Identification and characterization of deoxyguanosine adducts of methyl vinyl ketone and ethyl vinyl ketone. Genotoxicity of the ketones in the SOS chromotest

1991 ◽  
Vol 4 (1) ◽  
pp. 50-57 ◽  
Author(s):  
Erwin Eder ◽  
Christian Hoffman ◽  
Christoph Deininger
Keyword(s):  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Ethyl Vinyl ◽  
Methyl Vinyl ◽  
Sos Chromotest ◽  
Identification And Characterization

Radical oxidation of methyl vinyl ketone and methacrolein in aqueous droplets: Characterization of organosulfates and atmospheric implications

Chemosphere ◽  
2019 ◽  
Vol 214 ◽  
pp. 1-9 ◽  
Author(s):  
Paulina Wach ◽  
Grzegorz Spólnik ◽  
Krzysztof J. Rudziński ◽  
Krzysztof Skotak ◽  
Magda Claeys ◽  
...  
Keyword(s):  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Radical Oxidation ◽  
Methyl Vinyl

Aza-Morita–Baylis–Hillman reaction of ethyl (arylimino)acetate with methyl vinyl ketone and ethyl vinyl ketone

2006 ◽  
Vol 47 (44) ◽  
pp. 7685-7688 ◽  
Author(s):  
Jun Gao ◽  
Guang-Ning Ma ◽  
Qing-Jiang Li ◽  
Min Shi
Keyword(s):  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Ethyl Vinyl ◽  
Methyl Vinyl

scholarly journals Infrared characterization of formation and resonance stabilization of the Criegee intermediate methyl vinyl ketone oxide

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Chen-An Chung ◽  
Yuan-Pern Lee
Keyword(s):  
High Pressure ◽  
Fourier Transform ◽  
Reaction Mechanism ◽  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Fourier Transform Spectrometer ◽  
Methyl Vinyl ◽  
Criegee Intermediates ◽  
Resonance Stabilization

AbstractMethyl vinyl ketone oxide (MVKO) is an important Criegee intermediate in the ozonolysis of isoprene. MVKO is resonance stabilized by its allyl moiety, but no spectral characterization of this stabilization was reported to date. In this study, we photolyzed a mixture of 1,3-diiodo-but-2-ene and O2 to produce MVKO and characterized the syn-trans-MVKO, and tentatively syn-cis-MVKO, with transient infrared spectra recorded using a step-scan Fourier-transform spectrometer. The O‒O stretching band at 948 cm−1 of syn-trans-MVKO is much greater than the corresponding bands of syn-CH3CHOO and (CH3)2COO Criegee intermediates at 871 and 887 cm−1, respectively, confirming a stronger O‒O bond due to resonance stabilization. We observed also iodoalkenyl radical C2H3C(CH3)I upon photolysis of the precursor to confirm the fission of the terminal allylic C‒I bond rather than the central vinylic C‒I bond of the precursor upon photolysis. At high pressure, the adduct C2H3C(CH3)IOO was also observed. The reaction mechanism is characterized.

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