scholarly journals Aging of biomass burning aerosols over West Africa: Aircraft measurements of chemical composition, microphysical properties, and emission ratios

2008 ◽  
Vol 113 ◽  
Author(s):  
G. Capes ◽  
B. Johnson ◽  
G. McFiggans ◽  
P. I. Williams ◽  
J. Haywood ◽  
...  
Keyword(s):  
Chemical Composition ◽  
West Africa ◽  
Biomass Burning ◽  
Aircraft Measurements ◽  
Microphysical Properties ◽  
Emission Ratios

scholarly journals Aerosol Characterization during the Summer 2017 Huge Fire Event on Mount Vesuvius (Italy) by Remote Sensing and In Situ Observations

2021 ◽  
Vol 13 (10) ◽  
pp. 2001
Author(s):  
Antonella Boselli ◽  
Alessia Sannino ◽  
Mariagrazia D’Emilio ◽  
Xuan Wang ◽  
Salvatore Amoruso
Keyword(s):  
Remote Sensing ◽  
Biomass Burning ◽  
Ground Level ◽  
Large Area ◽  
Fire Event ◽  
Near Surface ◽  
Mean Values ◽  
Microphysical Properties ◽  
Observational Site ◽  
Biomass Burning Aerosol

During the summer of 2017, multiple huge fires occurred on Mount Vesuvius (Italy), dispersing a large quantity of ash in the surrounding area ensuing the burning of tens of hectares of Mediterranean scrub. The fires affected a very large area of the Vesuvius National Park and the smoke was driven by winds towards the city of Naples, causing daily peak values of particulate matter (PM) concentrations at ground level higher than the limit of the EU air quality directive. The smoke plume spreading over the area of Naples in this period was characterized by active (lidar) and passive (sun photometer) remote sensing as well as near-surface (optical particle counter) observational techniques. The measurements allowed us to follow both the PM variation at ground level and the vertical profile of fresh biomass burning aerosol as well as to analyze the optical and microphysical properties. The results evidenced the presence of a layer of fine mode aerosol with large mean values of optical depth (AOD > 0.25) and Ångstrom exponent (γ > 1.5) above the observational site. Moreover, the lidar ratio and aerosol linear depolarization obtained from the lidar observations were about 40 sr and 4%, respectively, consistent with the presence of biomass burning aerosol in the atmosphere.

Cloud Microphysical Properties Retrieval During Intense Biomass Burning Events Over Africa and Portugal

2007 ◽  
pp. 97-111 ◽  
Author(s):  
Maria João Costa ◽  
Elsa Cattani ◽  
Vincenzo Levizzan ◽  
Ana Maria Silva
Keyword(s):  
Biomass Burning ◽  
Microphysical Properties

Biomass Burning Effects on the Climate over Southern West Africa During the Summer Monsoon

2020 ◽  
pp. 1-18
Author(s):  
Alima Dajuma ◽  
Siélé Silué ◽  
Kehinde O. Ogunjobi ◽  
Heike Vogel ◽  
Evelyne Touré N’Datchoh ◽  
...  
Keyword(s):  
West Africa ◽  
Summer Monsoon ◽  
Biomass Burning

scholarly journals The tropical forest and fire emissions experiment: method evaluation of volatile organic compound emissions measured by PTR-MS, FTIR, and GC from tropical biomass burning

2007 ◽  
Vol 7 (3) ◽  
pp. 8755-8793 ◽  
Author(s):  
T. G. Karl ◽  
T. J. Christian ◽  
R. J. Yokelson ◽  
P. Artaxo ◽  
W. Min Hao ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Organic Compound ◽  
Tropical Forest ◽  
Biomass Burning ◽  
Volatile Organic Compound ◽  
Charge Ratio ◽  
Voc Emissions ◽  
Fire Emissions ◽  
Volatile Organic ◽  
Emission Ratios

Abstract. Volatile Organic Compound (VOC) emissions from fires in tropical forest fuels were quantified using Proton-Transfer-Reaction Mass Spectrometry (PTRMS), Fourier Transformation Infrared Spectroscopy (FTIR) and gas chromatography (GC) coupled to PTRMS (GC-PTR-MS). We investigated VOC emissions from 19 controlled laboratory fires at the USFS Fire Sciences Laboratory and 16 fires during an intensive airborne field campaign during the peak of the burning season in Brazil in 2004. The VOC emissions were dominated by oxygenated VOCs (OVOC) (OVOC/NMHC ~4:1, NMHC: non-methane hydrocarbons) The specificity of the PTR-MS instrument, which measures the mass to charge ratio of VOCs ionized by H3O+ ions, was validated by gas chromatography and by intercomparing in-situ measurements with those obtained from an open path FTIR instrument. Emission ratios for methyl vinyl ketone, methacrolein, crotonaldehyde, acrylonitrile and pyrrole were measured in the field for the first time. Our measurements show a higher contribution of OVOCs than previously assumed for modeling purposes. Comparison of fresh (<15 min) and aged (>1hour-1day) smoke suggests altered emission ratios due to gas phase chemistry for acetone but not for acetaldehyde and methanol. Emission ratios for numerous, important, reactive VOCs with respect to acetonitrile (a biomass burning tracer) are presented.

