scholarly journals Global estimates of mineral dust aerosol iron and aluminum solubility that account for particle size using diffusion-controlled and surface-area-controlled approximations

2012 ◽  
Vol 26 (2) ◽  
pp. n/a-n/a ◽  
Author(s):  
Qin Han ◽  
Charles S. Zender ◽  
J. Keith Moore ◽  
Clifton S. Buck ◽  
Ying Chen ◽  
...  
2018 ◽  
Vol 2 (4) ◽  
pp. 376-386 ◽  
Author(s):  
Sara Ibrahim ◽  
Manolis N. Romanias ◽  
Laurent Y. Alleman ◽  
Mohamad N. Zeineddine ◽  
Giasemi K. Angeli ◽  
...  

Atmosphere ◽  
2020 ◽  
Vol 11 (5) ◽  
pp. 533
Author(s):  
Aurelie R. Marcotte ◽  
Ariel D. Anbar ◽  
Brian J. Majestic ◽  
Pierre Herckes

There is significant iron deposition in the oceans, approximately 14–16 Tg annually from mineral dust aerosols, but only a small percentage (approx. 3%) of it is soluble and, thus, bioavailable. In this work, we examine the effect of mineralogy, particle size, and surface area on iron solubility in pure mineral phases to simulate atmospheric processing of mineral dust aerosols during transport. Pure iron-bearing minerals common to Saharan dust were partitioned into four size fractions (10–2.5, 2.5–1, 1–0.5, and 0.5–0.25 µm) and extracted into moderately acidic (pH 4.3) and acidic (pH 1.7) leaching media to simulate mineral processing during atmospheric transport. Results show that, in general, pure iron-bearing clay materials present an iron solubility (% dissolved Fe/total Fe in the mineral) an order of magnitude higher than pure iron oxide minerals. The relative solubility of iron in clay particles does not depend on particle size for the ranges examined (0.25–10 μm), while iron in hematite and magnetite shows a trend of increasing solubility with decreasing particle size in the acidic leaching medium. Our results indicate that while mineralogy and aerosol pH have an effect on the solubilization of iron from simulated mineral dust particles, surface processes of the aerosol might also have a role in iron solubilization during transport. The surface area of clay minerals does not change significantly as a function of particle size (10–0.25 µm), while the surface area of iron oxides is strongly size dependent. Overall, these results show how mineralogy and particle size can influence iron solubility in atmospheric dust.


2006 ◽  
Vol 111 (D17) ◽  
Author(s):  
G. Foret ◽  
G. Bergametti ◽  
F. Dulac ◽  
L. Menut

2011 ◽  
Vol 11 (12) ◽  
pp. 6049-6062 ◽  
Author(s):  
X. Yue ◽  
H. Liao ◽  
H. J. Wang ◽  
S. L. Li ◽  
J. P. Tang

Abstract. Mineral dust aerosol can be transported over the nearby oceans and influence the energy balance at the sea surface. The role of dust-induced sea surface temperature (SST) responses in simulations of the climatic effect of dust is examined by using a general circulation model with online simulation of mineral dust and a coupled mixed-layer ocean model. Both the longwave and shortwave radiative effects of mineral dust aerosol are considered in climate simulations. The SST responses are found to be very influential on simulated dust-induced climate change, especially when climate simulations consider the two-way dust-climate coupling to account for the feedbacks. With prescribed SSTs and dust concentrations, we obtain an increase of 0.02 K in the global and annual mean surface air temperature (SAT) in response to dust radiative effects. In contrast, when SSTs are allowed to respond to radiative forcing of dust in the presence of the dust cycle-climate interactions, we obtain a global and annual mean cooling of 0.09 K in SAT by dust. The extra cooling simulated with the SST responses can be attributed to the following two factors: (1) The negative net (shortwave plus longwave) radiative forcing of dust at the surface reduces SST, which decreases latent heat fluxes and upward transport of water vapor, resulting in less warming in the atmosphere; (2) The positive feedback between SST responses and dust cycle. The dust-induced reductions in SST lead to reductions in precipitation (or wet deposition of dust) and hence increase the global burden of small dust particles. These small particles have strong scattering effects, which enhance the dust cooling at the surface and further reduce SSTs.


2014 ◽  
Vol 15 ◽  
pp. 319-334 ◽  
Author(s):  
Sandra Lafon ◽  
Stéphane C. Alfaro ◽  
Servanne Chevaillier ◽  
Jean Louis Rajot

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