scholarly journals A two-dimensional atmospheric chemistry modeling investigation of Earth's Phanerozoic O3and near-surface ultraviolet radiation history

2007 ◽  
Vol 112 (D7) ◽  
Author(s):  
Michael B. J. Harfoot ◽  
David J. Beerling ◽  
Barry H. Lomax ◽  
John A. Pyle
Keyword(s):  
Ultraviolet Radiation ◽  
Atmospheric Chemistry ◽  
Two Dimensional ◽  
Near Surface ◽  
Radiation History ◽  
Chemistry Modeling

The response of planktonic phosphate uptake and turnover to ultraviolet radiation in Lake Erie

2002 ◽  
Vol 59 (5) ◽  
pp. 778-786 ◽  
Author(s):  
C D Allen ◽  
R E.H Smith
Keyword(s):  
Ultraviolet Radiation ◽  
Lake Erie ◽  
Radiation Treatment ◽  
Phosphate Uptake ◽  
Ultraviolet B ◽  
Phosphate Limitation ◽  
Bacterial Cells ◽  
Near Surface ◽  
Ambient Concentrations ◽  
Uptake Activity

The hypothesis that ambient ultraviolet radiation (UVR), at near-surface intensities, may diminish phosphorus availability to phytoplankton was tested in Lake Erie in July and August of 1998 and 1999. Relative to samples exposed to photosynthetically active radiation (PAR, 400–700 nm) only, those exposed to ultraviolet-B (UVB, 280–320) and (or) ultraviolet-A (UVA, 320–400 nm) in natural sunlight, or kept in darkness, had diminished phosphate uptake rates at elevated (1 µM P) dissolved phosphate concentrations. By contrast, the specific uptake rate of dissolved phosphate at ambient concentrations (turnover rate) was not significantly affected by UVR or darkness. Turnover was usually dominated by particles smaller than 0.8 µm, whereas uptake from elevated concentrations was dominated by larger particles. The size distribution of turnover and uptake activity was not affected by radiation treatment. Chlorophyll a concentrations were decreased by sufficient exposure to UVB and (or) UVA and increased by deprivation of PAR (dark controls), but the concentration of bacterial cells was unaffected. The results showed that UVR inhibited the phosphate uptake potential of larger, probably algal, plankton but did not change the apparent severity of phosphate limitation at ambient concentrations.

Two-dimensional elastic pseudo-spectral modeling of wide-aperture seismic array data with application to the Wichita Uplift-Anadarko Basin region of southwestern Oklahoma

1990 ◽  
Vol 80 (6A) ◽  
pp. 1677-1695 ◽  
Author(s):  
Ik Bum Kang ◽  
George A. McMechan
Keyword(s):  
Large Scale ◽  
Deep Structure ◽  
Sedimentary Basins ◽  
P Wave ◽  
Two Dimensional ◽  
Anadarko Basin ◽  
Near Surface ◽  
University Of Texas ◽  
Wide Aperture ◽  
The University

Abstract Full wave field modeling of wide-aperture data is performed with a pseudospectral implementation of the elastic wave equation. This approach naturally produces three-component stress and two-component particle displacement, velocity, and acceleration seismograms for compressional, shear, and Rayleigh waves. It also has distinct advantages in terms of computational requirements over finite-differencing when data from large-scale structures are to be modeled at high frequencies. The algorithm is applied to iterative two-dimensional modeling of seismograms from a survey performed in 1985 by The University of Texas at El Paso and The University of Texas at Dallas across the Anadarko basin and the Wichita Mountains in southwestern Oklahoma. The results provide an independent look at details of near-surface structure and reflector configurations. Near-surface (<3 km deep) structure and scattering effects account for a large percentage (>70 per cent) of the energy in the observed seismograms. The interpretation of the data is consistent with the results of previous studies of these data, but provides considerably more detail. Overall, the P-wave velocities in the Wichita Uplift are more typical of the middle crust than the upper crust (5.3 to 7.1 km/sec). At the surface, the uplift is either exposed as weathered outcrop (5.0 to 5.3 km/sec) or is overlain with sediments of up to 0.4 km in thickness, ranging in velocity from 2.7 to 3.4 km/sec, generally increasing with depth. The core of the uplift is relatively seismically transparent. A very clear, coherent reflection is observed from the Mountain View fault, which dips at ≈40° to the southwest, to at least 12 km depth. Velocities in the Anadarko Basin are typical of sedimentary basins; there is a general increase from ≈2.7 km/sec at the surface to ≈5.9 km/sec at ≈16 km depth, with discontinuous reflections at depths of ≈8, 10, 12, and 16 km.

