Solubility of hydrogen and ferric iron in rutile and TiO2(II): Implications for phase assemblages during ultrahigh-pressure metamorphism and for the stability of silica polymorphs in the lower mantle

2004 ◽  
Vol 31 (4) ◽  
Author(s):  
Geoffrey Bromiley
Keyword(s):  
Lower Mantle ◽  
Ferric Iron ◽  
Ultrahigh Pressure ◽  
Ultrahigh Pressure Metamorphism ◽  
The Stability

scholarly journals Electronic spin state of ferric iron in Al-bearing perovskite in the lower mantle

2005 ◽  
Vol 32 (17) ◽  
Author(s):  
Li Li ◽  
John P. Brodholt ◽  
Stephen Stackhouse ◽  
Donald J. Weidner ◽  
Maria Alfredsson ◽  
...  
Keyword(s):  
Spin State ◽  
Lower Mantle ◽  
Ferric Iron ◽  
Electronic Spin

scholarly journals Evidence for the stability of ultrahydrous stishovite in Earth’s lower mantle

2019 ◽  
Vol 117 (1) ◽  
pp. 184-189 ◽  
Author(s):  
Yanhao Lin ◽  
Qingyang Hu ◽  
Yue Meng ◽  
Michael Walter ◽  
Ho-Kwang Mao
Keyword(s):  
Transition Zone ◽  
Lower Mantle ◽  
Water Reservoir ◽  
Weight Percent ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mineral Components ◽  
The Stability ◽  
Stability Of Water

The distribution and transportation of water in Earth’s interior depends on the stability of water-bearing phases. The transition zone in Earth’s mantle is generally accepted as an important potential water reservoir because its main constituents, wadsleyite and ringwoodite, can incorporate weight percent levels of H2O in their structures at mantle temperatures. The extent to which water can be transported beyond the transition zone deeper into the mantle depends on the water carrying capacity of minerals stable in subducted lithosphere. Stishovite is one of the major mineral components in subducting oceanic crust, yet the capacity of stishovite to incorporate water beyond at lower mantle conditions remains speculative. In this study, we combine in situ laser heating with synchrotron X-ray diffraction to show that the unit cell volume of stishovite synthesized under hydrous conditions is ∼2.3 to 5.0% greater than that of anhydrous stishovite at pressures of ∼27 to 58 GPa and temperatures of 1,240 to 1,835 K. Our results indicate that stishovite, even at temperatures along a mantle geotherm, can potentially incorporate weight percent levels of H2O in its crystal structure and has the potential to be a key phase for transporting and storing water in the lower mantle.

Ar/Ar geochronology of ultrahigh-pressure metamorphism in central China

Tectonics ◽  
1995 ◽  
Vol 14 (4) ◽  
pp. 994-1006 ◽  
Author(s):  
Bradley R. Hacker ◽  
Qingchen Wang
Keyword(s):  
Central China ◽  
Ultrahigh Pressure ◽  
Ultrahigh Pressure Metamorphism ◽  
Ar Geochronology

Evolution of geodynamics since the Archean: Significant change at the dawn of the Phanerozoic

Geology ◽  
2020 ◽  
Vol 48 (5) ◽  
pp. 488-492 ◽  
Author(s):  
M. Brown ◽  
C.L. Kirkland ◽  
T.E. Johnson
Keyword(s):  
Ultrahigh Pressure ◽  
Secular Change ◽  
Metamorphic Rocks ◽  
Data Sets ◽  
Ultrahigh Pressure Metamorphism ◽  
Slab Breakoff ◽  
Wide Range ◽  
O Isotope ◽  
Global Data Sets ◽  
Global Data

Abstract A time-series analysis of thermobaric ratios (temperature/pressure [T/P]) for Paleoarchean to Cenozoic metamorphic rocks identified significant shifts in mean T/P that may be related to secular change in the geodynamics on Earth. Thermobaric ratios showed significant (>95% confidence) change points at 1910, 902, 540, and 515 Ma, recording drops in mean T/P, and at 1830, 604, and 525 Ma, recording rises in mean T/P. Highest mean T/P occurred during the Mesoproterozoic, and lowest mean T/P occurred from the Cambrian to the Oligocene. Correlated changes were seen between T/P and global data sets of time-constrained hafnium (Hf) and oxygen (O) isotope compositions in zircon. The range of correlated variation in T/P, Hf, and O was larger during the formation of Rodinia than Columbia. Large changes and a wide range for these variables continued through the Phanerozoic, during which a statistically significant 83 m.y. frequency of T/P excursions recorded the high tempo of orogenic activity associated with the separation, migration, and accretion of continental terranes during the formation of Pangea. Since the early Tonian, the decreasing mean T/P of metamorphism, widespread appearance of blueschist and ultrahigh-pressure metamorphism, and wide fluctuations in Hf and O isotope compositions document a change to the modern plate-tectonic regime, characterized by widespread continental subduction and deeper slab breakoff than in the Proterozoic.

Evidence for ultrahigh-pressure metamorphism discovered in the Appalachian orogen

Geology ◽  
2020 ◽  
Vol 48 (10) ◽  
pp. 947-951
Author(s):  
Joseph P. Gonzalez ◽  
Suzanne L. Baldwin ◽  
Jay B. Thomas ◽  
William O. Nachlas ◽  
Paul G. Fitzgerald
Keyword(s):  
Direct Evidence ◽  
Ultrahigh Pressure ◽  
Garnet Growth ◽  
Uhp Metamorphism ◽  
Ultrahigh Pressure Metamorphism ◽  
Iapetus Ocean ◽  
Taconic Orogeny ◽  
Growth History ◽  
Appalachian Orogen

Abstract The Appalachian orogen has long been enigmatic because, compared to other parts of the Paleozoic orogens that formed following the subduction of the Iapetus Ocean, direct evidence for ultrahigh-pressure (UHP) metamorphism has never been found. We report the first discovery of coesite in the Appalachian orogen in a metapelite from the mid-Ordovician (Taconic orogeny) Tillotson Peak Complex in Vermont (USA). Relict coesite occurs within a bimineralic SiO2 inclusion in garnet. In situ elastic barometry and trace-element thermometry allow reconstruction of the garnet growth history during prograde metamorphism. The data are interpreted to indicate garnet nucleation and crystallization during blueschist- to eclogite-facies subduction zone metamorphism, followed by garnet rim growth at UHP conditions of > 28 kbar and > 530 ° C. Results provide the first direct evidence that rocks of the Appalachian orogen underwent UHP metamorphism to depths of > 75 km and warrant future studies that constrain the extent of UHP metamorphism.

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