scholarly journals Origins of Major Element, Trace Element, and Isotope Garnet Signatures in Mid‐Ocean Ridge Basalts

2020 ◽  
Vol 125 (12) ◽  
Author(s):  
Stephanie Brown Krein ◽  
Mark Dietrich Behn ◽  
Timothy Lynn Grove
Keyword(s):  
Trace Element ◽  
Major Element ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Differentiation and source of the Nipissing Diabase intrusions, Ontario, Canada

1993 ◽  
Vol 30 (6) ◽  
pp. 1123-1140 ◽  
Author(s):  
P. C. Lightfoot ◽  
H. de Souza ◽  
W. Doherty
Keyword(s):  
Trace Element ◽  
Crustal Contamination ◽  
Primitive Mantle ◽  
Magma Source ◽  
Magma Type ◽  
Ni Content ◽  
Chemical Signatures ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Major and trace element data are presented for 2.2 Ga Proterozoic diabase sills from across the Nipissing magmatic province of Ontario. In situ differentiation of the magma coupled with assimilation of Huronian Supergroup roof sediments is responsible for the variation in composition between quartz diabase and granophyric diabase seen within many of the differentiated intrusions. Uniform trace element and isotope ratio signatures, such as La/Sm (2.8 – 3.7) and εNdCHUR (−2.7 to −5.9) characterize chilled margins and undifferentiated quartz diabases. These chemical signatures suggest the existence of a single magma source that was parental to intrusions throughout the magmatic province; this magma has higher La/Sm and lower Ti/Y than primitive mantle and is displaced towards the composition of shales. Most chilled diabases and quartz diabases have a similar Mg# (0.64 and 0.60) and Ni content (98 and 127 ppm), and it is argued that the magma differentiated at depth and was emplaced as a uniform low-Mg magma. The Wanapitei intrusion and Kukagami Lake sill are an exception in that although the quartz diabase has La/Sm similar to the Nipissing magma type, which suggests that they came from the same source, the Mg# (0.68–0.71) and Ni content (130–141 ppm) are higher, which may suggest that they are either slightly more primitive examples of the normal Nipissing magma or that cumulus hypersthene has been resorbed. The light rare earth element enriched signature of the Nipissing magmas was perhaps introduced from the continental crust as the magma migrated from the mantle to the surface, but a remarkably constant and large amount (>20%) of crustal contamination would be required. An addition of 1 –3% shale to the source of a transitional mid-ocean ridge basalt type magma can broadly reproduce the compositional features of the Nipissing magma type. The source characteristics were perhaps imparted during subduction accompanying the terminal Kenoran orogeny.

Element fluxes associated with subduction related magmatism

1991 ◽  
Vol 335 (1638) ◽  
pp. 393-405 ◽  
Keyword(s):  
Trace Element ◽  
Incompatible Element ◽  
Mantle Wedge ◽  
Isotope Ratios ◽  
Noticeable Effect ◽  
Arc Magmas ◽  
Mid Ocean Ridge ◽  
Ocean Ridge ◽  
Arc Magma ◽  
Subducted Sediment

Destructive plate margin magmas may be subdivided into two groups on the basis of their rare earth element (REE) ratios. Most island arc suites have low Ce/Yb, and remarkably restricted isotope ratios of 87 Sr/ 86 Sr = 0.7033, 143 Nd/ 144 Nd = 0.51302, 206 Pb/ 204 Pb = 18.76 , 207 Pb/ 204 Pb = 15.57, and 208 Pb/ 204 Pb = 38.4. However, they also have Rb/Sr (0.03), Th/U (2.2) and Ce/Yb (8.5) ratios which are significantly less than accepted estimates for the bulk continental crust. The high Ce/Yb suites have higher incompatible element contents, more restricted heavy REE, and much more variable isotope ratios. Such rocks are found in the Aeolian Islands, Grenada, Indonesia and Philippines, and their isotope and trace element features have been attributed both to contributions from subducted sediment, and/or old trace element enriched material in the mantle wedge. It is argued that for isotope and trace element models the slab component can usefully be taken to consist of subducted sediment and altered mid-ocean ridge basalts, since these may contain ca. 80% of the water in the subducted slab, and the distinctive trace element features of arc magmas are generally attributed to the movement of material in hydrous fluids. The isotope data indicate that not more than 15% of the Sr and Th in an average arc magma were derived from subducted material, and that the rest were derived from the mantle wedge. The fluxes of elements which cannot be characterized isotopically are more difficult to constrain, but for most minor and trace elements the slab derived contribution in arc magmas is too small to have a noticeable effect on the residual slab.

