Correlated IR spectroscopy and visible light scattering measurements of mineral dust aerosol

2010 ◽  
Vol 115 (D20) ◽  
Author(s):  
B. Meland ◽  
P. D. Kleiber ◽  
V. H. Grassian ◽  
M. A. Young
2013 ◽  
Vol 118 (2) ◽  
pp. 435-452 ◽  
Author(s):  
Jennifer M. Alexander ◽  
Olga Laskina ◽  
Brian Meland ◽  
Mark A. Young ◽  
Vicki H. Grassian ◽  
...  

2013 ◽  
Vol 9 ◽  
pp. 1278-1284 ◽  
Author(s):  
Helmut Ritter ◽  
Berit Knudsen ◽  
Valerij Durnev

We report the noncovalent linkage of terminally substituted oligo(dimethylsiloxanes) bearing α-cyclodextrins (α-CD) as host end groups for the cyclopentadienyl rings of ferrocene. This double complexation of unsubstituted ferrocene leads to a supramolecuar formation of the siloxane strands. Structural characterization was performed by the use of 1H NMR and IR spectroscopy and by mass spectrometry. Electron microscopy studies and dynamic light scattering measurements show a significant decrease of the derivative size after the complexation with ferrocene. In addition, further evidence for the successful complexation of the end groups was verified by the shifts of the protons in the 1H NMR spectra and in the correlation signals of the 2D ROESY NMR spectra.


Author(s):  
Daniel B. Curtis ◽  
Brian Meland ◽  
Murat Aycibin ◽  
Nathan P. Arnold ◽  
Vicki H. Grassian ◽  
...  

2003 ◽  
Vol 762 ◽  
Author(s):  
Claudio J. Oton ◽  
Zeno Gaburro ◽  
Mher Ghulinyan ◽  
Nicola Daldosso ◽  
Lucio Pancheri ◽  
...  

AbstractWe report the observation of strongly anisotropic scattering of laser light at oblique incidence on (100)-oriented porous silicon layers. We performed angle-resolved light scattering measurements and three concentric rings were observed. Modeling porous silicon by means of nanometric columnar air pores and an effective anisotropic uniaxial dielectric constant explains the observed phenomenon, and besides, the observation of the angle aperture of these rings allows a direct measurement of relative birefringence. We finally study the changes of optical anisotropy after different modifications of the structure.


2011 ◽  
Vol 11 (12) ◽  
pp. 6049-6062 ◽  
Author(s):  
X. Yue ◽  
H. Liao ◽  
H. J. Wang ◽  
S. L. Li ◽  
J. P. Tang

Abstract. Mineral dust aerosol can be transported over the nearby oceans and influence the energy balance at the sea surface. The role of dust-induced sea surface temperature (SST) responses in simulations of the climatic effect of dust is examined by using a general circulation model with online simulation of mineral dust and a coupled mixed-layer ocean model. Both the longwave and shortwave radiative effects of mineral dust aerosol are considered in climate simulations. The SST responses are found to be very influential on simulated dust-induced climate change, especially when climate simulations consider the two-way dust-climate coupling to account for the feedbacks. With prescribed SSTs and dust concentrations, we obtain an increase of 0.02 K in the global and annual mean surface air temperature (SAT) in response to dust radiative effects. In contrast, when SSTs are allowed to respond to radiative forcing of dust in the presence of the dust cycle-climate interactions, we obtain a global and annual mean cooling of 0.09 K in SAT by dust. The extra cooling simulated with the SST responses can be attributed to the following two factors: (1) The negative net (shortwave plus longwave) radiative forcing of dust at the surface reduces SST, which decreases latent heat fluxes and upward transport of water vapor, resulting in less warming in the atmosphere; (2) The positive feedback between SST responses and dust cycle. The dust-induced reductions in SST lead to reductions in precipitation (or wet deposition of dust) and hence increase the global burden of small dust particles. These small particles have strong scattering effects, which enhance the dust cooling at the surface and further reduce SSTs.


2014 ◽  
Vol 15 ◽  
pp. 319-334 ◽  
Author(s):  
Sandra Lafon ◽  
Stéphane C. Alfaro ◽  
Servanne Chevaillier ◽  
Jean Louis Rajot

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