Experiments on wind-driven heat exchange processes over melting snow

2021 ◽  
Author(s):  
Michael Haugeneder ◽  
Tobias Jonas ◽  
Dylan Reynolds ◽  
Michael Lehning ◽  
Rebecca Mott
Keyword(s):  
Snow Cover ◽  
Surface Wind ◽  
Infrared Camera ◽  
Snow Accumulation ◽  
Internal Boundary ◽  
Small Scale ◽  
Snow Melt ◽  
Two Dimensional ◽  
Atmospheric Conditions ◽  
Near Surface

<p>Snowmelt runoff predictions in alpine catchments are challenging because of the high spatial variability of t<span>he snow cover driven by </span>various snow accumulation and ablation processes. In spring, the coexistence of bare and snow-covered ground engages a number of processes such as the enhanced lateral advection of heat over partial snow cover, the development of internal boundary layers, and atmospheric decoupling effects due to increasing stability at the snow cover. The interdependency of atmospheric conditions, topographic settings and snow coverage remains a challenge to accurately account for these processes in snow melt models.<br>In this experimental study, we used an Infrared Camera (VarioCam) pointing at thin synthetic projection screens with negligible heat capacity. Using the surface temperature of the screen as a proxy for the air temperature, we obtained a two-dimensional instantaneous measurement. Screens were installed across the transition between snow-free and snow-covered areas. With IR-measurements taken at 10Hz, we capture<span> the dynamics of turbulent temperature fluctuations</span><span> </span>over the patchy snow cover at high spatial and temporal resolution. From this data we were able to obtain high-frequency, two-dimensional windfield estimations adjacent to the surface.</p><p>Preliminary results show the formation of a stable internal boundary layer (SIBL), which was temporally highly variable. Our data suggest that the SIBL height is very shallow and strongly sensitive to the mean near-surface wind speed. Only strong gusts were capable of penetrating through this SIBL leading to an enhanced energy input to the snow surface.</p><p>With these type of results from our experiments and further measurements this spring we aim to better understand small scale energy transfer processes over patch snow cover and it’s dependency on the atmospheric conditions, enabling to improve parameterizations of these processes in coarser-resolution snow melt models.</p>

scholarly journals Effects of temperature on the heterogeneous oxidation of sulfur dioxide by ozone on calcium carbonate

2011 ◽  
Vol 11 (13) ◽  
pp. 6593-6605 ◽  
Author(s):  
L. Y. Wu ◽  
S. R. Tong ◽  
W. G. Wang ◽  
M. F. Ge
Keyword(s):  
Sulfur Dioxide ◽  
Atmospheric Chemistry ◽  
Ambient Pressure ◽  
Oxidation Reactions ◽  
Heterogeneous Oxidation ◽  
Fourier Transform Spectrometry ◽  
Different Temperatures ◽  
Chemistry Modeling ◽  
Sulfate Formation ◽  
Diffuse Reflectance Infrared

Abstract. The heterogeneous oxidation of sulfur dioxide by ozone on CaCO3 was studied as a function of temperature (230 to 298 K) at ambient pressure. Oxidation reactions were followed in real time using diffuse reflectance infrared Fourier transform spectrometry (DRIFTS) to obtain kinetic and mechanistic data. From the analysis of the spectral features, the formation of sulfate was identified on the surface in the presence of O3 and SO2 at different temperatures from 230 to 298 K. The results showed that the heterogeneous oxidation and the rate of sulfate formation were sensitive to temperature. An interesting stage-transition region was observed at temperatures ranging from 230 to 257 K, but it became ambiguous gradually above 257 K. The reactive uptake coefficients at different temperatures from 230 to 298 K were acquired for the first time, which can be used directly in atmospheric chemistry modeling studies to predict the formation of secondary sulfate aerosol in the troposphere. Furthermore, the rate of sulfate formation had a turning point at about 250 K. The sulfate concentration at 250 K was about twice as large as that at 298 K. The rate of sulfate formation increased with decreasing temperature at temperatures above 250 K, while there is a contrary temperature effect at temperatures below 250 K. The activation energy for heterogeneous oxidation at temperatures from 245 K to 230 K was determined to be 14.63 ± 0.20 kJ mol−1. A mechanism for the temperature dependence was proposed and the atmospheric implications were discussed.

scholarly journals The Brazilian developments on the Regional Atmospheric Modeling System (BRAMS 5.2): an integrated environmental model tuned for tropical areas

2016 ◽  
Author(s):  
Saulo R. Freitas ◽  
Jairo Panetta ◽  
Karla M. Longo ◽  
Luiz F. Rodrigues ◽  
Demerval S. Moreira ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
South America ◽  
Atmospheric Chemistry ◽  
Amazon Basin ◽  
Carbon Dioxide Concentration ◽  
Atmospheric Modeling ◽  
Tracer Transport ◽  
Regional Atmospheric Modeling System ◽  
Near Surface ◽  
Regional Atmospheric Modeling