Isotopic and trace element constraints on the genesis of a boninitic sequence in the Thetford Mines ophiolitic complex, Quebec, Canada

1997 ◽  
Vol 34 (9) ◽  
pp. 1258-1271 ◽  
Author(s):  
Valérie Olive ◽  
Réjean Hébert ◽  
Michel Loubet
Keyword(s):  
Trace Element ◽  
Trace Element Composition ◽  
Nd Isotope ◽  
Geodynamic Environment ◽  
The Pacific ◽  
Geochemical Study ◽  
Mid Ocean Ridge ◽  
Isochron Diagram ◽  
Component C ◽  
Ocean Ridge

The Mont Ham Massif (part of the Thetford Mines ophiolite, south Quebec) represents a magmatic sequence made up of tholeiitic and boninitic derived products. A geochemical study confirms the multicomponent mixing models that have been classically advanced for the source of boninites, with slab-derived components added to the main refractory harzburgitic peridotite. An isochron diagram of the boninitic rocks is interpreted as a mixing trend between two components: (i) a light rare earth element (LREE) enriched component (A), interpreted as slab-derived fluid–melts equilibrated with sedimentary materials (εNd = −3, 147Sm/144Nd = 0.140), and (ii) a LREE-depleted component (B) (0.21 < 147Sm/144Nd < 0.23), interpreted as slab-derived fluid–melt equilibrated with recycled Iapetus oceanic crust and equated to the Nd-isotope characteristics of the Iapetus mantle (εNd = 9). A multicomponent source is also necessary to explain the Nd-isotope and trace element composition of the tholeiites, which are explained by the melting of a more fertile, lherzolitic mantle and (or) mid-ocean ridge basalt source (component C), characterized by a large-ion lithophile element depleted pattern and an Iapetus mantle Nd isotopic composition (εNd = 9), mixed in adequate proportions with the two previously infered slab-derived components (A and B). The genesis of the boninites of Mont Ham is not significantly different from those of boninites located in the Pacific. An intraoceanic subduction zone appears to be an appropriate geodynamic environment for the Mont Ham ophiolitic sequence.

scholarly journals Variations of Source Composition and Melting Degrees of Olivine-Phyric Rocks from Kamchatsky Mys: Results of Geochemical Modeling of Trace Element Contents in Melts

Petrology ◽  
2021 ◽  
Vol 29 (1) ◽  
pp. 14-23
Author(s):  
N. Nekrylov ◽  
A. A. Korneeva ◽  
D. P. Savelyev ◽  
T. N. Antsiferova
Keyword(s):  
Trace Element ◽  
Geochemical Modeling ◽  
Magmatic Evolution ◽  
Mid Ocean Ridge ◽  
Trace Element Contents ◽  
Fractional Melting ◽  
Element Contents ◽  
Ocean Ridge ◽  
Batch Melting ◽  
Good Agreement

Abstract We conducted the geochemical modeling of trace element contents for primary melts of olivine-phyric rocks from Kamchatsky Mys. This modeling reveals substantial chemical heterogeneity of their source while the average source composition is close to the enriched DMM (E-DMM). The average estimation of the melting degree is in the range from 9.1 ± 3.8% for the model of modal batch melting to 15.4 ± 5.2% for the model of accumulated fractional melting, which is slightly higher than the estimation for primitive mid-ocean ridge basalt (MORB) glasses (7.4 ± 2.2% and 12.5 ± 3.8% respectively). It is in a good agreement with high melting degrees estimated earlier for other rocks of the Kamchatsky Mys ophiolites. Low pressure of mantle melting caused by the elevated speed of decompression relative to the average MORB could explain elevated melting degrees estimated for Kamhcatsky Mys ophiolites as well as their characteristic Sr-anomalies and sulfide saturation on the earliest stages of magmatic evolution.