scholarly journals Processing of biomass burning aerosol in the Eastern Mediterranean during summertime

2013 ◽  
Vol 13 (10) ◽  
pp. 25969-25999 ◽  
Author(s):  
A. Bougiatioti ◽  
I. Stavroulas ◽  
E. Kostenidou ◽  
P. Zarmpas ◽  
C. Theodosi ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Biomass Burning ◽  
Eastern Mediterranean ◽  
Late Summer ◽  
Organic Aerosol ◽  
High Temporal Resolution ◽  
Night Time ◽  
Air Masses ◽  
Aerosol Mass ◽  
Atmospheric Processing

Abstract. The aerosol chemical composition in air masses affected by wildfires from the Greek islands of Chios, Euboea and Andros, the Dalmatian Coast and Sicily, during late summer of 2012 was characterized at the remote background site of Finokalia, Crete. Air masses were transported several hundreds of kilometers, arriving at the measurement station after approximately half a day of transport, mostly during night-time. The chemical composition of the particulate matter was studied by different high temporal resolution instruments, including an Aerosol Chemical Speciation Monitor (ACSM) and a seven-wavelength aethalometer. Despite the large distance from emission and long atmospheric processing, a clear biomass burning organic aerosol (BBOA) profile containing characteristic markers is derived from BC measurements and Positive Matrix Factorization (PMF) analysis of the ACSM mass spectra. The ratio of fresh to aged BBOA decreases with increasing atmospheric processing time and BBOA components appear to be converted to oxygenated organic aerosol (OOA). Given that the smoke was mainly transported overnight, it appears that the processing can take place in the dark. These results show that a significant fraction of the BBOA loses its characteristic AMS signature and is transformed to OOA in less than a day. This implies that biomass burning can contribute almost half of the organic aerosol mass in the area during summertime.

Trace gases and organic aerosol at a rural site in Vietnam during large scale biomass burning

2021 ◽  
Author(s):  
Simone M. Pieber ◽  
Dac-Loc Nguyen ◽  
Hendryk Czech ◽  
Stephan Henne ◽  
Nicolas Bukowiecki ◽  
...  
Keyword(s):  
Air Quality ◽  
Chemical Composition ◽  
Biomass Burning ◽  
Large Scale ◽  
Trace Gases ◽  
Organic Aerosol ◽  
Trace Gas ◽  
Rural Site ◽  
Air Masses ◽  
Mixing Ratios

&lt;p&gt;Open biomass burning (BB) is a globally widespread phenomenon. The fires release pollutants, which are harmful for human and ecosystem health and alter the Earth's radiative balance. Yet, the impact of various types of BB on the global radiative forcing remains poorly constrained concerning greenhouse gas emissions, BB organic aerosol (OA) chemical composition and related light absorbing properties. Fire emissions composition is influenced by multiple factors (e.g., fuel and thereby vegetation-type, fuel moisture, fire temperature, available oxygen). Due to regional variations in these parameters, studies in different world regions are needed. Here we investigate the influence of seasonally recurring BB on trace gas concentration and air quality at the regional Global Atmosphere Watch (GAW) station Pha Din (PDI) in rural Northwestern Vietnam. PDI is located in a sparsely populated area on the top of a hill (1466 m a.s.l.) and is well suited to study the large-scale fires on the Indochinese Peninsula, whose pollution plumes are frequently transported towards the site [1]. We present continuous trace gas observations of CO&lt;sub&gt;2&lt;/sub&gt;, CH&lt;sub&gt;4&lt;/sub&gt;, CO, and O&lt;sub&gt;3&lt;/sub&gt; conducted at PDI since 2014 and interpret the data with atmospheric transport simulations. Annually recurrent large scale BB leads to hourly time-scale peaks CO mixing ratios at PDI of 1000 to 1500 ppb around every April since the start of data collection in 2014. We complement this analysis with carbonaceous PM&lt;sub&gt;2.5 &lt;/sub&gt;chemical composition analyzed during an intensive campaign in March-April 2015. This includes measurements of elemental and organic carbon (EC/OC) and more than 50 organic markers, such as sugars, PAHs, fatty acids and nitro-aromatics [2]. For the intensive campaign, we linked CO, CO&lt;sub&gt;2&lt;/sub&gt;, CH&lt;sub&gt;4&lt;/sub&gt; and O&lt;sub&gt;3&lt;/sub&gt; mixing ratios to a statistical classification of BB events, which is based on OA composition. We found increased CO and O&lt;sub&gt;3&lt;/sub&gt; levels during medium and high BB influence during the intensive campaign. A backward trajectory analysis confirmed different source regions for the identified periods based on the OA cluster. Typically, cleaner air masses arrived from northeast, i.e., mainland China and Yellow sea during the intensive campaign. The more polluted periods were characterized by trajectories from southwest, with more continental recirculation of the medium cluster, and more westerly advection for the high cluster. These findings highlight that BB activities in Northern Southeast Asia significantly enhances the regional OA loading, chemical PM&lt;sub&gt;2.5 &lt;/sub&gt;composition and the trace gases in northwestern Vietnam. The presented analysis adds valuable data on air quality in a region of scarce data availability.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;REFERENCES&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;[1] Bukowiecki, N. et al. Effect of Large-scale Biomass Burning on Aerosol Optical Properties at the GAW Regional Station Pha Din, Vietnam. AAQR. 19, 1172&amp;#8211;1187 (2019).&lt;/p&gt;&lt;p&gt;[2] Nguyen, D. L, et al. Carbonaceous aerosol composition in air masses influenced by large-scale biomass burning: a case-study in Northwestern Vietnam. ACPD., https://doi.org/10.5194/acp-2020-1027, in review, 2020.&lt;/p&gt;