Abstract. We present a new version of the Brazilian developments on the Regional Atmospheric Modeling System where different previous versions for weather, chemistry and carbon cycle were unified in a single integrated software system. The new version also has a new set of state-of-the-art physical parameterizations and greater computational parallel and memory usage efficiency. Together with the description of the main features are examples of the quality of the transport scheme for scalars, radiative fluxes on surface and model simulation of rainfall systems over South America in different spatial resolutions using a scale-aware convective parameterization. Besides, the simulation of the diurnal cycle of the convection and carbon dioxide concentration over the Amazon Basin, as well as carbon dioxide fluxes from biogenic processes over a large portion of South America are shown. Atmospheric chemistry examples present model performance in simulating near-surface carbon monoxide and ozone in Amazon Basin and Rio de Janeiro megacity. For tracer transport and dispersion, it is demonstrated the model capabilities to simulate the volcanic ash 3-d redistribution associated with the eruption of a Chilean volcano. Then, the gain of computational efficiency is described with some details. BRAMS has been applied for research and operational forecasting mainly in South America. Model results from the operational weather forecast of BRAMS on 5 km grid spacing in the Center for Weather Forecasting and Climate Studies, INPE/Brazil, since 2013 are used to quantify the model skill of near surface variables and rainfall. The scores show the reliability of BRAMS for the tropical and subtropical areas of South America. Requirements for keeping this modeling system competitive regarding on its functionalities and skills are discussed. At last, we highlight the relevant contribution of this work on the building up of a South American community of model developers.

scholarly journals On the role of tropopause folds in summertime tropospheric ozone over the eastern Mediterranean and the Middle East

2016 ◽  
Vol 16 (21) ◽  
pp. 14025-14039 ◽  
Author(s):  
Dimitris Akritidis ◽  
Andrea Pozzer ◽  
Prodromos Zanis ◽  
Evangelos Tyrlis ◽  
Bojan Škerlak ◽  
...  
Keyword(s):  
Middle East ◽  
Atmospheric Chemistry ◽  
Tropospheric Ozone ◽  
Eastern Mediterranean ◽  
Stratospheric Ozone ◽  
Surface Ozone ◽  
Free Troposphere ◽  
Near Surface ◽  
Grid Points ◽  
High Concentrations

Abstract. We study the contribution of tropopause folds in the summertime pool of tropospheric ozone over the eastern Mediterranean and the Middle East (EMME) with the aid of the ECHAM5/MESSy Atmospheric Chemistry (EMAC) model. Tropopause fold events in EMAC simulations were identified with a 3-D labeling algorithm that detects folds at grid points where multiple crossings of the dynamical tropopause are computed. Subsequently the events featuring the largest horizontal and vertical extent were selected for further study. For the selection of these events we identified a significant contribution of the stratospheric ozone reservoir to the high concentrations of ozone in the middle and lower free troposphere over the EMME. A distinct increase of ozone is found over the EMME in the middle troposphere during summer as a result of the fold activity, shifting towards the southeast and decreasing altitude. We find that the interannual variability of near-surface ozone over the eastern Mediterranean (EM) during summer is related to that of both tropopause folds and ozone in the free troposphere.

Numerical Simulation of Non-Gaussian Wave Elevation and Kinematics Based on Two-Dimensional Fourier Transform

2006 ◽  
Author(s):  
Xiang Yuan Zheng ◽  
Torgeir Moan ◽  
Ser Tong Quek
Keyword(s):  
Fourier Transform ◽  
Wave Interaction ◽  
Wave Theory ◽  
Two Dimensions ◽  
Second Order ◽  
Interaction Matrix ◽  
Random Wave ◽  
Two Dimensional ◽  
Near Surface ◽  
Wave Elevation

The one-dimensional Fast Fourier Transform (FFT) has been extensively applied to efficiently simulate Gaussian wave elevation and water particle kinematics. The actual sea elevation/kinematics exhibit non-Gaussianities that mathematically can be represented by the second-order random wave theory. The elevation/kinematics formulation contains double-summation frequency sum and difference terms which in computation make the dynamic analysis of offshore structural response prohibitive. This study aims at a direct and efficient two-dimensional FFT algorithm for simulating the frequency sum terms. For the frequency difference terms, inverse FFT and FFT are respectively implemented across the two dimensions of the wave interaction matrix. Given specified wave conditions, not only the wave elevation but kinematics and associated Morison force are simulated. Favorable agreements are achieved when the statistics of elevation/kinematics are compared with not only the empirical fits but the analytical solutions developed based on modified eigenvalue/eigenvector approach, while the computation effort is very limited. In addition, the stochastic analyses in both time-and frequency domains show that the near-surface Morison force and induced linear oscillator response exhibits stronger non-Gaussianities by involving the second-order wave effects.

Sign in / Sign up

Export Citation Format

Share Document