Trace Element and Isotopic Evidence for Recycled Lithosphere from Basalts from 48 to 53°E, Southwest Indian Ridge

2020 ◽  
Author(s):  
Jixin Wang ◽  
Huaiyang Zhou ◽  
Vincent J M Salters ◽  
Henry J B Dick ◽  
Jared J Standish ◽  
...  
Keyword(s):  
Trace Element ◽  
Southwest Indian Ridge ◽  
Isotopic Compositions ◽  
Depleted Mantle ◽  
Bone Segment ◽  
Mid Ocean Ridge ◽  
Mantle Component ◽  
Indian Ridge ◽  
Basalt Glasses ◽  
Ocean Ridge

Abstract Mantle source heterogeneity and magmatic processes have been widely studied beneath most parts of the Southwest Indian Ridge (SWIR). But less is known from the newly recovered mid-ocean ridge basalts from the Dragon Bone Amagmatic Segment (53°E, SWIR) and the adjacent magmatically robust Dragon Flag Segment. Fresh basalt glasses from the Dragon Bone Segment are clearly more enriched in isotopic composition than the adjacent Dragon Flag basalts, but the trace element ratios of the Dragon Flag basalts are more extreme compared with average mid-ocean ridge basalts (MORB) than the Dragon Bone basalts. Their geochemical differences can be explained only by source differences rather than by variations in degree of melting of a roughly similar source. The Dragon Flag basalts are influenced by an arc-like mantle component as evidenced by enrichment in fluid-mobile over fluid-immobile elements. However, the sub-ridge mantle at the Dragon Flag Segment is depleted in melt component compared with a normal MORB source owing to previous melting in the subarc. This fluid-metasomatized, subarc depleted mantle is entrained beneath the Dragon Flag Segment. In comparison, for the Dragon Bone axial basalts, their Pb isotopic compositions and their slight enrichment in Ba, Nb, Ta, K, La, Sr and Zr and depletion in Pb and Ti concentrations show resemblance to the Ejeda–Bekily dikes of Madagascar. Also, Dragon Bone Sr and Nd isotopic compositions together with the Ce/Pb, La/Nb and La/Th ratios can be modeled by mixing the most isotopically depleted Dragon Flag basalts with a composition within the range of the Ejeda–Bekily dikes. It is therefore proposed that the Dragon Bone axial basalts, similar to the Ejeda–Bekily dikes, are sourced from subcontinental lithospheric Archean mantle beneath Gondwana, pulled from beneath the Madagascar Plateau. The recycling of the residual subarc mantle and the subcontinental lithospheric mantle could be related to either the breakup of Gondwana or the formation and accretion of Neoproterozoic island arc terranes during the collapse of the Mozambique Ocean, and is now present beneath the ridge.

Chemical Geodynamics of Asthenospheric Outflow in the western Pacific: Philippine Sea Back-arc Basin Mantle Source of the Yap Trench Forearc Lavas

2020 ◽  
Author(s):  
Limei Tang ◽  
Ling Chen
Keyword(s):  
Trace Element ◽  
Western Pacific ◽  
Philippine Sea Plate ◽  
Philippine Sea ◽  
Trace Element Chemistry ◽  
Lithospheric Extension ◽  
Mid Ocean Ridge ◽  
Back Arc ◽  
Ocean Ridge ◽  
The Western Pacific

