Spatial distribution of atmospheric mercury species in the Southern Ocean

2021 ◽  
Author(s):  
Fange Yue ◽  
Zhouqing Xie1 ◽  
Jinpei Yan ◽  
Yanxu Zhang ◽  
Bei Jiang
Keyword(s):  
Spatial Distribution ◽  
Southern Ocean ◽  
Atmospheric Mercury ◽  
Mercury Species

scholarly journals Drivers of abundance and spatial distribution in Southern Ocean peracarid crustacea

2021 ◽  
Vol 128 ◽  
pp. 107832
Author(s):  
Davide Di Franco ◽  
Katrin Linse ◽  
Huw J. Griffiths ◽  
Angelika Brandt
Keyword(s):  
Spatial Distribution ◽  
Southern Ocean

Distribution of atmospheric mercury species near ground

1974 ◽  
Vol 8 (12) ◽  
pp. 1003-1009 ◽  
Author(s):  
David L. Johnson ◽  
Robert S. Braman
Keyword(s):  
Atmospheric Mercury ◽  
Mercury Species

scholarly journals Simulation of atmospheric mercury depletion events (AMDEs) during polar springtime using the MECCA box model

2008 ◽  
Vol 8 (23) ◽  
pp. 7165-7180 ◽  
Author(s):  
Z.-Q. Xie ◽  
R. Sander ◽  
U. Pöschl ◽  
F. Slemr
Keyword(s):  
Aqueous Phase ◽  
Ozone Depletion ◽  
Elemental Mercury ◽  
Atmospheric Mercury ◽  
Box Model ◽  
Rate Coefficients ◽  
Mercury Species ◽  
Phase Reaction ◽  
Gaseous Elemental Mercury ◽  
Sea Salt Aerosol

Abstract. Atmospheric mercury depletion events (AMDEs) during polar springtime are closely correlated with bromine-catalyzed tropospheric ozone depletion events (ODEs). To study gas- and aqueous-phase reaction kinetics and speciation of mercury during AMDEs, we have included mercury chemistry into the box model MECCA (Module Efficiently Calculating the Chemistry of the Atmosphere), which enables dynamic simulation of bromine activation and ODEs. We found that the reaction of Hg with Br atoms dominates the loss of gaseous elemental mercury (GEM). To explain the experimentally observed synchronous depletion of GEM and O3, the reaction rate of Hg+BrO has to be much lower than that of Hg+Br. The synchronicity is best reproduced with rate coefficients at the lower limit of the literature values for both reactions, i.e. kHg+Br≈3×10−13 and kHg+BrO≤1×10−15 cm3 molecule−1 s−1, respectively. Throughout the simulated AMDEs, BrHgOBr was the most abundant reactive mercury species, both in the gas phase and in the aqueous phase. The aqueous-phase concentrations of BrHgOBr, HgBr2, and HgCl2 were several orders of magnitude larger than that of Hg(SO3)22−. Considering chlorine chemistry outside depletion events (i.e. without bromine activation), the concentration of total divalent mercury in sea-salt aerosol particles (mostly HgCl42−) was much higher than in dilute aqueous droplets (mostly Hg(SO3)22−), and did not exhibit a diurnal cycle (no correlation with HO2 radicals).

scholarly journals Diatom ooze—A large marine mercury sink

Science ◽  
2018 ◽  
Vol 361 (6404) ◽  
pp. 797-800 ◽  
Author(s):  
Sara Zaferani ◽  
Marta Pérez-Rodríguez ◽  
Harald Biester
Keyword(s):  
High Resolution ◽  
Southern Ocean ◽  
Marine Sediment ◽  
Crucial Role ◽  
Anthropogenic Pollution ◽  
Atmospheric Mercury ◽  
Mercury Accumulation ◽  
Accumulation Rates ◽  
Sediment Data

The role of algae for sequestration of atmospheric mercury in the ocean is largely unknown owing to a lack of marine sediment data. We used high-resolution cores from marine Antarctica to estimate Holocene global mercury accumulation in biogenic siliceous sediments (diatom ooze). Diatom ooze exhibits the highest mercury accumulation rates ever reported for the marine environment and provides a large sink of anthropogenic mercury, surpassing existing model estimates by as much as a factor of 7. Anthropogenic pollution of the Southern Ocean began ~150 years ago, and up to 20% of anthropogenic mercury emitted to the atmosphere may have been stored in diatom ooze. These findings reveal the crucial role of diatoms as a fast vector for mercury sequestration and diatom ooze as a large marine mercury sink.

