scholarly journals Effects of improvements in near-infrared water vapour line intensities on short-wave atmospheric absorption

2001 ◽  
Vol 28 (12) ◽  
pp. 2401-2404
Author(s):  
Júlio C. S. Chagas ◽  
David A. Newnham ◽  
Kevin M. Smith ◽  
Keith P. Shine
Author(s):  
Igor V. Ptashnik ◽  
Robert A. McPheat ◽  
Keith P. Shine ◽  
Kevin M. Smith ◽  
R. Gary Williams

For a long time, it has been believed that atmospheric absorption of radiation within wavelength regions of relatively high infrared transmittance (so-called ‘windows’) was dominated by the water vapour self-continuum, that is, spectrally smooth absorption caused by H 2 O−H 2 O pair interaction. Absorption due to the foreign continuum (i.e. caused mostly by H 2 O−N 2 bimolecular absorption in the Earth's atmosphere) was considered to be negligible in the windows. We report new retrievals of the water vapour foreign continuum from high-resolution laboratory measurements at temperatures between 350 and 430 K in four near-infrared windows between 1.1 and 5 μm (9000–2000 cm −1 ). Our results indicate that the foreign continuum in these windows has a very weak temperature dependence and is typically between one and two orders of magnitude stronger than that given in representations of the continuum currently used in many climate and weather prediction models. This indicates that absorption owing to the foreign continuum may be comparable to the self-continuum under atmospheric conditions in the investigated windows. The calculated global-average clear-sky atmospheric absorption of solar radiation is increased by approximately 0.46 W m −2 (or 0.6% of the total clear-sky absorption) by using these new measurements when compared with calculations applying the widely used MTCKD (Mlawer–Tobin–Clough–Kneizys–Davies) foreign-continuum model.


2019 ◽  
Author(s):  
Arundhati Deshmukh ◽  
Danielle Koppel ◽  
Chern Chuang ◽  
Danielle Cadena ◽  
Jianshu Cao ◽  
...  

Technologies which utilize near-infrared (700 – 1000 nm) and short-wave infrared (1000 – 2000 nm) electromagnetic radiation have applications in deep-tissue imaging, telecommunications and satellite telemetry due to low scattering and decreased background signal in this spectral region. However, there are few molecular species, which absorb efficiently beyond 1000 nm. Transition dipole moment coupling (e.g. J-aggregation) allows for redshifted excitonic states and provides a pathway to highly absorptive electronic states in the infrared. We present aggregates of two cyanine dyes whose absorption peaks redshift dramatically upon aggregation in water from ~ 800 nm to 1000 nm and 1050 nm with sheet-like morphologies and high molar absorptivities (e ~ 10<sup>5 </sup>M<sup>-1</sup>cm<sup>-1</sup>). To describe this phenomenology, we extend Kasha’s model for J- and H-aggregation to describe the excitonic states of <i> 2-dimensional aggregates</i> whose slip is controlled by steric hindrance in the assembled structure. A consequence of the increased dimensionality is the phenomenon of an <i>intermediate </i>“I-aggregate”, one which redshifts yet displays spectral signatures of band-edge dark states akin to an H-aggregate. We distinguish between H-, I- and J-aggregates by showing the relative position of the bright (absorptive) state within the density of states using temperature dependent spectroscopy. Our results can be used to better design chromophores with predictable and tunable aggregation with new photophysical properties.


2021 ◽  
Vol 13 (3) ◽  
pp. 536
Author(s):  
Eve Laroche-Pinel ◽  
Mohanad Albughdadi ◽  
Sylvie Duthoit ◽  
Véronique Chéret ◽  
Jacques Rousseau ◽  
...  

The main challenge encountered by Mediterranean winegrowers is water management. Indeed, with climate change, drought events are becoming more intense each year, dragging the yield down. Moreover, the quality of the vineyards is affected and the level of alcohol increases. Remote sensing data are a potential solution to measure water status in vineyards. However, important questions are still open such as which spectral, spatial, and temporal scales are adapted to achieve the latter. This study aims at using hyperspectral measurements to investigate the spectral scale adapted to measure their water status. The final objective is to find out whether it would be possible to monitor the vine water status with the spectral bands available in multispectral satellites such as Sentinel-2. Four Mediterranean vine plots with three grape varieties and different water status management systems are considered for the analysis. Results show the main significant domains related to vine water status (Short Wave Infrared, Near Infrared, and Red-Edge) and the best vegetation indices that combine these domains. These results give some promising perspectives to monitor vine water status.


2021 ◽  
Vol 13 (15) ◽  
pp. 2967
Author(s):  
Nicola Acito ◽  
Marco Diani ◽  
Gregorio Procissi ◽  
Giovanni Corsini

Atmospheric compensation (AC) allows the retrieval of the reflectance from the measured at-sensor radiance and is a fundamental and critical task for the quantitative exploitation of hyperspectral data. Recently, a learning-based (LB) approach, named LBAC, has been proposed for the AC of airborne hyperspectral data in the visible and near-infrared (VNIR) spectral range. LBAC makes use of a parametric regression function whose parameters are learned by a strategy based on synthetic data that accounts for (1) a physics-based model for the radiative transfer, (2) the variability of the surface reflectance spectra, and (3) the effects of random noise and spectral miscalibration errors. In this work we extend LBAC with respect to two different aspects: (1) the platform for data acquisition and (2) the spectral range covered by the sensor. Particularly, we propose the extension of LBAC to spaceborne hyperspectral sensors operating in the VNIR and short-wave infrared (SWIR) portion of the electromagnetic spectrum. We specifically refer to the sensor of the PRISMA (PRecursore IperSpettrale della Missione Applicativa) mission, and the recent Earth Observation mission of the Italian Space Agency that offers a great opportunity to improve the knowledge on the scientific and commercial applications of spaceborne hyperspectral data. In addition, we introduce a curve fitting-based procedure for the estimation of column water vapor content of the atmosphere that directly exploits the reflectance data provided by LBAC. Results obtained on four different PRISMA hyperspectral images are presented and discussed.


2021 ◽  
pp. 2101217
Author(s):  
Hengyang Xiang ◽  
Zhelu Hu ◽  
Chenghao Xin ◽  
Hung‐Ju Lin ◽  
Lionel Aigouy ◽  
...  

Water ◽  
2013 ◽  
Vol 5 (4) ◽  
pp. 2026-2036 ◽  
Author(s):  
Ignacio Melendez-Pastor ◽  
M. Almendro-Candel ◽  
Jose Navarro-Pedreño ◽  
Ignacio Gómez ◽  
Mariano Lillo ◽  
...  

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