere. Most parcels found in the lower stratosphere arise from East Asia, the Tropical West Pacific (TWP) and the Central/South America. The belt of TTL parcel origins is very wide compared to the final dehydration zones near the top of the TTL. This is due to the convergence of rising air as a result of the stronger diabatic heating near the tropopause relative to levels above and below. The observed water vapor anomalies – both wet and dry – correspond to regions where parcels have minimal displacement from their initialization. These minimum displacement regions include the winter TWP and the Asian and American monsoons. To better understand the stratospheric water vapor concentration we introduce the water vapor spectrum and investigate the source of the wettest and driest components of the spectrum. We find that the driest air parcels that originate below the TWP, moving upward to dehydrate in the TWP cold upper troposphere. The wettest air parcels originate at the edges of the TWP as well as the summer American and Asian monsoons. The wet air parcels are important since they skew the mean stratospheric water vapor distribution toward higher values. Both TWP cold temperatures that produce dry parcels as well as extra-TWP processes that control the wet parcels determine stratospheric water vapor.

scholarly journals Hydrates in supersaturated binary sulfuric acid‐water vapor

1974 ◽  
Vol 61 (2) ◽  
pp. 573-581 ◽  
Author(s):  
R. H. Heist ◽  
H. Reiss
Keyword(s):  
Water Vapor ◽  
Sulfuric Acid ◽  
Acid Water
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