Behavior of indicator variograms and transition probabilities in relation to the variance in lengths of hydrofacies

2000 ◽  
Vol 36 (11) ◽  
pp. 3375-3381 ◽  
Author(s):  
Robert W. Ritzi
2016 ◽  
Author(s):  
Barry G Rawlins ◽  
Joanna Wragg ◽  
Christina Rheinhard ◽  
Robert C Atwood ◽  
Alasdair Houston ◽  
...  

Abstract. The spatial distribution and accessibility of organic matter (OM) to soil microbes in aggregates – determined by the fine-scale, 3-D distribution of organic matter, pores and mineral phases – may be an important control on the magnitude of soil heterotrophic respiration (SHR). Attempts to model SHR at fine scales requires data on the transition probabilities between adjacent pore space and soil OM, a measure of microbial accessibility to the latter. We used a combination of osmium staining and synchrotron X-ray CT to determine the 3-D (voxel) distribution of these three phases (scale 6.6 μm) throughout nine aggregates taken from a single soil core (range of organic carbon (OC) concentrations 4.2–7.7 %). Prior to the synchrotron analyses we had measured the magnitude of SHR for each aggregate over 24 hours under controlled conditions (moisture content and temperature). We test the hypothesis that larger magnitudes of SHR will be observed in aggregates with shorter length scales of OM variation (i.e. more frequent, and possibly more finely disseminated, OM and a larger number of aerobic microsites). After scaling to their OC concentrations, there was a six-fold variation in the magnitude of SHR for the nine aggregates. The distribution of pore volumes, pore shape and volume normalised surface area were similar for each of the nine aggregates. The overall transition probabilities between OM and pore voxels were between 0.02 and 0.03, significantly smaller than those used in previous simulation studies. We computed the length scales over which OM, pore and mineral phases vary within each aggregate using indicator variograms. The median range of models fitted to variograms of OM varied between 178 and 487 μm. The linear correlation between these median length scales of OM variation and the magnitudes of SHR for each aggregate was −0.42, providing some evidence to support our hypothesis. We require a larger number of observations to make a statistical inference. There was no evidence to suggest a statistical relationship between OM:pore transition probabilities and the magnitudes of aggregate SHR. The solid-phase volume proportions (45–63 %) of OM we report for our aggregates were surprisingly large by comparison to those assumed in previous modelling approaches. We suggest this requires further assessment using accurate measurements of OM bulk density in a range of soil types.


Author(s):  
C. C. Ahn ◽  
D. H. Pearson ◽  
P. Rez ◽  
B. Fultz

Previous experimental measurements of the total white line intensities from L2,3 energy loss spectra of 3d transition metals reported a linear dependence of the white line intensity on 3d occupancy. These results are inconsistent, however, with behavior inferred from relativistic one electron Dirac-Fock calculations, which show an initial increase followed by a decrease of total white line intensity across the 3d series. This inconsistency with experimental data is especially puzzling in light of work by Thole, et al., which successfully calculates x-ray absorption spectra of the lanthanide M4,5 white lines by employing a less rigorous Hartree-Fock calculation with relativistic corrections based on the work of Cowan. When restricted to transitions allowed by dipole selection rules, the calculated spectra of the lanthanide M4,5 white lines show a decreasing intensity as a function of Z that was consistent with the available experimental data.Here we report the results of Dirac-Fock calculations of the L2,3 white lines of the 3d and 4d elements, and compare the results to the experimental work of Pearson et al. In a previous study, similar calculations helped to account for the non-statistical behavior of L3/L2 ratios of the 3d metals. We assumed that all metals had a single 4s electron. Because these calculations provide absolute transition probabilities, to compare the calculated white line intensities to the experimental data, we normalized the calculated intensities to the intensity of the continuum above the L3 edges. The continuum intensity was obtained by Hartree-Slater calculations, and the normalization factor for the white line intensities was the integrated intensity in an energy window of fixed width and position above the L3 edge of each element.


Author(s):  
R. Jamuna

CpG islands (CGIs) play a vital role in genome analysis as genomic markers.  Identification of the CpG pair has contributed not only to the prediction of promoters but also to the understanding of the epigenetic causes of cancer. In the human genome [1] wherever the dinucleotides CG occurs the C nucleotide (cytosine) undergoes chemical modifications. There is a relatively high probability of this modification that mutates C into a T. For biologically important reasons the mutation modification process is suppressed in short stretches of the genome, such as ‘start’ regions. In these regions [2] predominant CpG dinucleotides are found than elsewhere. Such regions are called CpG islands. DNA methylation is an effective means by which gene expression is silenced. In normal cells, DNA methylation functions to prevent the expression of imprinted and inactive X chromosome genes. In cancerous cells, DNA methylation inactivates tumor-suppressor genes, as well as DNA repair genes, can disrupt cell-cycle regulation. The most current methods for identifying CGIs suffered from various limitations and involved a lot of human interventions. This paper gives an easy searching technique with data mining of Markov Chain in genes. Markov chain model has been applied to study the probability of occurrence of C-G pair in the given   gene sequence. Maximum Likelihood estimators for the transition probabilities for each model and analgously for the  model has been developed and log odds ratio that is calculated estimates the presence or absence of CpG is lands in the given gene which brings in many  facts for the cancer detection in human genome.


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