High-pressure experiments and the phase diagram of lower mantle and core materials

2000 ◽  
Vol 38 (2) ◽  
pp. 221-245 ◽  
Author(s):  
R. Boehler
2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Carla Lupo ◽  
Evan Sheridan ◽  
Edoardo Fertitta ◽  
David Dubbink ◽  
Chris J. Pickard ◽  
...  

AbstractUsing spin-assisted ab initio random structure searches, we explore an exhaustive quantum phase diagram of archetypal interfaced Mott insulators, i.e. lanthanum-iron and lanthanum-titanium oxides. In particular, we report that the charge transfer induced by the interfacial electronic reconstruction stabilises a high-spin ferrous Fe2+ state. We provide a pathway to control the strength of correlation in this electronic state by tuning the epitaxial strain, yielding a manifold of quantum electronic phases, i.e. Mott-Hubbard, charge transfer and Slater insulating states. Furthermore, we report that the electronic correlations are closely related to the structural oxygen octahedral rotations, whose control is able to stabilise the low-spin state of Fe2+ at low pressure previously observed only under the extreme high pressure conditions in the Earth’s lower mantle. Thus, we provide avenues for magnetic switching via THz radiations which have crucial implications for next generation of spintronics technologies.


2015 ◽  
Vol 91 (13) ◽  
Author(s):  
Agnès Dewaele ◽  
Vincent Stutzmann ◽  
Johann Bouchet ◽  
François Bottin ◽  
Florent Occelli ◽  
...  

2015 ◽  
Vol 107 (22) ◽  
pp. 221908 ◽  
Author(s):  
Serge Desgreniers ◽  
John S. Tse ◽  
Takahiro Matsuoka ◽  
Yasuo Ohishi ◽  
Quan Li ◽  
...  

1994 ◽  
Vol 209 (1-2) ◽  
pp. 311-317 ◽  
Author(s):  
Yasuo Fujinaga ◽  
Tasaku Sato
Keyword(s):  

ACS Omega ◽  
2018 ◽  
Vol 3 (12) ◽  
pp. 18227-18233 ◽  
Author(s):  
Junbo Gong ◽  
Xiaodong Fan ◽  
Rucheng Dai ◽  
Zhongping Wang ◽  
Zejun Ding ◽  
...  

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