Temporal Trend and Spatial Distribution of Speciated Atmospheric Mercury Emissions in China During 1978–2014

2016 ◽  
Vol 50 (24) ◽  
pp. 13428-13435 ◽  
Author(s):  
Qingru Wu ◽  
Shuxiao Wang ◽  
Guoliang Li ◽  
Sai Liang ◽  
Che-Jen Lin ◽  
...  
Keyword(s):  
Spatial Distribution ◽  
Temporal Trend ◽  
Atmospheric Mercury ◽  
Mercury Emissions

scholarly journals Circumpolar transport and air-surface exchange of atmospheric mercury at Ny-Ålesund (79° N), Svalbard, spring 2002

2007 ◽  
Vol 7 (1) ◽  
pp. 151-166 ◽  
Author(s):  
J. Sommar ◽  
I. Wängberg ◽  
T. Berg ◽  
K. Gårdfeldt ◽  
J. Munthe ◽  
...  
Keyword(s):  
Sea Level ◽  
Elemental Mercury ◽  
Atmospheric Mercury ◽  
Mercury Species ◽  
Research Station ◽  
Flux Chamber ◽  
Vertical Column ◽  
Surface Exchange ◽  
Lower Altitude ◽  
Gaseous Mercury

Abstract. Mercury in different environmental compartments has been measured at Ny-Ålesund (78°54' N, 11°53' E) during an intensive campaign, 17 April to 14 May 2002. Time-resolved speciated determination of mercury in the atmosphere and snow was conducted at the Norwegian research station at the Zeppelin mountain, 474 m above the sea level, and at the Italian research facility Dirigibile Italia, 12 m above the sea level. Total Gaseous Mercury (TGM) was present in the range <0.1 to 2.2 ng m−3 during the campaign. Three mercury depletion events, identified as periods with decreased TGM concentrations, were observed. At the lower altitude, TGM concentrations following such events were found to exhibit both higher magnitude and larger variability in comparison to results from the Zeppelin station. Oxidised mercury species in air and fall-out with snow as well as mercury attached to particles were also measured and their concentrations were found to be anti-correlated with TGM in air. concentrations of total Hg in snow (Hg-tot) showed a large (~15×) increase in response to Gaseous Elemental Mercury Depletion Events (GEMDEs, range 1.5–76.5 ng L−1). Solid evidence for photo-stimulated emissions of Hg0(g) from the snow pack in conjunction to depletion events were obtained from gradient measurements as well as from flux chamber measurements. Steep diurnal concentration variations of Hg0(aq) in surface seawater were also found to concur with changing solar radiation. The concentration of Hg0(aq) in seawater was found to be in the range 12.2–70.4 pg L−1, which corresponds to supersaturation. Hence, the seawater surface constituted a source emitting elemental mercury. The concentrations of RGM (reactive gaseous mercury), Hg-p (particulate mercury), and BrO column densities (detected by DOAS) were very low except for a few individual samples during the major Hg0 depletion event. BrO vertical column densities obtained by the remote satellite ESR-2 and trajectory analysis indicate that the air masses exhibiting low Hg0 concentrations originated from areas with high BrO densities.

Distribution of atmospheric mercury species near ground. Reply to comments

1975 ◽  
Vol 9 (4) ◽  
pp. 366-366
Author(s):  
Robert S. Braman ◽  
David L. Johnson
Keyword(s):  
Atmospheric Mercury ◽  
Mercury Species
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