Heterogeneous reaction of N2O5on sodium nitrate aerosol

1998 ◽  
Vol 103 (D23) ◽  
pp. 31103-31112 ◽  
Author(s):  
Andreas Wahner ◽  
Thomas F. Mentel ◽  
Martin Sohn ◽  
Jutta Stier
Keyword(s):  
Sodium Nitrate ◽  
Heterogeneous Reaction ◽  
Nitrate Aerosol

Drying and Crystallization of Evaporating Sodium Nitrate Aerosol Droplets

2020 ◽  
Vol 124 (28) ◽  
pp. 6024-6036 ◽  
Author(s):  
F. K. A. Gregson ◽  
J. F. Robinson ◽  
R. E. H. Miles ◽  
C. P. Royall ◽  
J. P. Reid
Keyword(s):  
Sodium Nitrate ◽  
Nitrate Aerosol

Effects of sodium nitrate aerosol on cardiopulmonary function of dogs, sheep, and man

1979 ◽  
Vol 18 (2) ◽  
pp. 421-436 ◽  
Author(s):  
Marvin A. Sackner ◽  
Richard D. Dougherty ◽  
Gillette A. Chapman ◽  
Stephen Zarzecki ◽  
Linda Zarzemski ◽  
...  
Keyword(s):  
Sodium Nitrate ◽  
Cardiopulmonary Function ◽  
Nitrate Aerosol

Scalable Synthesis of Functionalized Ferrocenyl Azides and Amines Enabled by Flow Chemistry

2019 ◽  
Author(s):  
Merlin Kleoff ◽  
Johannes Schwan ◽  
Lisa Boeser ◽  
Bence Hartmayer ◽  
Mathias Christmann ◽  
...  
Keyword(s):  
Reaction Time ◽  
Heterogeneous Reaction ◽  
Reduction Process ◽  
Flow Chemistry ◽  
Subsequent Reaction ◽  
Scalable Synthesis ◽  
High Yields ◽  
Reactor Section

A scalable access to functionalized 1,1’- and 1,2-ferrocenyl azides has been realized in flow. By halogen‒lithium exchange of ferrocenyl halides and subsequent reaction with tosyl azide, a variety of functionalized ferrocenyl azides was obtained in high yields. To allow a scalable preparation of these potentially explosive compounds, an efficient flow protocol was developed accelerating the reaction time to minutes and circumventing accumulation of potentially hazardous intermediates. Switching from homogeneous to triphasic flow amidst process was key for handling a heterogeneous reaction mixture formed after a heated reactor section. The corresponding and synthetically versatile ferrocenyl amines were then prepared by a reliable reduction process.

Effects of salts on the kinetics of oxidation of alkenes by thallic salts in aqueous solutions

1981 ◽  
Vol 46 (3) ◽  
pp. 693-700 ◽  
Author(s):  
Milan Strašák ◽  
Jaroslav Majer
Keyword(s):  
Aqueous Solutions ◽  
Phase Transfer ◽  
Heterogeneous Reaction ◽  
Qualitative Model ◽  
Kinetic Effect ◽  
Tetraalkylammonium Salts ◽  
Reaction Conditions ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Heterogeneous Reaction Conditions

The kinetics of oxidation of alkenes by thallic sulphate in aqueous solutions, involving the two reaction steps-the hydroxythallation and the dethallation - was studied, and the effect of salts on the kinetics was examined; this made it possible to specify more precisely the reaction mechanism and to suggest a qualitative model of the reaction coordinate. It was found that in homogeneous as well as in heterogeneous reaction conditions, the reaction can be accelerated appreciably by adding tetraalkylammonium salts. These salts not only operate as catalysts of the phase transfer, but also exert a significant kinetic effect, which can be explained with a simplification in terms of a stabilization of the transition state of the reaction.

Formation of sodium disulfite in a solid-gas system

1991 ◽  
Vol 56 (8) ◽  
pp. 1575-1579 ◽  
Author(s):  
Jiří Vobiš ◽  
Karel Mocek ◽  
Emerich Erdös
Keyword(s):  
Sodium Sulfite ◽  
Heterogeneous Reaction ◽  
Optimum Conditions ◽  
Kinetic Measurements ◽  
Dissociation Pressure ◽  
Partial Pressures ◽  
Gas System ◽  
Gaseous Sulfur ◽  
Equilibrium Dissociation

The formation of sodium disulfite by the heterogeneous reaction of solid active sodium sulfite with gaseous sulfur dioxide in the presence of water vapour was investigated over the temperature range of 293 to 393 K at SO2. H2O and O2 partial pressures of 1.2-7.4, 1.2-6.4 and 0-11.3 kPa, respectively. The effect of the reaction time was also examined. Kinetic measurements were supplemented with the determination of the equilibrium dissociation pressure of SO2 in contact with sodium sulfite at 373.15 K. The major aim of the work was to establish the optimum conditions for attaining the maximum degree of conversion of the solid reactant to sodium disulfite. The conditions for the formation of virtually pure sodium disulfite were found.

