scholarly journals Changes of total CO2andpCO2in the surface ocean during the mixed layer development in the northern North Pacific

2000 ◽  
Vol 105 (C2) ◽  
pp. 3465-3481 ◽  
Author(s):  
Yoshikazu Sasai ◽  
Motoyoshi Ikeda ◽  
Noriyuki Tanaka

Abstract Recent evidence shows that the North Pacific subtropical gyre, the Kuroshio Extension (KE) and Oyashio Extension (OE) fronts have moved poleward in the past few decades. However, changes of the North Pacific Subtropical Fronts (STFs), anchored by the North Pacific subtropical countercurrent in the southern subtropical gyre, remain to be quantified. By synthesizing observations, reanalysis, and eddy-resolving ocean hindcasts, we show that the STFs, especially their eastern part, weakened (20%±5%) and moved poleward (1.6°±0.4°) from 1980 to 2018. Changes of the STFs are modified by mode waters to the north. We find that the central mode water (CMW) (180°-160°W) shows most significant weakening (18%±7%) and poleward shifting (2.4°±0.9°) trends, while the eastern part of the subtropical mode water (STMW) (160°E-180°) has similar but moderate changes (10% ± 8%; 0.9°±0.4°). Trends of the western part of the STMW (140°E-160°E) are not evident. The weakening and poleward shifting of mode waters and STFs are enhanced to the east and are mainly associated with changes of the northern deep mixed layers and outcrop lines—which have a growing northward shift as they elongate to the east. The eastern deep mixed layer shows the largest shallowing trend, where the subduction rate also decreases the most. The mixed layer and outcrop line changes are strongly coupled with the northward migration of the North Pacific subtropical gyre and the KE/OE jets as a result of the poleward expanded Hadley cell, indicating that the KE/OE fronts, mode waters, and STFs change as a whole system.


Ocean Science ◽  
2013 ◽  
Vol 9 (2) ◽  
pp. 193-216 ◽  
Author(s):  
C. Rödenbeck ◽  
R. F. Keeling ◽  
D. C. E. Bakker ◽  
N. Metzl ◽  
A. Olsen ◽  
...  

Abstract. A temporally and spatially resolved estimate of the global surface-ocean CO2 partial pressure field and the sea–air CO2 flux is presented, obtained by fitting a simple data-driven diagnostic model of ocean mixed-layer biogeochemistry to surface-ocean CO2 partial pressure data from the SOCAT v1.5 database. Results include seasonal, interannual, and short-term (daily) variations. In most regions, estimated seasonality is well constrained from the data, and compares well to the widely used monthly climatology by Takahashi et al. (2009). Comparison to independent data tentatively supports the slightly higher seasonal variations in our estimates in some areas. We also fitted the diagnostic model to atmospheric CO2 data. The results of this are less robust, but in those areas where atmospheric signals are not strongly influenced by land flux variability, their seasonality is nevertheless consistent with the results based on surface-ocean data. From a comparison with an independent seasonal climatology of surface-ocean nutrient concentration, the diagnostic model is shown to capture relevant surface-ocean biogeochemical processes reasonably well. Estimated interannual variations will be presented and discussed in a companion paper.


2013 ◽  
Vol 10 (5) ◽  
pp. 8283-8311 ◽  
Author(s):  
M. Wakita ◽  
S. Watanabe ◽  
M. Honda ◽  
A. Nagano ◽  
K. Kimoto ◽  
...  

Abstract. Rising atmospheric CO2 contents have led to greater CO2 uptake by the oceans, lowering both pH due to increasing hydrogen ions and CaCO3 saturation states due to declining carbonate ion (CO32−). Here, we used previously compiled data sets and new data collected in 2010 and 2011 to investigate ocean acidification of the North Pacific western subarctic gyre. In winter, the western subarctic gyre is a source of CO2 to the atmosphere because of convective mixing of deep waters rich in dissolved inorganic carbon (DIC). We calculated pH in winter mixed layer from DIC and total alkalinity (TA), and found that it decreased at the rate of −0.001 ± 0.0004 yr−1 from 1997 to 2011. This decrease rate is slower than that expected under condition of seawater/atmosphere equilibration, and it is also slower than the rate in the subtropical regions (−0.002 yr−1). The slow rate is caused by a reduction of CO2 emission in winter due to an increase in TA. Below the mixed layer, the calcite saturation horizon (~185 m depth) shoaled at the rate of 2.9 ± 0.9 m yr−1 as the result of the declining CO32− concentration (−0.03 ± 0.01 μmol k−1yr−1). Between 200 m and 300 m depth, pH decline during the study period (−0.0051 ± 0.0010 yr−1) was larger than ever reported in the open North Pacific. This enhanced acidification rate below the calcite saturation horizon reflected not only the uptake of anthropogenic CO2 but also the increase in the decomposition of organic matter evaluated from the increase in AOU, which suggests that the dissolution of CaCO3 particles increased.