scholarly journals Biomass burning emission disturbances of isoprene oxidation in a tropical forest

2018 ◽  
Vol 18 (17) ◽  
pp. 12715-12734 ◽  
Author(s):  
Fernando Santos ◽  
Karla Longo ◽  
Alex Guenther ◽  
Saewung Kim ◽  
Dasa Gu ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Biomass Burning ◽  
Oxidative Capacity ◽  
Oxidation Products ◽  
Amazon Rainforest ◽  
Amazon Forest ◽  
Oxidation Reactions ◽  
Smoke Plumes ◽  
Isoprene Oxidation ◽  
The Impact

Abstract. We present a characterization of the chemical composition of the atmosphere of the Brazilian Amazon rainforest based on trace gas measurements carried out during the South AMerican Biomass Burning Analysis (SAMBBA) airborne experiment in September 2012. We analyzed the observations of primary biomass burning emission tracers, i.e., carbon monoxide (CO), nitrogen oxides (NOx), ozone (O3), isoprene, and its main oxidation products, methyl vinyl ketone (MVK), methacrolein (MACR), and isoprene hydroxy hydroperoxide (ISOPOOH). The focus of SAMBBA was primarily on biomass burning emissions, but there were also several flights in areas of the Amazon forest not directly affected by biomass burning, revealing a background with a signature of biomass burning in the chemical composition due to long-range transport of biomass burning tracers from both Africa and the eastern part of Amazonia. We used the [MVK + MACR + ISOPOOH] ∕ [isoprene] ratio and the hydroxyl radical (OH) indirect calculation to assess the oxidative capacity of the Amazon forest atmosphere. We compared the background regions (CO < 150 ppbv), fresh and aged smoke plumes classified according to their photochemical age ([O3] ∕ [CO]), to evaluate the impact of biomass burning emissions on the oxidative capacity of the Amazon forest atmosphere. We observed that biomass burning emissions disturb the isoprene oxidation reactions, especially for fresh plumes ([MVK + MACR + ISOPOOH] ∕ [isoprene] =  7) downwind. The oxidation of isoprene is higher in fresh smoke plumes at lower altitudes (∼ 500 m) than in aged smoke plumes, anticipating near the surface a complex chain of oxidation reactions which may be related to secondary organic aerosol (SOA) formation. We proposed a refinement of the OH calculation based on the sequential reaction model, which considers vertical and horizontal transport for both biomass burning regimes and background environment. Our approach for the [OH] estimation resulted in values on the same order of magnitude of a recent observation in the Amazon rainforest [OH] ≅ 106 (molecules cm−3). During the fresh plume regime, the vertical profile of [OH] and the [MVK + MACR + ISOPOOH] ∕ [isoprene] ratio showed evidence of an increase in the oxidizing power in the transition from planetary boundary layer to cloud layer (1000–1500 m). These high values of [OH] (1.5 × 106 molecules cm−3) and [MVK + MACR + ISOPOOH] ∕ [isoprene] (7.5) indicate a significant change above and inside the cloud decks due to cloud edge effects on photolysis rates, which have a major impact on OH production rates.

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