Vapor pressures of aqueous solutions of (silver, thallium, sodium) nitrate at 98.5.degree.C

1980 ◽  
Vol 25 (4) ◽  
pp. 331-332 ◽  
Author(s):  
Marie Christine Abraham ◽  
Maurice Abraham ◽  
James Sangster
Keyword(s):  
Aqueous Solutions ◽  
Sodium Nitrate ◽  
Vapor Pressures

scholarly journals Demonstration of Phase Change Thermal Energy Storage in Zinc Oxide Microencapsulated Sodium Nitrate

2021 ◽  
Vol 11 (13) ◽  
pp. 6234
Author(s):  
Ciprian Neagoe ◽  
Ioan Albert Tudor ◽  
Cristina Florentina Ciobota ◽  
Cristian Bogdanescu ◽  
Paul Stanciu ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Thermal Properties ◽  
High Temperature ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Sodium Nitrate ◽  
Thermal Energy Storage ◽  
Metal Corrosion ◽  
Scanning Calorimetry

Microencapsulation of sodium nitrate (NaNO3) as phase change material for high temperature thermal energy storage aims to reduce costs related to metal corrosion in storage tanks. The goal of this work was to test in a prototype thermal energy storage tank (16.7 L internal volume) the thermal properties of NaNO3 microencapsulated in zinc oxide shells, and estimate the potential of NaNO3–ZnO microcapsules for thermal storage applications. A fast and scalable microencapsulation procedure was developed, a flow calorimetry method was adapted, and a template document created to perform tank thermal transfer simulation by the finite element method (FEM) was set in Microsoft Excel. Differential scanning calorimetry (DSC) and transient plane source (TPS) methods were used to measure, in small samples, the temperature dependency of melting/solidification heat, specific heat, and thermal conductivity of the NaNO3–ZnO microcapsules. Scanning electron microscopy (SEM) and chemical analysis demonstrated the stability of microcapsules over multiple tank charge–discharge cycles. The energy stored as latent heat is available for a temperature interval from 303 to 285 °C, corresponding to onset–offset for NaNO3 solidification. Charge–self-discharge experiments on the pilot tank showed that the amount of thermal energy stored in this interval largely corresponds to the NaNO3 content of the microcapsules; the high temperature energy density of microcapsules is estimated in the range from 145 to 179 MJ/m3. Comparison between real tank experiments and FEM simulations demonstrated that DSC and TPS laboratory measurements on microcapsule thermal properties may reliably be used to design applications for thermal energy storage.

Role of nanomaterial's as adsorbent for heterogeneous reaction in waste water treatment

2021 ◽  
pp. 130596
Author(s):  
M. Sridevi ◽  
C. Nirmala ◽  
N. Jawahar ◽  
G. Arthi ◽  
Sugumari Vallinayagam ◽  
...  
Keyword(s):  
Waste Water ◽  
Water Treatment ◽  
Heterogeneous Reaction ◽  
Waste Water Treatment

Thermoelectric Studies of Silver Nitrate in Sodium Nitrate – Potassium Nitrate Eutectic Melt

1971 ◽  
Vol 49 (12) ◽  
pp. 2044-2047
Author(s):  
L. G. Boxall ◽  
K. E. Johnson
Keyword(s):  
Seebeck Coefficient ◽  
Silver Nitrate ◽  
Mole Fraction ◽  
Sodium Nitrate ◽  
Nitrate Concentration ◽  
Potassium Nitrate ◽  
Silver Nitrate Concentration ◽  
Eutectic Melt

The Seebeck coefficient, εT, of the thermocell Ag(T)/AgNO3 in NaNO3 − KNO3/Ag (T + ΔT) was measured as a function of silver nitrate concentration and temperature. Extrapolation of the results to unit mole fraction, N, of AgNO3 gave the value εT0 = − 277.5 − 0.136T °C (µV deg−1).For several mixed melts of AgNO3 and an alkali nitrate the function [Formula: see text] was calculated and shown to be linear in N. P was extrapolated to finite values for the pure alkali nitrates.

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