2009 ◽  
Vol 6 (11) ◽  
pp. 2333-2353 ◽  
Author(s):  
M. Vichi ◽  
S. Masina

Abstract. Global Ocean Biogeochemistry General Circulation Models are useful tools to study biogeochemical processes at global and large scales under current climate and future scenario conditions. The credibility of future estimates is however dependent on the model skill in capturing the observed multi-annual variability of firstly the mean bulk biogeochemical properties, and secondly the rates at which organic matter is processed within the food web. For this double purpose, the results of a multi-annual simulation of the global ocean biogeochemical model PELAGOS have been objectively compared with multi-variate observations from the last 20 years of the 20th century, both considering bulk variables and carbon production/consumption rates. Simulated net primary production (NPP) is comparable with satellite-derived estimates at the global scale and when compared with an independent data-set of in situ observations in the equatorial Pacific. The usage of objective skill indicators allowed us to demonstrate the importance of comparing like with like when considering carbon transformation processes. NPP scores improve substantially when in situ data are compared with modeled NPP which takes into account the excretion of freshly-produced dissolved organic carbon (DOC). It is thus recommended that DOC measurements be performed during in situ NPP measurements to quantify the actual production of organic carbon in the surface ocean. The chlorophyll bias in the Southern Ocean that affects this model as well as several others is linked to the inadequate representation of the mixed layer seasonal cycle in the region. A sensitivity experiment confirms that the artificial increase of mixed layer depths towards the observed values substantially reduces the bias. Our assessment results qualify the model for studies of carbon transformation in the surface ocean and metabolic balances. Within the limits of the model assumption and known biases, PELAGOS indicates a net heterotrophic balance especially in the more oligotrophic regions of the Atlantic during the boreal winter period. However, at the annual time scale and over the global ocean, the model suggests that the surface ocean is close to a weakly positive autotrophic balance in accordance with recent experimental findings and geochemical considerations.


Ocean Science ◽  
2006 ◽  
Vol 2 (1) ◽  
pp. 61-70 ◽  
Author(s):  
F. M. Bingham ◽  
T. Suga

Abstract. Winter mixed layer characteristics in the North Pacific Ocean are examined and compared between Argo floats in 2006 and the World Ocean Atlas 2001 (WOA01) climatology for a series of named water masses, North Pacific Tropical Water (NPTW), Eastern Subtropical Mode Water (ESTMW), North Pacific Subtropical Mode Water (NPSTMW), Light Central Mode Water (LCMW) and Dense Central Mode Water (DCMW). The WOA01 is found to be in good agreement with the Argo data in terms of water mass volumes, average temperature-salinity (T-S) properties, and outcrop areas. The exception to this conclusion is for the central mode waters, DCMW and LCMW, whose outcropping is shown to be much more intermittent than is apparent in the WOA01 and whose T-S properties vary from what is shown in the WOA01. Distributions of mixed layer T-S properties measured by floats are examined within the outcropping areas defined by the WOA01 and show some shifting of T-S characteristics within the confines of the named water masses. In 2006, all the water masses were warmer than climatology on average, with a magnitude of about 0.5°C. The NPTW, NPSTMW and LCMW were saltier than climatology and the ESTMW and DCMW fresher, with magnitudes of about 0.05. In order to put these results into context, differences between Argo and WOA01 were examined over the North Pacific between 20 and 45° N. A large-scsale warming and freshening is seen throughout this area, except for the western North Pacific, where results were more mixed.


2015 ◽  
Vol 49 (3) ◽  
pp. 891-907 ◽  
Author(s):  
Takahiro Toyoda ◽  
Yosuke Fujii ◽  
Tsurane Kuragano ◽  
Naohiro Kosugi ◽  
Daisuke Sasano ◽  
...  

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