scholarly journals Free tropospheric measurements of formic acid (HCOOH) from infrared ground-based solar absorption spectra: Retrieval approach, evidence for a seasonal cycle, and comparison with model calculations

2004 ◽  
Vol 109 (D18) ◽  
Author(s):  
Curtis P. Rinsland
2016 ◽  
Vol 9 (2) ◽  
pp. 577-585 ◽  
Author(s):  
Matthias Buschmann ◽  
Nicholas M. Deutscher ◽  
Vanessa Sherlock ◽  
Mathias Palm ◽  
Thorsten Warneke ◽  
...  

Abstract. High-resolution solar absorption spectra, taken within the Network for the Detection of Atmospheric Composition Change Infrared Working Group (NDACC-IRWG) in the mid-infrared spectral region, are used to infer partial or total column abundances of many gases. In this paper we present the retrieval of a column-averaged mole fraction of carbon dioxide from NDACC-IRWG spectra taken with a Fourier transform infrared (FTIR) spectrometer at the site in Ny-Ålesund, Spitsbergen. The retrieved time series is compared to colocated standard TCCON (Total Carbon Column Observing Network) measurements of column-averaged dry-air mole fractions of CO2 (denoted by xCO2). Comparing the NDACC and TCCON retrievals, we find that the sensitivity of the NDACC retrieval is lower in the troposphere (by a factor of 2) and higher in the stratosphere, compared to TCCON. Thus, the NDACC retrieval is less sensitive to tropospheric changes (e.g., the seasonal cycle) in the column average.


2015 ◽  
Vol 8 (10) ◽  
pp. 10523-10548 ◽  
Author(s):  
M. Buschmann ◽  
N. M. Deutscher ◽  
V. Sherlock ◽  
M. Palm ◽  
T. Warneke ◽  
...  

Abstract. High resolution solar absorption spectra, taken within the Network for the Detection of Atmospheric Composition Change (NDACC) in the mid-infrared spectral region are used to infer partial or total column abundances of many gases. In this paper we present the retrieval of a column averaged mole fraction of carbon dioxide from NDACC-IRWG spectra taken with a Fourier-Transform-Infra-Red (FTIR) spectrometer at the site in Ny-Ålesund, Spitsbergen. The retrieved time series is compared to co-located standard TCCON measurements of total column CO2. Comparing the NDACC and TCCON retrievals we find that the sensitivity of the NDACC retrieval is lower in the troposphere (by a factor of two) and higher in the stratosphere, compared to TCCON. Thus, the NDACC retrieval is less sensitive to tropospheric changes (e.g. the seasonal cycle) in the column average.


2000 ◽  
Vol 105 (D11) ◽  
pp. 14637-14652 ◽  
Author(s):  
Curtis Rinsland ◽  
Aaron Goldman ◽  
Brian J. Connor ◽  
Thomas M. Stephen ◽  
Nicholas B. Jones ◽  
...  

1985 ◽  
Vol 12 (4) ◽  
pp. 199-202 ◽  
Author(s):  
M. T. Coffey ◽  
W. G. Mankin ◽  
A. Goldman ◽  
C. P. Rinsland ◽  
G. A. Harvey ◽  
...  

1985 ◽  
Vol 12 (10) ◽  
pp. 663-666 ◽  
Author(s):  
J. C. Larsen ◽  
C. P. Rinsland ◽  
A. Goldman ◽  
D. G. Murcray ◽  
F. J. Murcray

2006 ◽  
Vol 419 (4-6) ◽  
pp. 501-505 ◽  
Author(s):  
Osamu Takahashi ◽  
Saiko Yamanouchi ◽  
Keisuke Yamamoto ◽  
Kiyohiko Tabayashi

2003 ◽  
Vol 82 (1-4) ◽  
pp. 133-150 ◽  
Author(s):  
Pierre-François Coheur ◽  
Cathy Clerbaux ◽  
Michel Carleer ◽  
Sophie Fally ◽  
Daniel Hurtmans ◽  
...  

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