&lt;p&gt;We present new major and trace element chemistry and Sr, Nd, and Pb isotope data from basalts, recovered from the forearc setting of the Yap Trench in the western Pacific, and discuss their melt evolution and petrogenesis within the framework of the geodynamic interactions among the Caroline Plate, the Caroline ridge, and the Philippine Sea plate. These rocks have mid-ocean ridge basalt (MORB)-like geochemical features, including medium Fe contents, tholeiitic affinity, high TiO&lt;sub&gt;2&lt;/sub&gt; values at a given Fe&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;/MgO ratio, Ti/V, Nb/Y, Ba/Yb, and Ba/Th ratios similar to those of back-arc basin basalts (BABB), and trace element patterns commonly displayed by MORB and BABB lavas. However, these basalts are characterized by highly radiogenic Sr and Pb contents, reminiscent of western Pacific sediments. We suggest that forearc magmatism was responsible for the origin and petrogenesis of these rocks. Forearc magmatism was induced by the shrinking of the Philippine Sea plate, which squeezed out the underlying back-arc basin asthenosphere with Indian&amp;#8211;type ambient mantle characteristics to invade the forearc mantle of the Yap Trench and causes lithospheric extension. Upwelling and decompression melting of this mantle produced MORB-like lavas in the narrow forearc setting. An apparent slab tear or gap in the subducting plate facilitate the penetration of the mantle outflow. The collision of the Caroline Ridge subducted more sediments into the mantle wedge. Melting of the subducted sediments and the invasion of the Indian-type asthenosphere into the forearc account for the highly radioactive Sr and Pb isotopes of the MORB-like lavas.&lt;/p&gt;

scholarly journals A Disequilibrium Reactive Transport Model for Mantle Magmatism

2020 ◽  
Author(s):  
Beñat Oliveira ◽  
Juan Carlos Afonso ◽  
Romain Tilhac
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Trace Element ◽  
Chemical Evolution ◽  
Reactive Transport ◽  
Major Elements ◽  
Phase Changes ◽  
Scale Model ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Abstract Besides standard thermo-mechanical conservation laws, a general description of mantle magmatism requires the simultaneous consideration of phase changes (e.g. from solid to liquid), chemical reactions (i.e. exchange of chemical components) and multiple dynamic phases (e.g. liquid percolating through a deforming matrix). Typically, these processes evolve at different rates, over multiple spatial scales and exhibit complex feedback loops and disequilibrium features. Partially as a result of these complexities, integrated descriptions of the thermal, mechanical and chemical evolution of mantle magmatism have been challenging for numerical models. Here we present a conceptual and numerical model that provides a versatile platform to study the dynamics and nonlinear feedbacks inherent in mantle magmatism and to make quantitative comparisons between petrological and geochemical datasets. Our model is based on the combination of three main modules: (1) a Two-Phase, Multi-Component, Reactive Transport module that describes how liquids and solids evolve in space and time; (2) a melting formalism, called Dynamic Disequilibirum Melting, based on thermodynamic grounds and capable of describing the chemical exchange of major elements between phases in disequilibrium; (3) a grain-scale model for diffusion-controlled trace-element mass transfer. We illustrate some of the benefits of the model by analyzing both major and trace elements during mantle magmatism in a mid-ocean ridge-like context. We systematically explore the effects of mantle potential temperature, upwelling velocity, degree of equilibrium and hetererogeneous sources on the compositional variability of melts and residual peridotites. Our model not only reproduces the main thermo-chemical features of decompression melting but also predicts counter-intuitive differentiation trends as a consequence of phase changes and transport occurring in disequilibrium. These include a negative correlation between Na2O and FeO in melts generated at the same Tp and the continued increase of the melt’s CaO/Al2O3 after Cpx exhaustion. Our model results also emphasize the role of disequilibrium arising from diffusion for the interpretation of trace-element signatures. The latter is shown to be able to reconcile the major- and trace-element compositions of abyssal peridotites with field evidence indicating extensive reaction between peridotites and melts. The combination of chemical disequilibrium of major elements and sluggish diffusion of trace elements may also result in weakened middle rare earth to heavy rare earth depletion comparable with the effect of residual garnet in mid-ocean ridge basalt, despite its absence in the modelled melts source. We also find that the crystallization of basalts ascending in disequilibrium through the asthenospheric mantle could be responsible for the formation of olivine gabbros and wehrlites that are observed in the deep sections of ophiolites. The presented framework is general and readily extendable to accommodate additional processes of geological relevance (e.g. melting in the presence of volatiles and/or of complex heterogeneous sources, refertilization of the lithospheric mantle, magma channelization and shallow processes) and the implementation of other geochemical and isotopic proxies. Here we illustrate the effect of heterogeneous sources on the thermo-mechanical-chemical evolution of melts and residues using a mixed peridotite–pyroxenite source.

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